Organophotoredox-Catalyzed Stereoselective Synthesis of Bicyclo[3.2.0]heptanes via [2+2] Photocycloaddition

Organophotoredox-Catalyzed Stereoselective Synthesis of Bicyclo[3.2.0]heptanes via [2+2] Photocycloaddition

The stereoselective synthesis of bicyclo[3.2.0]heptanes via an anion radical [2+2] photocycloaddition of aryl bis-enone derivatives was investigated. By employing chiral oxazolidinone auxiliaries bound to aryl bis-enone substrates, enantioenriched, highly substituted bicyclo[3.2.0]heptanes have been...

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Bibliographic Details
Main Authors: Tommaso Benettin, Simonetta Resta, Alessandra Forni, Laura Raimondi, Alessandra Puglisi, Sergio Rossi
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Molecules
Subjects:
photocatalysis
[2+2] photocycloaddition
Eosin Y
stereoselective synthesis
aryl bis-enones
bicyclo[3.2.0]heptanes
Online Access:https://www.mdpi.com/1420-3049/30/10/2090
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