Mercury Deposition in South China Across the Ordovician‐Silurian Transition: Implications for Climate Change

Abstract Most of the global climate changes are closely associated with volcanic activity. However, the link between global cooling during the Ordovician‐Silurian (O‐S) transition and volcanism remains unclear due to limited constraints on large volcanic events before, during, and after the peak of...

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Main Authors: Weiliang Kong, Zhen Qiu, Jiaqiang Zhang, Wen Liu, Qin Zhang
Format: Article
Language:English
Published: Wiley 2025-07-01
Series:Geochemistry, Geophysics, Geosystems
Online Access:https://doi.org/10.1029/2024GC012122
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author Weiliang Kong
Zhen Qiu
Jiaqiang Zhang
Wen Liu
Qin Zhang
author_facet Weiliang Kong
Zhen Qiu
Jiaqiang Zhang
Wen Liu
Qin Zhang
author_sort Weiliang Kong
collection DOAJ
description Abstract Most of the global climate changes are closely associated with volcanic activity. However, the link between global cooling during the Ordovician‐Silurian (O‐S) transition and volcanism remains unclear due to limited constraints on large volcanic events before, during, and after the peak of the Hirnantian glaciation (PHG). Here, we present high‐resolution mercury (Hg) concentrations and isotopes from South China across the O‐S transition to assess volcanic activity and its contributions to climate changes. Anomalous Hg enrichments and volcanic‐range Hg isotopes in samples above volcanic ash layers confirm the effectiveness of Hg as a tracer of volcanic events. Variations in Hg isotopes across the O‐S transition reveal multiple Hg sources related to volcanic activity, that is, dominant volcanic Hg input during pre‐PHG and post‐PHG‐2, deposition of volcanic‐sourced atmospheric Hg(II) to seawater during PHG, and increased terrestrial Hg input from enhanced weathering during post‐PHG‐1. We propose that prolonged global cooling was driven by an albedo catastrophe caused by volcanic aerosols and sustained by reduced atmospheric CO2 levels due to enhanced organic carbon burial and weathering. This study highlights Hg as a tracer of volcanic activity and provides new evidence on the role of volcanism in driving climate changes across the O‐S transition.
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institution Kabale University
issn 1525-2027
language English
publishDate 2025-07-01
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series Geochemistry, Geophysics, Geosystems
spelling doaj-art-b77f1ee2db0247cf90a231d8c073d5672025-08-20T03:58:41ZengWileyGeochemistry, Geophysics, Geosystems1525-20272025-07-01267n/an/a10.1029/2024GC012122Mercury Deposition in South China Across the Ordovician‐Silurian Transition: Implications for Climate ChangeWeiliang Kong0Zhen Qiu1Jiaqiang Zhang2Wen Liu3Qin Zhang4Research Institute of Petroleum Exploration & Development China National Petroleum Corporation Beijing ChinaResearch Institute of Petroleum Exploration & Development China National Petroleum Corporation Beijing ChinaResearch Institute of Petroleum Exploration & Development China National Petroleum Corporation Beijing ChinaResearch Institute of Petroleum Exploration & Development China National Petroleum Corporation Beijing ChinaResearch Institute of Petroleum Exploration & Development China National Petroleum Corporation Beijing ChinaAbstract Most of the global climate changes are closely associated with volcanic activity. However, the link between global cooling during the Ordovician‐Silurian (O‐S) transition and volcanism remains unclear due to limited constraints on large volcanic events before, during, and after the peak of the Hirnantian glaciation (PHG). Here, we present high‐resolution mercury (Hg) concentrations and isotopes from South China across the O‐S transition to assess volcanic activity and its contributions to climate changes. Anomalous Hg enrichments and volcanic‐range Hg isotopes in samples above volcanic ash layers confirm the effectiveness of Hg as a tracer of volcanic events. Variations in Hg isotopes across the O‐S transition reveal multiple Hg sources related to volcanic activity, that is, dominant volcanic Hg input during pre‐PHG and post‐PHG‐2, deposition of volcanic‐sourced atmospheric Hg(II) to seawater during PHG, and increased terrestrial Hg input from enhanced weathering during post‐PHG‐1. We propose that prolonged global cooling was driven by an albedo catastrophe caused by volcanic aerosols and sustained by reduced atmospheric CO2 levels due to enhanced organic carbon burial and weathering. This study highlights Hg as a tracer of volcanic activity and provides new evidence on the role of volcanism in driving climate changes across the O‐S transition.https://doi.org/10.1029/2024GC012122
spellingShingle Weiliang Kong
Zhen Qiu
Jiaqiang Zhang
Wen Liu
Qin Zhang
Mercury Deposition in South China Across the Ordovician‐Silurian Transition: Implications for Climate Change
Geochemistry, Geophysics, Geosystems
title Mercury Deposition in South China Across the Ordovician‐Silurian Transition: Implications for Climate Change
title_full Mercury Deposition in South China Across the Ordovician‐Silurian Transition: Implications for Climate Change
title_fullStr Mercury Deposition in South China Across the Ordovician‐Silurian Transition: Implications for Climate Change
title_full_unstemmed Mercury Deposition in South China Across the Ordovician‐Silurian Transition: Implications for Climate Change
title_short Mercury Deposition in South China Across the Ordovician‐Silurian Transition: Implications for Climate Change
title_sort mercury deposition in south china across the ordovician silurian transition implications for climate change
url https://doi.org/10.1029/2024GC012122
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AT jiaqiangzhang mercurydepositioninsouthchinaacrosstheordoviciansiluriantransitionimplicationsforclimatechange
AT wenliu mercurydepositioninsouthchinaacrosstheordoviciansiluriantransitionimplicationsforclimatechange
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