Field-Induced Slow Magnetic Relaxation in Pentacoordinate Co(II) Complexes: Tuning Magnetic Anisotropy Through Halide Substitution

Field-Induced Slow Magnetic Relaxation in Pentacoordinate Co(II) Complexes: Tuning Magnetic Anisotropy Through Halide Substitution

We report the synthesis, structural characterization, and magnetic properties of three pentacoordinate Co(II) complexes [CoX(dppb)<sub>2</sub>]X (X = Cl (<b>1Cl</b>), Br (<b>2Br</b>), and I (<b>3I</b>)) supported by the bidentate phosphine ligand 1,2-b...

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Bibliographic Details
Main Authors:	Hong-Yao Guo, Wei-Quan Lin, Ji-Dong Leng
Format:	Article
Language:	English
Published:	MDPI AG 2025-05-01
Series:	Molecules
Subjects:	single-ion magnets cobalt(II) complexes pentacoordinate geometry magnetic anisotropy halide substitution bidentate phosphine ligands
Online Access:	https://www.mdpi.com/1420-3049/30/11/2295
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