The hybridization of Ag2CO3 rods with g-C3N4 sheets with improved photocatalytic activity

A series of graphitic carbon nitride/silver carbonate (g-C3N4/Ag2CO3) rod-like composites with different weight contents of g-C3N4 have been prepared by a facile precipitation method. The g-C3N4/Ag2CO3 rod-like composites exhibited higher photocatalytic activity than pure Ag2CO3 toward degradation o...

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Main Authors: Konglin Wu, Yanwei Cui, Xianwen Wei, Xinjie Song, Jiarui Huang
Format: Article
Language:English
Published: Springer 2015-09-01
Series:Journal of Saudi Chemical Society
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1319610315000903
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author Konglin Wu
Yanwei Cui
Xianwen Wei
Xinjie Song
Jiarui Huang
author_facet Konglin Wu
Yanwei Cui
Xianwen Wei
Xinjie Song
Jiarui Huang
author_sort Konglin Wu
collection DOAJ
description A series of graphitic carbon nitride/silver carbonate (g-C3N4/Ag2CO3) rod-like composites with different weight contents of g-C3N4 have been prepared by a facile precipitation method. The g-C3N4/Ag2CO3 rod-like composites exhibited higher photocatalytic activity than pure Ag2CO3 toward degradation of rhodamine B (RhB) and methylene blue (MB) under visible-light irradiation. The photocatalytic reaction follows a pseudo-first-order reaction and the rate constants for the degradation of RhB and MB by 3.5% g-C3N4/Ag2CO3 are about 2 times and 1.7 times that of pure Ag2CO3, respectively. A possible photocatalytic mechanism was proposed based on the photoluminescence (PL) spectra and a series of radical trapping experimental analyses. The remarkably improved photocatalytic performance should be ascribed to the heterostructure between Ag2CO3 and g-C3N4, which greatly promoted the photoinduced charge transfer and inhibited the recombination of electrons and holes.
format Article
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institution Kabale University
issn 1319-6103
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publishDate 2015-09-01
publisher Springer
record_format Article
series Journal of Saudi Chemical Society
spelling doaj-art-b83b08c5ef8d4336a70c3d689db6b49f2025-08-20T03:48:41ZengSpringerJournal of Saudi Chemical Society1319-61032015-09-0119546547010.1016/j.jscs.2015.07.002The hybridization of Ag2CO3 rods with g-C3N4 sheets with improved photocatalytic activityKonglin Wu0Yanwei Cui1Xianwen Wei2Xinjie Song3Jiarui Huang4College of Chemistry and Materials Science, Center for Nano Science and Technology, Anhui Normal University, Wuhu, Anhui 241000, People’s Republic of ChinaCollege of Chemistry and Materials Science, Center for Nano Science and Technology, Anhui Normal University, Wuhu, Anhui 241000, People’s Republic of ChinaCollege of Chemistry and Materials Science, Center for Nano Science and Technology, Anhui Normal University, Wuhu, Anhui 241000, People’s Republic of ChinaDepartment of Food Science and Technology, Yeungnam University, Gyeongsan, Gyeongbuk 712749, Republic of KoreaCollege of Chemistry and Materials Science, Center for Nano Science and Technology, Anhui Normal University, Wuhu, Anhui 241000, People’s Republic of ChinaA series of graphitic carbon nitride/silver carbonate (g-C3N4/Ag2CO3) rod-like composites with different weight contents of g-C3N4 have been prepared by a facile precipitation method. The g-C3N4/Ag2CO3 rod-like composites exhibited higher photocatalytic activity than pure Ag2CO3 toward degradation of rhodamine B (RhB) and methylene blue (MB) under visible-light irradiation. The photocatalytic reaction follows a pseudo-first-order reaction and the rate constants for the degradation of RhB and MB by 3.5% g-C3N4/Ag2CO3 are about 2 times and 1.7 times that of pure Ag2CO3, respectively. A possible photocatalytic mechanism was proposed based on the photoluminescence (PL) spectra and a series of radical trapping experimental analyses. The remarkably improved photocatalytic performance should be ascribed to the heterostructure between Ag2CO3 and g-C3N4, which greatly promoted the photoinduced charge transfer and inhibited the recombination of electrons and holes.http://www.sciencedirect.com/science/article/pii/S1319610315000903Ag2CO3g-C3N4CompositeVisible-lightPhotocatalysis
spellingShingle Konglin Wu
Yanwei Cui
Xianwen Wei
Xinjie Song
Jiarui Huang
The hybridization of Ag2CO3 rods with g-C3N4 sheets with improved photocatalytic activity
Journal of Saudi Chemical Society
Ag2CO3
g-C3N4
Composite
Visible-light
Photocatalysis
title The hybridization of Ag2CO3 rods with g-C3N4 sheets with improved photocatalytic activity
title_full The hybridization of Ag2CO3 rods with g-C3N4 sheets with improved photocatalytic activity
title_fullStr The hybridization of Ag2CO3 rods with g-C3N4 sheets with improved photocatalytic activity
title_full_unstemmed The hybridization of Ag2CO3 rods with g-C3N4 sheets with improved photocatalytic activity
title_short The hybridization of Ag2CO3 rods with g-C3N4 sheets with improved photocatalytic activity
title_sort hybridization of ag2co3 rods with g c3n4 sheets with improved photocatalytic activity
topic Ag2CO3
g-C3N4
Composite
Visible-light
Photocatalysis
url http://www.sciencedirect.com/science/article/pii/S1319610315000903
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