SYNTHESIS AND CRYSTAL STRUCTURE OF [PPh ] [WOS (CUNCS) ]
The reaction of [PPhJ, NOS,] with CuCl and KSCN (1 :3:3) in acetone produces the yell-ow crystals of [PPh,], [WOS,(CuNCS),]. The crystals are triclinic, space group P1(2), z=2, a=12.4823(7), b=12.9224(7), c=18.6395(10)?, ?=83.907(5), ?= 73.152(4), Y= 65.194(4)'. The crystal structure was determ...
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| Format: | Article |
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| Language: | English |
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University of Tehran
1996-12-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
| Online Access: | https://jsciences.ut.ac.ir/article_31132_d85b7e3a0003a3c9cf42a2f23014bbd4.pdf |
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| description | The reaction of [PPhJ, NOS,] with CuCl and KSCN (1 :3:3) in acetone produces
the yell-ow crystals of [PPh,], [WOS,(CuNCS),]. The crystals are triclinic, space
group P1(2), z=2, a=12.4823(7), b=12.9224(7), c=18.6395(10)?, ?=83.907(5), ?=
73.152(4), Y= 65.194(4)'. The crystal structure was determined by single crystal Xray diffraction methods (Mo-K ?) and refined by least-squares calculations to a final R-value of 0.062 (R = 0.081) for 1851 unique observed reflections [F>3?|F|]. In [WOS (CuNCS) ] anion the tungsten and copper atoms have essentially a tetrahedral and trigonal planar co-ordination geometry respectively |
| format | Article |
| id | doaj-art-b4beb93ebde241aca74241b062e56e8f |
| institution | OA Journals |
| issn | 1016-1104 2345-6914 |
| language | English |
| publishDate | 1996-12-01 |
| publisher | University of Tehran |
| record_format | Article |
| series | Journal of Sciences, Islamic Republic of Iran |
| spelling | doaj-art-b4beb93ebde241aca74241b062e56e8f2025-08-20T02:25:51ZengUniversity of TehranJournal of Sciences, Islamic Republic of Iran1016-11042345-69141996-12-017431132SYNTHESIS AND CRYSTAL STRUCTURE OF [PPh ] [WOS (CUNCS) ]The reaction of [PPhJ, NOS,] with CuCl and KSCN (1 :3:3) in acetone produces the yell-ow crystals of [PPh,], [WOS,(CuNCS),]. The crystals are triclinic, space group P1(2), z=2, a=12.4823(7), b=12.9224(7), c=18.6395(10)?, ?=83.907(5), ?= 73.152(4), Y= 65.194(4)'. The crystal structure was determined by single crystal Xray diffraction methods (Mo-K ?) and refined by least-squares calculations to a final R-value of 0.062 (R = 0.081) for 1851 unique observed reflections [F>3?|F|]. In [WOS (CuNCS) ] anion the tungsten and copper atoms have essentially a tetrahedral and trigonal planar co-ordination geometry respectivelyhttps://jsciences.ut.ac.ir/article_31132_d85b7e3a0003a3c9cf42a2f23014bbd4.pdf |
| spellingShingle | SYNTHESIS AND CRYSTAL STRUCTURE OF
[PPh ] [WOS (CUNCS) ] Journal of Sciences, Islamic Republic of Iran |
| title | SYNTHESIS AND CRYSTAL STRUCTURE OF
[PPh ] [WOS (CUNCS) ] |
| title_full | SYNTHESIS AND CRYSTAL STRUCTURE OF
[PPh ] [WOS (CUNCS) ] |
| title_fullStr | SYNTHESIS AND CRYSTAL STRUCTURE OF
[PPh ] [WOS (CUNCS) ] |
| title_full_unstemmed | SYNTHESIS AND CRYSTAL STRUCTURE OF
[PPh ] [WOS (CUNCS) ] |
| title_short | SYNTHESIS AND CRYSTAL STRUCTURE OF
[PPh ] [WOS (CUNCS) ] |
| title_sort | synthesis and crystal structure of pph wos cuncs |
| url | https://jsciences.ut.ac.ir/article_31132_d85b7e3a0003a3c9cf42a2f23014bbd4.pdf |