Efficacy of Andrographis paniculata leaf extract as a green corrosion inhibitor for mild steel in concentrated sulfuric acid: Experimental and computational insights

The rising demand for eco-friendly corrosion inhibitors has intensified efforts to find sustainable alternatives to hazardous chemical inhibitors widely used in industry. Mild steel, although commonly utilized in acidic environments, is prone to significant corrosion, necessitating effective solutio...

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Main Authors: Femiana Gapsari, Putu H. Setyarini, Khairul Anam, Saprizal Hadisaputra, Syarif Hidayatullah, Purnami, Abdul Mudjib Sulaiman, Chin Wei Lai
Format: Article
Language:English
Published: Elsevier 2025-01-01
Series:Results in Surfaces and Interfaces
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666845924001818
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author Femiana Gapsari
Putu H. Setyarini
Khairul Anam
Saprizal Hadisaputra
Syarif Hidayatullah
Purnami
Abdul Mudjib Sulaiman
Chin Wei Lai
author_facet Femiana Gapsari
Putu H. Setyarini
Khairul Anam
Saprizal Hadisaputra
Syarif Hidayatullah
Purnami
Abdul Mudjib Sulaiman
Chin Wei Lai
author_sort Femiana Gapsari
collection DOAJ
description The rising demand for eco-friendly corrosion inhibitors has intensified efforts to find sustainable alternatives to hazardous chemical inhibitors widely used in industry. Mild steel, although commonly utilized in acidic environments, is prone to significant corrosion, necessitating effective solutions to prevent structural degradation. This study investigates the potential of Andrographis paniculata leaf extract (APLE) as a sustainable, green corrosion inhibitor for mild steel in concentrated sulfuric acid, a condition representative of harsh industrial environments. Using electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PDP) methods, APLE demonstrated a high inhibition efficiency of 95.14% at a concentration of 4000 ppm, effectively reducing both anodic and cathodic corrosion reactions. Scanning electron microscopy (SEM) revealed a protective layer formation on the steel surface, significantly reducing corrosion. The adsorption of APLE followed the Langmuir isotherm, indicating monolayer coverage, while quantum chemical calculations validated APLE's electron-donating capability, enhancing surface stability through physisorption. These findings underscore APLE as a viable, eco-friendly alternative to conventional inhibitors, offering promising applications in various acidic environments.
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spelling doaj-art-b4e0132425654ab08b7f14ed75df21162025-08-20T02:53:12ZengElsevierResults in Surfaces and Interfaces2666-84592025-01-011810036110.1016/j.rsurfi.2024.100361Efficacy of Andrographis paniculata leaf extract as a green corrosion inhibitor for mild steel in concentrated sulfuric acid: Experimental and computational insightsFemiana Gapsari0Putu H. Setyarini1Khairul Anam2Saprizal Hadisaputra3Syarif Hidayatullah4 Purnami5Abdul Mudjib Sulaiman6Chin Wei Lai7Department of Mechanical Engineering, Faculty of Engineering, Brawijaya University, MT Haryono 167, Malang, 65145, Indonesia; Corresponding author.Department of Mechanical Engineering, Faculty of Engineering, Brawijaya University, MT Haryono 167, Malang, 65145, IndonesiaDepartment of Mechanical Engineering, Faculty of Engineering, Brawijaya University, MT Haryono 167, Malang, 65145, IndonesiaChemistry Education Division, University of Mataram, Jalan Majapahit No 62, Mataram, 83125, IndonesiaDepartment of Mechanical Engineering, Faculty of Engineering, University of Mataram, Jalan Majapahit No 62, Mataram, 83125, IndonesiaDepartment of Mechanical Engineering, Faculty of Engineering, Brawijaya University, MT Haryono 167, Malang, 65145, IndonesiaDepartment of Mechanical Engineering, Faculty of Engineering, Brawijaya University, MT Haryono 167, Malang, 65145, Indonesia; Department of Mechanical and Industrial Engineering, Universitas Gadjah Mada, Jalan Grafika No. 2, Yogyakarta, 55281, IndonesiaNanotechnology and Catalysis Research Centre, Institute for Advanced Studies, Universiti Malaya, Level 3, Block A, Kuala Lumpur, 50603, MalaysiaThe rising demand for eco-friendly corrosion inhibitors has intensified efforts to find sustainable alternatives to hazardous chemical inhibitors widely used in industry. Mild steel, although commonly utilized in acidic environments, is prone to significant corrosion, necessitating effective solutions to prevent structural degradation. This study investigates the potential of Andrographis paniculata leaf extract (APLE) as a sustainable, green corrosion inhibitor for mild steel in concentrated sulfuric acid, a condition representative of harsh industrial environments. Using electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PDP) methods, APLE demonstrated a high inhibition efficiency of 95.14% at a concentration of 4000 ppm, effectively reducing both anodic and cathodic corrosion reactions. Scanning electron microscopy (SEM) revealed a protective layer formation on the steel surface, significantly reducing corrosion. The adsorption of APLE followed the Langmuir isotherm, indicating monolayer coverage, while quantum chemical calculations validated APLE's electron-donating capability, enhancing surface stability through physisorption. These findings underscore APLE as a viable, eco-friendly alternative to conventional inhibitors, offering promising applications in various acidic environments.http://www.sciencedirect.com/science/article/pii/S2666845924001818Andrographis paniculate leaf extract (APLE)CorrosionConcentrated acidInhibitor
spellingShingle Femiana Gapsari
Putu H. Setyarini
Khairul Anam
Saprizal Hadisaputra
Syarif Hidayatullah
Purnami
Abdul Mudjib Sulaiman
Chin Wei Lai
Efficacy of Andrographis paniculata leaf extract as a green corrosion inhibitor for mild steel in concentrated sulfuric acid: Experimental and computational insights
Results in Surfaces and Interfaces
Andrographis paniculate leaf extract (APLE)
Corrosion
Concentrated acid
Inhibitor
title Efficacy of Andrographis paniculata leaf extract as a green corrosion inhibitor for mild steel in concentrated sulfuric acid: Experimental and computational insights
title_full Efficacy of Andrographis paniculata leaf extract as a green corrosion inhibitor for mild steel in concentrated sulfuric acid: Experimental and computational insights
title_fullStr Efficacy of Andrographis paniculata leaf extract as a green corrosion inhibitor for mild steel in concentrated sulfuric acid: Experimental and computational insights
title_full_unstemmed Efficacy of Andrographis paniculata leaf extract as a green corrosion inhibitor for mild steel in concentrated sulfuric acid: Experimental and computational insights
title_short Efficacy of Andrographis paniculata leaf extract as a green corrosion inhibitor for mild steel in concentrated sulfuric acid: Experimental and computational insights
title_sort efficacy of andrographis paniculata leaf extract as a green corrosion inhibitor for mild steel in concentrated sulfuric acid experimental and computational insights
topic Andrographis paniculate leaf extract (APLE)
Corrosion
Concentrated acid
Inhibitor
url http://www.sciencedirect.com/science/article/pii/S2666845924001818
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