Pharmacokinetic, biodistribution, safety and efficacy studies of borophenylalanine (BPA) in BNCT in hepatocellular carcinoma cells and tumor-bearing mouse model

Abstract Boron neutron capture therapy (BNCT), using boronophenylalanine (BPA) as the main boron carrier, is a dual-targeted particle radiotherapy at the cellular level. Although BPA shows clinical promise in liver cancer, there is relatively little basic research on its effect on hepatocellular car...

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Main Authors: Tanglong Zhang, Pengcheng Zhang, Huanyu Zhang, Zhuoya Zhang, Xiaodong Jin, Ting Zhao, Juntao Ran
Format: Article
Language:English
Published: Nature Portfolio 2025-08-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-025-14885-1
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author Tanglong Zhang
Pengcheng Zhang
Huanyu Zhang
Zhuoya Zhang
Xiaodong Jin
Ting Zhao
Juntao Ran
author_facet Tanglong Zhang
Pengcheng Zhang
Huanyu Zhang
Zhuoya Zhang
Xiaodong Jin
Ting Zhao
Juntao Ran
author_sort Tanglong Zhang
collection DOAJ
description Abstract Boron neutron capture therapy (BNCT), using boronophenylalanine (BPA) as the main boron carrier, is a dual-targeted particle radiotherapy at the cellular level. Although BPA shows clinical promise in liver cancer, there is relatively little basic research on its effect on hepatocellular carcinoma. Therefore, we systematically evaluated the uptake, safety, pharmacokinetics, and therapeutic efficacy of BPA. Boron uptake in hepatocellular carcinoma cells (Hepa1-6, HepG2) was quantified by ICP-AES, revealing concentration- and time-dependent accumulation (plateau at 6 h), while CCK-8 assays indicated significant cytotoxicity at 24 h. Pharmacokinetic studies in Sprague-Dawley (SD) rats showed rapid boron distribution (peak at 25 ± 5.8 min) with a blood clearance half-life of 74.71 ± 52.22 min. In tumor-bearing mouse models, BPA achieved tumor-specific targeting, with tumor-to-normal tissue (T/N) and tumor-to-blood (T/B) ratios exceeding 2 and 4, respectively, at 2 h post-injection, followed by rapid systemic clearance. Cell viability significantly decreased after BPA-BNCT irradiation, and the tumor growth inhibition rate in mice reached 77%. BPA did not produce tissue damage in vivo, and there were no abnormalities in blood counts or liver or kidney function in vivo after irradiation. These findings suggest that BPA can be selectively enriched in hepatocellular tumors with good pharmacokinetics and therapeutic efficacy, supporting its clinical application in BNCT of hepatocellular carcinoma.
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spelling doaj-art-b3df2d795a3f45f0b5da01de92652cf12025-08-20T03:04:25ZengNature PortfolioScientific Reports2045-23222025-08-0115111210.1038/s41598-025-14885-1Pharmacokinetic, biodistribution, safety and efficacy studies of borophenylalanine (BPA) in BNCT in hepatocellular carcinoma cells and tumor-bearing mouse modelTanglong Zhang0Pengcheng Zhang1Huanyu Zhang2Zhuoya Zhang3Xiaodong Jin4Ting Zhao5Juntao Ran6Department of Radiation Oncology, The First Hospital of Lanzhou UniversityDepartment of Radiation Oncology, The First Hospital of Lanzhou UniversityDepartment of Radiation Oncology, The First Hospital of Lanzhou UniversityDepartment of Radiation Oncology, The First Hospital of Lanzhou UniversityKey Laboratory of Heavy Ion Radiation Biology, Medicine of Chinese Academy of SciencesKey Laboratory of Heavy Ion Radiation Biology, Medicine of Chinese Academy of SciencesDepartment of Radiation Oncology, The First Hospital of Lanzhou UniversityAbstract Boron neutron capture therapy (BNCT), using boronophenylalanine (BPA) as the main boron carrier, is a dual-targeted particle radiotherapy at the cellular level. Although BPA shows clinical promise in liver cancer, there is relatively little basic research on its effect on hepatocellular carcinoma. Therefore, we systematically evaluated the uptake, safety, pharmacokinetics, and therapeutic efficacy of BPA. Boron uptake in hepatocellular carcinoma cells (Hepa1-6, HepG2) was quantified by ICP-AES, revealing concentration- and time-dependent accumulation (plateau at 6 h), while CCK-8 assays indicated significant cytotoxicity at 24 h. Pharmacokinetic studies in Sprague-Dawley (SD) rats showed rapid boron distribution (peak at 25 ± 5.8 min) with a blood clearance half-life of 74.71 ± 52.22 min. In tumor-bearing mouse models, BPA achieved tumor-specific targeting, with tumor-to-normal tissue (T/N) and tumor-to-blood (T/B) ratios exceeding 2 and 4, respectively, at 2 h post-injection, followed by rapid systemic clearance. Cell viability significantly decreased after BPA-BNCT irradiation, and the tumor growth inhibition rate in mice reached 77%. BPA did not produce tissue damage in vivo, and there were no abnormalities in blood counts or liver or kidney function in vivo after irradiation. These findings suggest that BPA can be selectively enriched in hepatocellular tumors with good pharmacokinetics and therapeutic efficacy, supporting its clinical application in BNCT of hepatocellular carcinoma.https://doi.org/10.1038/s41598-025-14885-1Boron neutron capture therapyDistribution of drugsPharmacokineticBPA
spellingShingle Tanglong Zhang
Pengcheng Zhang
Huanyu Zhang
Zhuoya Zhang
Xiaodong Jin
Ting Zhao
Juntao Ran
Pharmacokinetic, biodistribution, safety and efficacy studies of borophenylalanine (BPA) in BNCT in hepatocellular carcinoma cells and tumor-bearing mouse model
Scientific Reports
Boron neutron capture therapy
Distribution of drugs
Pharmacokinetic
BPA
title Pharmacokinetic, biodistribution, safety and efficacy studies of borophenylalanine (BPA) in BNCT in hepatocellular carcinoma cells and tumor-bearing mouse model
title_full Pharmacokinetic, biodistribution, safety and efficacy studies of borophenylalanine (BPA) in BNCT in hepatocellular carcinoma cells and tumor-bearing mouse model
title_fullStr Pharmacokinetic, biodistribution, safety and efficacy studies of borophenylalanine (BPA) in BNCT in hepatocellular carcinoma cells and tumor-bearing mouse model
title_full_unstemmed Pharmacokinetic, biodistribution, safety and efficacy studies of borophenylalanine (BPA) in BNCT in hepatocellular carcinoma cells and tumor-bearing mouse model
title_short Pharmacokinetic, biodistribution, safety and efficacy studies of borophenylalanine (BPA) in BNCT in hepatocellular carcinoma cells and tumor-bearing mouse model
title_sort pharmacokinetic biodistribution safety and efficacy studies of borophenylalanine bpa in bnct in hepatocellular carcinoma cells and tumor bearing mouse model
topic Boron neutron capture therapy
Distribution of drugs
Pharmacokinetic
BPA
url https://doi.org/10.1038/s41598-025-14885-1
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