Influence of Cement Type and Water-to-Cement Ratio on the Formation of Thaumasite

Cement mortar prisms were prepared with three different cement types and different water-to-cement ratios plus 30% mass of limestone filler. After 28 days of curing in water at room temperature, these samples were submerged in 2% magnesium sulfate solution at 5°C and the visual appearance and streng...

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Main Authors: Ailian Zhang, Linchun Zhang
Format: Article
Language:English
Published: Wiley 2017-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2017/7643960
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author Ailian Zhang
Linchun Zhang
author_facet Ailian Zhang
Linchun Zhang
author_sort Ailian Zhang
collection DOAJ
description Cement mortar prisms were prepared with three different cement types and different water-to-cement ratios plus 30% mass of limestone filler. After 28 days of curing in water at room temperature, these samples were submerged in 2% magnesium sulfate solution at 5°C and the visual appearance and strength development for every mortar were measured at intervals up to 1 year. Samples selected from the surface of prisms after 1-year immersion were examined by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. The results show that mortars with sulfate resisting Portland cement (SRC) or sulphoaluminate cement (SAC) underwent weaker degradation due to the thaumasite form of sulfate attack than mortars with ordinary Portland cement (OPC). A lower water-to-cement ratio leads to better resistance to the thaumasite form of sulfate attack of the cement mortar. A great deal of thaumasite or thaumasite-containing materials formed in the OPC mortar, and a trace of thaumasite can also be detected in SRC and SAC mortars. Therefore, the thaumasite form of sulfate attack can be alleviated but cannot be avoided by the use of SAC or SRC.
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spelling doaj-art-b1f8eeb3d31b44b48c02e239fd4de9c52025-08-20T03:39:25ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422017-01-01201710.1155/2017/76439607643960Influence of Cement Type and Water-to-Cement Ratio on the Formation of ThaumasiteAilian Zhang0Linchun Zhang1Department of Civil Engineering, Sichuan College of Architectural Technology, Deyang 618000, ChinaDepartment of Civil Engineering, Sichuan College of Architectural Technology, Deyang 618000, ChinaCement mortar prisms were prepared with three different cement types and different water-to-cement ratios plus 30% mass of limestone filler. After 28 days of curing in water at room temperature, these samples were submerged in 2% magnesium sulfate solution at 5°C and the visual appearance and strength development for every mortar were measured at intervals up to 1 year. Samples selected from the surface of prisms after 1-year immersion were examined by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. The results show that mortars with sulfate resisting Portland cement (SRC) or sulphoaluminate cement (SAC) underwent weaker degradation due to the thaumasite form of sulfate attack than mortars with ordinary Portland cement (OPC). A lower water-to-cement ratio leads to better resistance to the thaumasite form of sulfate attack of the cement mortar. A great deal of thaumasite or thaumasite-containing materials formed in the OPC mortar, and a trace of thaumasite can also be detected in SRC and SAC mortars. Therefore, the thaumasite form of sulfate attack can be alleviated but cannot be avoided by the use of SAC or SRC.http://dx.doi.org/10.1155/2017/7643960
spellingShingle Ailian Zhang
Linchun Zhang
Influence of Cement Type and Water-to-Cement Ratio on the Formation of Thaumasite
Advances in Materials Science and Engineering
title Influence of Cement Type and Water-to-Cement Ratio on the Formation of Thaumasite
title_full Influence of Cement Type and Water-to-Cement Ratio on the Formation of Thaumasite
title_fullStr Influence of Cement Type and Water-to-Cement Ratio on the Formation of Thaumasite
title_full_unstemmed Influence of Cement Type and Water-to-Cement Ratio on the Formation of Thaumasite
title_short Influence of Cement Type and Water-to-Cement Ratio on the Formation of Thaumasite
title_sort influence of cement type and water to cement ratio on the formation of thaumasite
url http://dx.doi.org/10.1155/2017/7643960
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