Proton-conducting membranes based on CsH2PO4 and copolymer of tetrafluoroethylene with vinylidene fluoride
In this work, proton conductivity, morphology and mechanical properties of (1–x)CsH2PO4–xF-42 (x=0.05–0.3, weight ratio) membranes were investigated for the first time. Thin flexible membranes for x≥0.15 with the uniform distribution of the components were obtained by a tape casting method. Mechanic...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Ural Federal University
2022-07-01
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| Series: | Chimica Techno Acta |
| Subjects: | |
| Online Access: | https://chimicatechnoacta.ru/article/view/6026 |
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| Summary: | In this work, proton conductivity, morphology and mechanical properties of (1–x)CsH2PO4–xF-42 (x=0.05–0.3, weight ratio) membranes were investigated for the first time. Thin flexible membranes for x≥0.15 with the uniform distribution of the components were obtained by a tape casting method. Mechanical properties of the membranes were measured by Vickers microhardness tests for a low polymer content (x˂0.15), also the tensile strength for membranes with high polymer content x=0.2–0.3 were evaluated. Proton conductivity of the (1–x)CsH2PO4–xpF-42 composite polymer electrolytes decreases monotonically with increasing x due to the effect of a «conductor-insulator» percolation. The combination of conductivity, mechanical strength and hydrophobic properties of (1–x)CsH2PO4–xF-42 makes certain compositions of proton-conducting membranes (x~0.2–0.25) promising for their use in intermediate-temperature fuel cells, despite decreased conductivity. |
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| ISSN: | 2411-1414 |