Fabrication of Microfibre-nanowire Junction Arrays of ZnO/SnO2 Composite by the Carbothermal Evaporation Method

A cotton-like ZnO/SnO2 nanocomposite was grown by the carbothermal evaporation of a mixture of ZnO and SnO2 powders at 1100oC by the vapour-liquid- solid process, in which the Sn particles produced by the reduction of SnO2 act as the catalyst. Field-emission scanning electron microscope images sugge...

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Main Authors: Roghayeh Imani, Meysam Pazoki, Gerrit Boschloo, Aleš Iglic
Format: Article
Language:English
Published: Wiley 2014-07-01
Series:Nanomaterials and Nanotechnology
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Online Access:http://www.intechopen.com/journals/nanomaterials_and_nanotechnology/fabrication-of-microfibre-nanowire-junction-arrays-of-zno-sno2-composite-by-the-carbothermal-evapora
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author Roghayeh Imani
Meysam Pazoki
Gerrit Boschloo
Aleš Iglic
author_facet Roghayeh Imani
Meysam Pazoki
Gerrit Boschloo
Aleš Iglic
author_sort Roghayeh Imani
collection DOAJ
description A cotton-like ZnO/SnO2 nanocomposite was grown by the carbothermal evaporation of a mixture of ZnO and SnO2 powders at 1100oC by the vapour-liquid- solid process, in which the Sn particles produced by the reduction of SnO2 act as the catalyst. Field-emission scanning electron microscope images suggest that the composites are made of microfibre-nanowire junction arrays. The structure is formed due to the fast growth of the ZnO microfibre and the subsequent epitaxial radial growth of the ZnO nanowires with Sn particles at the tips. The photovoltaic performance of the ZnO/SnO2 nanocomposite D35-cpdt dye . A dye-sensitized solar cell (DSSC) with a ZnO/SnO2 nanocomposite photoanode based on a cobalt electrolyte achieved a solar-to-electricity conversion efficiency of ∼0.34% with a short circuit current (JSC) of 0.66 mA/cm2, an open circuit voltage (VOC) of 870 mV, and a fill factor (FF) of 59. The results show the potential of this one dimensional structure in cobalt electrolyte- based DSSCs; the further optimization which is needed to achieve higher efficiencies is also discussed.
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institution Kabale University
issn 1847-9804
language English
publishDate 2014-07-01
publisher Wiley
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series Nanomaterials and Nanotechnology
spelling doaj-art-b3921bd07bed4c459a41ff1b3f3417d92025-02-03T06:47:39ZengWileyNanomaterials and Nanotechnology1847-98042014-07-01421http://dx.doi.org/10.5772/5888547262Fabrication of Microfibre-nanowire Junction Arrays of ZnO/SnO2 Composite by the Carbothermal Evaporation MethodRoghayeh ImaniMeysam PazokiGerrit BoschlooAleš IglicA cotton-like ZnO/SnO2 nanocomposite was grown by the carbothermal evaporation of a mixture of ZnO and SnO2 powders at 1100oC by the vapour-liquid- solid process, in which the Sn particles produced by the reduction of SnO2 act as the catalyst. Field-emission scanning electron microscope images suggest that the composites are made of microfibre-nanowire junction arrays. The structure is formed due to the fast growth of the ZnO microfibre and the subsequent epitaxial radial growth of the ZnO nanowires with Sn particles at the tips. The photovoltaic performance of the ZnO/SnO2 nanocomposite D35-cpdt dye . A dye-sensitized solar cell (DSSC) with a ZnO/SnO2 nanocomposite photoanode based on a cobalt electrolyte achieved a solar-to-electricity conversion efficiency of ∼0.34% with a short circuit current (JSC) of 0.66 mA/cm2, an open circuit voltage (VOC) of 870 mV, and a fill factor (FF) of 59. The results show the potential of this one dimensional structure in cobalt electrolyte- based DSSCs; the further optimization which is needed to achieve higher efficiencies is also discussed.http://www.intechopen.com/journals/nanomaterials_and_nanotechnology/fabrication-of-microfibre-nanowire-junction-arrays-of-zno-sno2-composite-by-the-carbothermal-evaporaZnO/SnO2 NanocompositeDye-sensitized Solar CellNanostructured Surfaces
spellingShingle Roghayeh Imani
Meysam Pazoki
Gerrit Boschloo
Aleš Iglic
Fabrication of Microfibre-nanowire Junction Arrays of ZnO/SnO2 Composite by the Carbothermal Evaporation Method
Nanomaterials and Nanotechnology
ZnO/SnO2 Nanocomposite
Dye-sensitized Solar Cell
Nanostructured Surfaces
title Fabrication of Microfibre-nanowire Junction Arrays of ZnO/SnO2 Composite by the Carbothermal Evaporation Method
title_full Fabrication of Microfibre-nanowire Junction Arrays of ZnO/SnO2 Composite by the Carbothermal Evaporation Method
title_fullStr Fabrication of Microfibre-nanowire Junction Arrays of ZnO/SnO2 Composite by the Carbothermal Evaporation Method
title_full_unstemmed Fabrication of Microfibre-nanowire Junction Arrays of ZnO/SnO2 Composite by the Carbothermal Evaporation Method
title_short Fabrication of Microfibre-nanowire Junction Arrays of ZnO/SnO2 Composite by the Carbothermal Evaporation Method
title_sort fabrication of microfibre nanowire junction arrays of zno sno2 composite by the carbothermal evaporation method
topic ZnO/SnO2 Nanocomposite
Dye-sensitized Solar Cell
Nanostructured Surfaces
url http://www.intechopen.com/journals/nanomaterials_and_nanotechnology/fabrication-of-microfibre-nanowire-junction-arrays-of-zno-sno2-composite-by-the-carbothermal-evapora
work_keys_str_mv AT roghayehimani fabricationofmicrofibrenanowirejunctionarraysofznosno2compositebythecarbothermalevaporationmethod
AT meysampazoki fabricationofmicrofibrenanowirejunctionarraysofznosno2compositebythecarbothermalevaporationmethod
AT gerritboschloo fabricationofmicrofibrenanowirejunctionarraysofznosno2compositebythecarbothermalevaporationmethod
AT alesiglic fabricationofmicrofibrenanowirejunctionarraysofznosno2compositebythecarbothermalevaporationmethod