Green synthesis and antifungal activities of benzothiazole derivatives containing α-trifluoromethyl tertiary alcohol and coumarin moiety

A series of benzothiazole derivatives containing α-trifluoromethyl tertiary alcohol and coumarin moiety were synthesized via the reaction of 2-methylbenzo[d]thiazole and 3-(trifluoroacetyl)coumarin with high yields under catalyst-free and green solvent. The structures of products were validated thro...

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Bibliographic Details
Main Authors: Shengfei Jiang, Jianqi Xu, Zhuang Wu, Lulu Wu, Zhenliang Pan, Guoyu Yang, Lijun Shi, Liangxin Fan, Cuilian Xu
Format: Article
Language:English
Published: Elsevier 2025-07-01
Series:Results in Chemistry
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Online Access:http://www.sciencedirect.com/science/article/pii/S2211715625003704
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Summary:A series of benzothiazole derivatives containing α-trifluoromethyl tertiary alcohol and coumarin moiety were synthesized via the reaction of 2-methylbenzo[d]thiazole and 3-(trifluoroacetyl)coumarin with high yields under catalyst-free and green solvent. The structures of products were validated through 1H NMR, 13C NMR, HRMS and X-Ray analysis. Meanwhile, the inhibition activity against five common plant pathogenic fungi: Rhizoctonia solani, Fusarium moniliforme, Phytophthora parasitica, Fusarium graminearum and Fusarium oxysporum, was evaluated in vitro at 200 μg/mL. The results obtained from the bioassay signified that all products possessed significant antifungal effect against Rhizoctonia solani compared to other four fungi.
ISSN:2211-7156