THE KINETICS OF HYDROLYSIS OF TRANS-DIFLUOROTETRAMMINECHROMIUM (111) ION IN VARIOUS CONCENTRATED ACID SOLUTIONS
The rate of hydrolysis of trans -[Cr(NH ) F ] was obtained as a function of acid concentsation in perchloric, sulfuric and nitric acid at 3Q°C. The results have been analyzed by the treatment of Bunnett and Olsen. Values of the parameter ?in Olsen equation are consistent with the participation of...
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| Language: | English |
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University of Tehran
1994-06-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
| Online Access: | https://jsciences.ut.ac.ir/article_31377_5d0e7b7f79a5402a1bcfe8e9f43536fc.pdf |
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| collection | DOAJ |
| description | The rate of hydrolysis of trans -[Cr(NH ) F ] was obtained as a function of acid
concentsation in perchloric, sulfuric and nitric acid at 3Q°C. The results have been
analyzed by the treatment of Bunnett and Olsen. Values of the parameter ?in Olsen
equation are consistent with the participation of water as a proton-wansfer agent in the rate-determining step. The Arrhenius plot for perchloric acid was linear, with an
activation energy of 19.8 ± 0.8 KCal K mole . |
| format | Article |
| id | doaj-art-b1f5b451024e4a7e9df8ba1ba36ee569 |
| institution | OA Journals |
| issn | 1016-1104 2345-6914 |
| language | English |
| publishDate | 1994-06-01 |
| publisher | University of Tehran |
| record_format | Article |
| series | Journal of Sciences, Islamic Republic of Iran |
| spelling | doaj-art-b1f5b451024e4a7e9df8ba1ba36ee5692025-08-20T02:25:51ZengUniversity of TehranJournal of Sciences, Islamic Republic of Iran1016-11042345-69141994-06-015131377THE KINETICS OF HYDROLYSIS OF TRANS-DIFLUOROTETRAMMINECHROMIUM (111) ION IN VARIOUS CONCENTRATED ACID SOLUTIONSThe rate of hydrolysis of trans -[Cr(NH ) F ] was obtained as a function of acid concentsation in perchloric, sulfuric and nitric acid at 3Q°C. The results have been analyzed by the treatment of Bunnett and Olsen. Values of the parameter ?in Olsen equation are consistent with the participation of water as a proton-wansfer agent in the rate-determining step. The Arrhenius plot for perchloric acid was linear, with an activation energy of 19.8 ± 0.8 KCal K mole .https://jsciences.ut.ac.ir/article_31377_5d0e7b7f79a5402a1bcfe8e9f43536fc.pdf |
| spellingShingle | THE KINETICS OF HYDROLYSIS OF
TRANS-DIFLUOROTETRAMMINECHROMIUM
(111) ION IN VARIOUS
CONCENTRATED ACID SOLUTIONS Journal of Sciences, Islamic Republic of Iran |
| title | THE KINETICS OF HYDROLYSIS OF
TRANS-DIFLUOROTETRAMMINECHROMIUM
(111) ION IN VARIOUS
CONCENTRATED ACID SOLUTIONS |
| title_full | THE KINETICS OF HYDROLYSIS OF
TRANS-DIFLUOROTETRAMMINECHROMIUM
(111) ION IN VARIOUS
CONCENTRATED ACID SOLUTIONS |
| title_fullStr | THE KINETICS OF HYDROLYSIS OF
TRANS-DIFLUOROTETRAMMINECHROMIUM
(111) ION IN VARIOUS
CONCENTRATED ACID SOLUTIONS |
| title_full_unstemmed | THE KINETICS OF HYDROLYSIS OF
TRANS-DIFLUOROTETRAMMINECHROMIUM
(111) ION IN VARIOUS
CONCENTRATED ACID SOLUTIONS |
| title_short | THE KINETICS OF HYDROLYSIS OF
TRANS-DIFLUOROTETRAMMINECHROMIUM
(111) ION IN VARIOUS
CONCENTRATED ACID SOLUTIONS |
| title_sort | kinetics of hydrolysis of trans difluorotetramminechromium 111 ion in various concentrated acid solutions |
| url | https://jsciences.ut.ac.ir/article_31377_5d0e7b7f79a5402a1bcfe8e9f43536fc.pdf |