Effect of Zn content on corrosion behavior of Mg-Y-Zn alloys

The microstructure, corrosion behavior, and electrochemical behavior of as-cast Mg-4Y-xZn (x=1,2,3,4 wt.%) are studied by SEM, weight loss and electrochemical tests. Mg12YZn (X), Mg3Y2Zn3 (W) and Mg24Y5 constitute the phase composition system of the alloy. When Zn content is 1 wt.%, all tests reveal...

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Main Authors: Shi Y., Liu X.-Q., Liu Z.-L., Xie H.-J., Wang Y.-H., Li J.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2022-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
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Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2022/1450-53392100048S.pdf
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author Shi Y.
Liu X.-Q.
Liu Z.-L.
Xie H.-J.
Wang Y.-H.
Li J.
author_facet Shi Y.
Liu X.-Q.
Liu Z.-L.
Xie H.-J.
Wang Y.-H.
Li J.
author_sort Shi Y.
collection DOAJ
description The microstructure, corrosion behavior, and electrochemical behavior of as-cast Mg-4Y-xZn (x=1,2,3,4 wt.%) are studied by SEM, weight loss and electrochemical tests. Mg12YZn (X), Mg3Y2Zn3 (W) and Mg24Y5 constitute the phase composition system of the alloy. When Zn content is 1 wt.%, all tests reveal that alloy has the optimal corrosion performance. The second phase in these alloys, due to their nobler nature than α-Mg, exists as a cathode during the corrosion process, so that α-Mg preferentially occurs corrosion to accelerate the formation of corrosion pits. After soaking in 3.5 wt.% NaCl solution for some time, the stability of the W phase changed, and gradually dissolved, which was finally removed by chromic acid used for removal of corrosion products. In addition, X phase can be used as an anode in the micro-galvanic cells formed with W phase to reduce the corrosion rate of α-Mg and thus improve the corrosion performance of the alloy.
format Article
id doaj-art-b50d8afac0dd490aae569f619b089412
institution Kabale University
issn 1450-5339
2217-7175
language English
publishDate 2022-01-01
publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-b50d8afac0dd490aae569f619b0894122025-02-02T00:42:48ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392217-71752022-01-01581516110.2298/JMMB210525048S1450-53392100048SEffect of Zn content on corrosion behavior of Mg-Y-Zn alloysShi Y.0Liu X.-Q.1Liu Z.-L.2Xie H.-J.3Wang Y.-H.4Li J.5College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu, ChinaCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu, China + Jiangsu (Zhongyi) Engineering Research Center of Light Alloy Precision Die Casting, Changshu, Jiangsu, ChinaCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu, China + Jiangsu (Zhongyi) Engineering Research Center of Light Alloy Precision Die Casting, Changshu, Jiangsu, ChinaCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu, ChinaCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu, ChinaJiangsu (Zhongyi) Engineering Research Center of Light Alloy Precision Die Casting, Changshu, Jiangsu, China + Jiangsu Favour Automotive New Stuff Sci‐Tech Co., Ltd., Changshu, ChinaThe microstructure, corrosion behavior, and electrochemical behavior of as-cast Mg-4Y-xZn (x=1,2,3,4 wt.%) are studied by SEM, weight loss and electrochemical tests. Mg12YZn (X), Mg3Y2Zn3 (W) and Mg24Y5 constitute the phase composition system of the alloy. When Zn content is 1 wt.%, all tests reveal that alloy has the optimal corrosion performance. The second phase in these alloys, due to their nobler nature than α-Mg, exists as a cathode during the corrosion process, so that α-Mg preferentially occurs corrosion to accelerate the formation of corrosion pits. After soaking in 3.5 wt.% NaCl solution for some time, the stability of the W phase changed, and gradually dissolved, which was finally removed by chromic acid used for removal of corrosion products. In addition, X phase can be used as an anode in the micro-galvanic cells formed with W phase to reduce the corrosion rate of α-Mg and thus improve the corrosion performance of the alloy.http://www.doiserbia.nb.rs/img/doi/1450-5339/2022/1450-53392100048S.pdfmg-y-znsecond phasecorrosion behaviorselectrochemical behaviors
spellingShingle Shi Y.
Liu X.-Q.
Liu Z.-L.
Xie H.-J.
Wang Y.-H.
Li J.
Effect of Zn content on corrosion behavior of Mg-Y-Zn alloys
Journal of Mining and Metallurgy. Section B: Metallurgy
mg-y-zn
second phase
corrosion behaviors
electrochemical behaviors
title Effect of Zn content on corrosion behavior of Mg-Y-Zn alloys
title_full Effect of Zn content on corrosion behavior of Mg-Y-Zn alloys
title_fullStr Effect of Zn content on corrosion behavior of Mg-Y-Zn alloys
title_full_unstemmed Effect of Zn content on corrosion behavior of Mg-Y-Zn alloys
title_short Effect of Zn content on corrosion behavior of Mg-Y-Zn alloys
title_sort effect of zn content on corrosion behavior of mg y zn alloys
topic mg-y-zn
second phase
corrosion behaviors
electrochemical behaviors
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2022/1450-53392100048S.pdf
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AT xiehj effectofzncontentoncorrosionbehaviorofmgyznalloys
AT wangyh effectofzncontentoncorrosionbehaviorofmgyznalloys
AT lij effectofzncontentoncorrosionbehaviorofmgyznalloys