Anti-Bacterial Properties and Hemocompatibility of Alkali Treated Nano-Structured Micro-Porous Titanium Surfaces

Titanium and its alloys have been the material of choice for orthopedic implants due to their excellent physical properties as well as biocompatibility. However, titanium is not able to integrate with bone due to the mismatch of mechanical properties. Additionally, bone has a micro–nano hierarchy, w...

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Main Authors: Aniruddha Vijay Savargaonkar, Emma Holloway, Liszt Y. C. Madruga, Bruno L Pereira, Paulo Soares, Ketul C. Popat
Format: Article
Language:English
Published: MDPI AG 2025-02-01
Series:Biomimetics
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Online Access:https://www.mdpi.com/2313-7673/10/2/115
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author Aniruddha Vijay Savargaonkar
Emma Holloway
Liszt Y. C. Madruga
Bruno L Pereira
Paulo Soares
Ketul C. Popat
author_facet Aniruddha Vijay Savargaonkar
Emma Holloway
Liszt Y. C. Madruga
Bruno L Pereira
Paulo Soares
Ketul C. Popat
author_sort Aniruddha Vijay Savargaonkar
collection DOAJ
description Titanium and its alloys have been the material of choice for orthopedic implants due to their excellent physical properties as well as biocompatibility. However, titanium is not able to integrate with bone due to the mismatch of mechanical properties. Additionally, bone has a micro–nano hierarchy, which is absent on titanium’s surface. A potential solution to the former is to make the surfaces porous to bring the mechanical properties closer to that of the bone, and a solution for the latter is to fabricate nanostructures. In this study, micro-porous titanium surfaces were hydrothermally treated using an alkali medium to fabricate nanostructures on the existing micro-porosity of the surface. The surface properties were evaluated using scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and nanoindentation. The anti-bacterial properties of the surfaces were evaluated against Gram-positive and Gram-negative bacteria using fluorescence microscopy and scanning electron microscopy. Blood clotting is shown to improve the surface-to-bone integration; hence, whole blood clotting and platelet adhesion and activation were evaluated using a whole blood clotting assay, fluorescence microscopy, and scanning electron microscopy. The results indicate that nanostructured micro-porous titanium surfaces display significantly enhanced anti-bacterial properties as well as equivalent blood clotting characteristics compared to non-porous titanium surfaces.
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spelling doaj-art-b1f719cee77343e4bf157b7ff34a8a2a2025-08-20T03:12:02ZengMDPI AGBiomimetics2313-76732025-02-0110211510.3390/biomimetics10020115Anti-Bacterial Properties and Hemocompatibility of Alkali Treated Nano-Structured Micro-Porous Titanium SurfacesAniruddha Vijay Savargaonkar0Emma Holloway1Liszt Y. C. Madruga2Bruno L Pereira3Paulo Soares4Ketul C. Popat5Department of Mechanical Engineering, Colorado State University, Fort Collins, CO 80523, USADepartment of Chemical and Biological Engineering, Colorado State University, Fort Collins, CO 80523, USADepartment of Bioengineering, George Mason University, Fairfax, VA 22030, USADepartment of Mechanical Engineering, Pontifícia Universidade Católica do Paraná, Curitiba 80215-901, PR, BrazilDepartment of Mechanical Engineering, Pontifícia Universidade Católica do Paraná, Curitiba 80215-901, PR, BrazilDepartment of Mechanical Engineering, Colorado State University, Fort Collins, CO 80523, USATitanium and its alloys have been the material of choice for orthopedic implants due to their excellent physical properties as well as biocompatibility. However, titanium is not able to integrate with bone due to the mismatch of mechanical properties. Additionally, bone has a micro–nano hierarchy, which is absent on titanium’s surface. A potential solution to the former is to make the surfaces porous to bring the mechanical properties closer to that of the bone, and a solution for the latter is to fabricate nanostructures. In this study, micro-porous titanium surfaces were hydrothermally treated using an alkali medium to fabricate nanostructures on the existing micro-porosity of the surface. The surface properties were evaluated using scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and nanoindentation. The anti-bacterial properties of the surfaces were evaluated against Gram-positive and Gram-negative bacteria using fluorescence microscopy and scanning electron microscopy. Blood clotting is shown to improve the surface-to-bone integration; hence, whole blood clotting and platelet adhesion and activation were evaluated using a whole blood clotting assay, fluorescence microscopy, and scanning electron microscopy. The results indicate that nanostructured micro-porous titanium surfaces display significantly enhanced anti-bacterial properties as well as equivalent blood clotting characteristics compared to non-porous titanium surfaces.https://www.mdpi.com/2313-7673/10/2/115titaniumnanostructuresbiomaterialsanti-bacterial studieshemocompatibility
spellingShingle Aniruddha Vijay Savargaonkar
Emma Holloway
Liszt Y. C. Madruga
Bruno L Pereira
Paulo Soares
Ketul C. Popat
Anti-Bacterial Properties and Hemocompatibility of Alkali Treated Nano-Structured Micro-Porous Titanium Surfaces
Biomimetics
titanium
nanostructures
biomaterials
anti-bacterial studies
hemocompatibility
title Anti-Bacterial Properties and Hemocompatibility of Alkali Treated Nano-Structured Micro-Porous Titanium Surfaces
title_full Anti-Bacterial Properties and Hemocompatibility of Alkali Treated Nano-Structured Micro-Porous Titanium Surfaces
title_fullStr Anti-Bacterial Properties and Hemocompatibility of Alkali Treated Nano-Structured Micro-Porous Titanium Surfaces
title_full_unstemmed Anti-Bacterial Properties and Hemocompatibility of Alkali Treated Nano-Structured Micro-Porous Titanium Surfaces
title_short Anti-Bacterial Properties and Hemocompatibility of Alkali Treated Nano-Structured Micro-Porous Titanium Surfaces
title_sort anti bacterial properties and hemocompatibility of alkali treated nano structured micro porous titanium surfaces
topic titanium
nanostructures
biomaterials
anti-bacterial studies
hemocompatibility
url https://www.mdpi.com/2313-7673/10/2/115
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