Modification of the Properties of Vanadium Oxide Thin Films by Plasma-Immersion Ion Implantation

The paper describes the effect of doping with hydrogen and tungsten by means of plasma-immersion ion implantation (PIII) on the properties of vanadium dioxide and hydrated vanadium pentoxide films. It is shown that the parameters of the metal-insulator phase transition in VO2 thin films depend on th...

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Main Authors: Sergey Burdyukh, Olga Berezina, Alexander Pergament
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:Advances in Condensed Matter Physics
Online Access:http://dx.doi.org/10.1155/2018/9789370
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author Sergey Burdyukh
Olga Berezina
Alexander Pergament
author_facet Sergey Burdyukh
Olga Berezina
Alexander Pergament
author_sort Sergey Burdyukh
collection DOAJ
description The paper describes the effect of doping with hydrogen and tungsten by means of plasma-immersion ion implantation (PIII) on the properties of vanadium dioxide and hydrated vanadium pentoxide films. It is shown that the parameters of the metal-insulator phase transition in VO2 thin films depend on the hydrogen implantation dose. Next, we explore the effect of PIII on composition, optical properties, and the internal electrochromic effect (IECE) in V2O5·nH2O films. The variations in the composition and structure caused by the hydrogen insertion, as well as those caused by the electrochromic effect, are studied by nuclear magnetic resonance, thermogravimetry, Raman spectroscopy, and X-ray structural analysis. It is shown that the ion implantation-induced hydrogenation can substantially enhance the manifestation and performance of the IECE in V2O5 xerogel films. Finally, the effect of PIII-assisted doping with W on the parameters of electrical switching in Au/V2O5·nH2O/Au sandwich structures is examined. It is shown that implanting small tungsten doses improves the switching parameters after forming. When implanting large doses, switching is observed without electroforming, and if electroforming is applied, the switching effect, on the contrary, disappears.
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spelling doaj-art-b4227577baad4d7dabb7587c553a0d382025-08-20T03:20:52ZengWileyAdvances in Condensed Matter Physics1687-81081687-81242018-01-01201810.1155/2018/97893709789370Modification of the Properties of Vanadium Oxide Thin Films by Plasma-Immersion Ion ImplantationSergey Burdyukh0Olga Berezina1Alexander Pergament2Institute of Physics and Technology, Petrozavodsk State University, Petrozavodsk 185910, RussiaInstitute of Physics and Technology, Petrozavodsk State University, Petrozavodsk 185910, RussiaInstitute of Physics and Technology, Petrozavodsk State University, Petrozavodsk 185910, RussiaThe paper describes the effect of doping with hydrogen and tungsten by means of plasma-immersion ion implantation (PIII) on the properties of vanadium dioxide and hydrated vanadium pentoxide films. It is shown that the parameters of the metal-insulator phase transition in VO2 thin films depend on the hydrogen implantation dose. Next, we explore the effect of PIII on composition, optical properties, and the internal electrochromic effect (IECE) in V2O5·nH2O films. The variations in the composition and structure caused by the hydrogen insertion, as well as those caused by the electrochromic effect, are studied by nuclear magnetic resonance, thermogravimetry, Raman spectroscopy, and X-ray structural analysis. It is shown that the ion implantation-induced hydrogenation can substantially enhance the manifestation and performance of the IECE in V2O5 xerogel films. Finally, the effect of PIII-assisted doping with W on the parameters of electrical switching in Au/V2O5·nH2O/Au sandwich structures is examined. It is shown that implanting small tungsten doses improves the switching parameters after forming. When implanting large doses, switching is observed without electroforming, and if electroforming is applied, the switching effect, on the contrary, disappears.http://dx.doi.org/10.1155/2018/9789370
spellingShingle Sergey Burdyukh
Olga Berezina
Alexander Pergament
Modification of the Properties of Vanadium Oxide Thin Films by Plasma-Immersion Ion Implantation
Advances in Condensed Matter Physics
title Modification of the Properties of Vanadium Oxide Thin Films by Plasma-Immersion Ion Implantation
title_full Modification of the Properties of Vanadium Oxide Thin Films by Plasma-Immersion Ion Implantation
title_fullStr Modification of the Properties of Vanadium Oxide Thin Films by Plasma-Immersion Ion Implantation
title_full_unstemmed Modification of the Properties of Vanadium Oxide Thin Films by Plasma-Immersion Ion Implantation
title_short Modification of the Properties of Vanadium Oxide Thin Films by Plasma-Immersion Ion Implantation
title_sort modification of the properties of vanadium oxide thin films by plasma immersion ion implantation
url http://dx.doi.org/10.1155/2018/9789370
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AT olgaberezina modificationofthepropertiesofvanadiumoxidethinfilmsbyplasmaimmersionionimplantation
AT alexanderpergament modificationofthepropertiesofvanadiumoxidethinfilmsbyplasmaimmersionionimplantation