Formation Kinetics and Morphology Characteristics of Natural Gas Hydrates in Sandstone Fractures
Fractures in marine sediments are critical zones for hydrate formation. The kinetics and morphological characteristics of hydrates within sandstone fractures are comprehensively investigated in this study by employing a high-pressure visualization reaction vessel to examine their formation, dissocia...
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2025-07-01
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| author | Chaozheng Ma Xiaoxu Hu Hongxiang Si Jiyao Wang Juntao Pan Tingting Luo Tao Han Aowang Wang |
| author_facet | Chaozheng Ma Xiaoxu Hu Hongxiang Si Jiyao Wang Juntao Pan Tingting Luo Tao Han Aowang Wang |
| author_sort | Chaozheng Ma |
| collection | DOAJ |
| description | Fractures in marine sediments are critical zones for hydrate formation. The kinetics and morphological characteristics of hydrates within sandstone fractures are comprehensively investigated in this study by employing a high-pressure visualization reaction vessel to examine their formation, dissociation, and reformation processes. The results are presented below: (1) In 3 mm Type I fractures, the induction time is longer than that observed in the other two fracture widths. Hydrates predominantly form on the fracture walls and gradually expand toward both sides of the fracture. (2) Gas enters the fracture from multiple directions, causing the hydrate in Type X fractures to expand toward the center from all sides, which shortens the induction time and increases the quantity of hydrate formation. (3) An increase in fracture roughness promotes nucleation of the hydrate at surface protrusions but inhibits the total quantity of hydrate formation. (4) Hydrate dissociation typically propagates from the fracture wall into the interior, exhibiting a wavy surface morphology. Gas production is influenced by the fracture width, with the highest gas production observed in a 3 mm fracture. (5) Due to the memory effect, the hydrate induction time for reformation is significantly shorter, though the quantity of hydrate formed is lower than that of the first formation. This study aims to provide micro-level insights into the distribution of hydrates in sandstone fractures, thereby facilitating more efficient and safe extraction of hydrates from fractures. |
| format | Article |
| id | doaj-art-b589261878fc4e958bfbf13c57b0fb6b |
| institution | DOAJ |
| issn | 2076-3417 |
| language | English |
| publishDate | 2025-07-01 |
| publisher | MDPI AG |
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| spelling | doaj-art-b589261878fc4e958bfbf13c57b0fb6b2025-08-20T03:16:43ZengMDPI AGApplied Sciences2076-34172025-07-011513739910.3390/app15137399Formation Kinetics and Morphology Characteristics of Natural Gas Hydrates in Sandstone FracturesChaozheng Ma0Xiaoxu Hu1Hongxiang Si2Jiyao Wang3Juntao Pan4Tingting Luo5Tao Han6Aowang Wang7State Key Laboratory of Intelligent Construction and Healthy Operation & Maintenance of Deep Underground Engineering, School of Mechanics and Civil Engineering, China University of Mining and Technology, Xuzhou 221116, ChinaXinwen Mining Group Co., Ltd., Tai’an 271233, ChinaXinwen Mining Group Co., Ltd., Tai’an 271233, ChinaKey Laboratory of Coalbed Methane Resources and Reservoir Formation Process of the Ministry of Education, School of Resources and Geosciences, China University of Mining and Technology, Xuzhou 221116, ChinaState Key Laboratory of Intelligent Construction and Healthy Operation & Maintenance of Deep Underground Engineering, School of Mechanics and Civil Engineering, China University of Mining and Technology, Xuzhou 221116, ChinaState Key Laboratory of Intelligent Construction and Healthy Operation & Maintenance of Deep Underground Engineering, School of Mechanics and Civil Engineering, China University of Mining and Technology, Xuzhou 221116, ChinaState Key Laboratory of Intelligent Construction and Healthy Operation & Maintenance of Deep Underground Engineering, School of Mechanics and Civil Engineering, China University of Mining and Technology, Xuzhou 221116, ChinaState Key Laboratory of Intelligent Construction and Healthy Operation & Maintenance of Deep Underground Engineering, School of Mechanics and Civil Engineering, China University of Mining and Technology, Xuzhou 221116, ChinaFractures in marine sediments are critical zones for hydrate formation. The kinetics and morphological characteristics of hydrates within sandstone fractures are comprehensively investigated in this study by employing a high-pressure visualization reaction vessel to examine their formation, dissociation, and reformation processes. The results are presented below: (1) In 3 mm Type I fractures, the induction time is longer than that observed in the other two fracture widths. Hydrates predominantly form on the fracture walls and gradually expand toward both sides of the fracture. (2) Gas enters the fracture from multiple directions, causing the hydrate in Type X fractures to expand toward the center from all sides, which shortens the induction time and increases the quantity of hydrate formation. (3) An increase in fracture roughness promotes nucleation of the hydrate at surface protrusions but inhibits the total quantity of hydrate formation. (4) Hydrate dissociation typically propagates from the fracture wall into the interior, exhibiting a wavy surface morphology. Gas production is influenced by the fracture width, with the highest gas production observed in a 3 mm fracture. (5) Due to the memory effect, the hydrate induction time for reformation is significantly shorter, though the quantity of hydrate formed is lower than that of the first formation. This study aims to provide micro-level insights into the distribution of hydrates in sandstone fractures, thereby facilitating more efficient and safe extraction of hydrates from fractures.https://www.mdpi.com/2076-3417/15/13/7399natural gas hydratesandstone fracturesformation kineticmorphology |
| spellingShingle | Chaozheng Ma Xiaoxu Hu Hongxiang Si Jiyao Wang Juntao Pan Tingting Luo Tao Han Aowang Wang Formation Kinetics and Morphology Characteristics of Natural Gas Hydrates in Sandstone Fractures Applied Sciences natural gas hydrate sandstone fractures formation kinetic morphology |
| title | Formation Kinetics and Morphology Characteristics of Natural Gas Hydrates in Sandstone Fractures |
| title_full | Formation Kinetics and Morphology Characteristics of Natural Gas Hydrates in Sandstone Fractures |
| title_fullStr | Formation Kinetics and Morphology Characteristics of Natural Gas Hydrates in Sandstone Fractures |
| title_full_unstemmed | Formation Kinetics and Morphology Characteristics of Natural Gas Hydrates in Sandstone Fractures |
| title_short | Formation Kinetics and Morphology Characteristics of Natural Gas Hydrates in Sandstone Fractures |
| title_sort | formation kinetics and morphology characteristics of natural gas hydrates in sandstone fractures |
| topic | natural gas hydrate sandstone fractures formation kinetic morphology |
| url | https://www.mdpi.com/2076-3417/15/13/7399 |
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