Exploring of spectroscopic, dielectric, and bioactivity performance of bioglass/sodium alginate-PVP loaded-Amoxicillin/Clavulanic Acid microspheres for bone tissue engineering

Abstract This study aims to develop an innovative drug delivery bio-system using bioglass (BIOGLASS) and biopolymers of Sodium Alginate (SA) and polyvinylpyrrolidone (PVP) in microsphere form as a carrier for Amoxicillin/Clavulanic Acid drug. In this work BIOGLASS/SA-PVP and Amoxicillin/Clavulanic A...

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Main Authors: Ahmed M. Bakr, Amany M. El Nahrawy, A. M. Mansour, Ali B. Abou Hammad
Format: Article
Language:English
Published: Nature Portfolio 2025-05-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-025-96590-7
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author Ahmed M. Bakr
Amany M. El Nahrawy
A. M. Mansour
Ali B. Abou Hammad
author_facet Ahmed M. Bakr
Amany M. El Nahrawy
A. M. Mansour
Ali B. Abou Hammad
author_sort Ahmed M. Bakr
collection DOAJ
description Abstract This study aims to develop an innovative drug delivery bio-system using bioglass (BIOGLASS) and biopolymers of Sodium Alginate (SA) and polyvinylpyrrolidone (PVP) in microsphere form as a carrier for Amoxicillin/Clavulanic Acid drug. In this work BIOGLASS/SA-PVP and Amoxicillin/Clavulanic Acid loaded BIOGLASS/SA-PVP microspheres (0%, 5%, 10%, and 15%) were synthesized using the ion crosslinking method technique. The fabricated microspheres were analyzed using FT-IR, FESEM/EDX, and XRD confirming the in-vitro examination. XRD and FTIR data demonstrate the effective creation of the apatite layer and the appearance of new apatite peaks at both 605 cm−1 and 565 cm−1, distinguishing the prolonged vibrations associated with the $${\text{PO}}_{4}^{-3}$$ group. SEM images reveal that the prepared bio-beads have a spherical shape, with sizes falling in the micro-scale. The dielectric constant (εʹ), the dielectric loss (εʺ), and the AC conductivity (σ) were slow at the frequency range of 4 Hz to 8 MHz at room temperature. The antibacterial examinations of the fabricated microspheres were performed employing agar diffusion procedure against the clinical pathogens Gram+ and Gram- bacteria. The SBF (simulated body fluid) experiments display the formation of a hydroxy appetite coating on the microsphere’s surfaces that approves their significant bioactivity. Furthermore, antimicrobial results of BIOGLASS/SA-PVP/Amoxicillin/Clavulanic Acid microspheres reveal a notable impact on the antimicrobial performance. The in-vitro tests established that fabricated bio-microspheres are a promising opportunity for bone tissue engineering (substitutes and regeneration), signifying their promise for bone application.
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spelling doaj-art-b49ff56b955044edb63de9fde7be97fc2025-08-20T03:52:19ZengNature PortfolioScientific Reports2045-23222025-05-0115111910.1038/s41598-025-96590-7Exploring of spectroscopic, dielectric, and bioactivity performance of bioglass/sodium alginate-PVP loaded-Amoxicillin/Clavulanic Acid microspheres for bone tissue engineeringAhmed M. Bakr0Amany M. El Nahrawy1A. M. Mansour2Ali B. Abou Hammad3Spectroscopy Department, Physics Research Institute, National Research CentreSolid State Physics Department, Physics Research Institute, National Research CentreSolid State Physics Department, Physics Research Institute, National Research CentreSolid State Physics Department, Physics Research Institute, National Research CentreAbstract This study aims to develop an innovative drug delivery bio-system using bioglass (BIOGLASS) and biopolymers of Sodium Alginate (SA) and polyvinylpyrrolidone (PVP) in microsphere form as a carrier for Amoxicillin/Clavulanic Acid drug. In this work BIOGLASS/SA-PVP and Amoxicillin/Clavulanic Acid loaded BIOGLASS/SA-PVP microspheres (0%, 5%, 10%, and 15%) were synthesized using the ion crosslinking method technique. The fabricated microspheres were analyzed using FT-IR, FESEM/EDX, and XRD confirming the in-vitro examination. XRD and FTIR data demonstrate the effective creation of the apatite layer and the appearance of new apatite peaks at both 605 cm−1 and 565 cm−1, distinguishing the prolonged vibrations associated with the $${\text{PO}}_{4}^{-3}$$ group. SEM images reveal that the prepared bio-beads have a spherical shape, with sizes falling in the micro-scale. The dielectric constant (εʹ), the dielectric loss (εʺ), and the AC conductivity (σ) were slow at the frequency range of 4 Hz to 8 MHz at room temperature. The antibacterial examinations of the fabricated microspheres were performed employing agar diffusion procedure against the clinical pathogens Gram+ and Gram- bacteria. The SBF (simulated body fluid) experiments display the formation of a hydroxy appetite coating on the microsphere’s surfaces that approves their significant bioactivity. Furthermore, antimicrobial results of BIOGLASS/SA-PVP/Amoxicillin/Clavulanic Acid microspheres reveal a notable impact on the antimicrobial performance. The in-vitro tests established that fabricated bio-microspheres are a promising opportunity for bone tissue engineering (substitutes and regeneration), signifying their promise for bone application.https://doi.org/10.1038/s41598-025-96590-7BioglassSodium alginatePVPAmoxicillin/Clavulanic AcidBioactivitySBF
spellingShingle Ahmed M. Bakr
Amany M. El Nahrawy
A. M. Mansour
Ali B. Abou Hammad
Exploring of spectroscopic, dielectric, and bioactivity performance of bioglass/sodium alginate-PVP loaded-Amoxicillin/Clavulanic Acid microspheres for bone tissue engineering
Scientific Reports
Bioglass
Sodium alginate
PVP
Amoxicillin/Clavulanic Acid
Bioactivity
SBF
title Exploring of spectroscopic, dielectric, and bioactivity performance of bioglass/sodium alginate-PVP loaded-Amoxicillin/Clavulanic Acid microspheres for bone tissue engineering
title_full Exploring of spectroscopic, dielectric, and bioactivity performance of bioglass/sodium alginate-PVP loaded-Amoxicillin/Clavulanic Acid microspheres for bone tissue engineering
title_fullStr Exploring of spectroscopic, dielectric, and bioactivity performance of bioglass/sodium alginate-PVP loaded-Amoxicillin/Clavulanic Acid microspheres for bone tissue engineering
title_full_unstemmed Exploring of spectroscopic, dielectric, and bioactivity performance of bioglass/sodium alginate-PVP loaded-Amoxicillin/Clavulanic Acid microspheres for bone tissue engineering
title_short Exploring of spectroscopic, dielectric, and bioactivity performance of bioglass/sodium alginate-PVP loaded-Amoxicillin/Clavulanic Acid microspheres for bone tissue engineering
title_sort exploring of spectroscopic dielectric and bioactivity performance of bioglass sodium alginate pvp loaded amoxicillin clavulanic acid microspheres for bone tissue engineering
topic Bioglass
Sodium alginate
PVP
Amoxicillin/Clavulanic Acid
Bioactivity
SBF
url https://doi.org/10.1038/s41598-025-96590-7
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