Experimental Research on Quarry Wastewater Purification Using Flocculation Process

The flocculation-based purification of quarry wastewater continues to pose a significant challenge in mineral processing and environmental engineering, primarily due to persistent turbidity issues and inefficient floc settling behaviour. In this study, we systematically investigate the synergistic e...

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Main Authors: Yongjie Bu, Kangjian Zeng, Heng Yang, Aihui Sun, Qingjun Guan, Shuang Zhou, Wenqing Peng, Weijun Wang, Peng Ge, Yue Yang
Format: Article
Language:English
Published: MDPI AG 2025-06-01
Series:Molecules
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Online Access:https://www.mdpi.com/1420-3049/30/13/2761
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author Yongjie Bu
Kangjian Zeng
Heng Yang
Aihui Sun
Qingjun Guan
Shuang Zhou
Wenqing Peng
Weijun Wang
Peng Ge
Yue Yang
author_facet Yongjie Bu
Kangjian Zeng
Heng Yang
Aihui Sun
Qingjun Guan
Shuang Zhou
Wenqing Peng
Weijun Wang
Peng Ge
Yue Yang
author_sort Yongjie Bu
collection DOAJ
description The flocculation-based purification of quarry wastewater continues to pose a significant challenge in mineral processing and environmental engineering, primarily due to persistent turbidity issues and inefficient floc settling behaviour. In this study, we systematically investigate the synergistic effects of organic and inorganic flocculants to reduce turbidity and improve floc settling performance. Through a series of optimised experiments using polyaluminium chloride as an inorganic flocculant, polyacrylamide as an organic flocculant, and calcium oxide as a pH regulator agent, the treatment efficiency was evaluated. Under the optimal conditions with 200 g/m<sup>3</sup> CaO as the regulator agent and 2.5 g/m<sup>3</sup> PAC and 12 g/m<sup>3</sup> PAM as flocculants, the residual turbidity was reduced to 97.30 NTU, meeting stringent industrial discharge standards and enabling zero-discharge water reuse. Zeta potential measurements, optical microscopy, and DLVO theory collectively elucidated the interfacial interactions between flocculants and mineral particles, with zeta potential revealing electrostatic effects, microscopy visualising aggregation patterns, and DLVO theory modelling revealing colloidal stability, thereby mechanistically explaining the enhanced aggregation behaviour.
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institution OA Journals
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publishDate 2025-06-01
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series Molecules
spelling doaj-art-b1e3118c36a74dc5b0ae21d3a7cdca852025-08-20T02:36:32ZengMDPI AGMolecules1420-30492025-06-013013276110.3390/molecules30132761Experimental Research on Quarry Wastewater Purification Using Flocculation ProcessYongjie Bu0Kangjian Zeng1Heng Yang2Aihui Sun3Qingjun Guan4Shuang Zhou5Wenqing Peng6Weijun Wang7Peng Ge8Yue Yang9School of Resource Environment and Safety Engineering, Hunan University of Science and Technology, Xiangtan 411201, ChinaSchool of Resource Environment and Safety Engineering, Hunan University of Science and Technology, Xiangtan 411201, ChinaSchool of Resource Environment and Safety Engineering, Hunan University of Science and Technology, Xiangtan 411201, ChinaSchool of Resource Environment and Safety Engineering, Hunan University of Science and Technology, Xiangtan 411201, ChinaSchool of Resource Environment and Safety Engineering, Hunan University of Science and Technology, Xiangtan 411201, ChinaSchool of Resource Environment and Safety Engineering, Hunan University of Science and Technology, Xiangtan 411201, ChinaSchool of Resource Environment and Safety Engineering, Hunan University of Science and Technology, Xiangtan 411201, ChinaSchool of Resource Environment and Safety Engineering, Hunan University of Science and Technology, Xiangtan 411201, ChinaSchool of Minerals Processing and Bioengineering, Central South University, Changsha 410083, ChinaSchool of Minerals Processing and Bioengineering, Central South University, Changsha 410083, ChinaThe flocculation-based purification of quarry wastewater continues to pose a significant challenge in mineral processing and environmental engineering, primarily due to persistent turbidity issues and inefficient floc settling behaviour. In this study, we systematically investigate the synergistic effects of organic and inorganic flocculants to reduce turbidity and improve floc settling performance. Through a series of optimised experiments using polyaluminium chloride as an inorganic flocculant, polyacrylamide as an organic flocculant, and calcium oxide as a pH regulator agent, the treatment efficiency was evaluated. Under the optimal conditions with 200 g/m<sup>3</sup> CaO as the regulator agent and 2.5 g/m<sup>3</sup> PAC and 12 g/m<sup>3</sup> PAM as flocculants, the residual turbidity was reduced to 97.30 NTU, meeting stringent industrial discharge standards and enabling zero-discharge water reuse. Zeta potential measurements, optical microscopy, and DLVO theory collectively elucidated the interfacial interactions between flocculants and mineral particles, with zeta potential revealing electrostatic effects, microscopy visualising aggregation patterns, and DLVO theory modelling revealing colloidal stability, thereby mechanistically explaining the enhanced aggregation behaviour.https://www.mdpi.com/1420-3049/30/13/2761quarrywastewater treatmentflocculantDLVO
spellingShingle Yongjie Bu
Kangjian Zeng
Heng Yang
Aihui Sun
Qingjun Guan
Shuang Zhou
Wenqing Peng
Weijun Wang
Peng Ge
Yue Yang
Experimental Research on Quarry Wastewater Purification Using Flocculation Process
Molecules
quarry
wastewater treatment
flocculant
DLVO
title Experimental Research on Quarry Wastewater Purification Using Flocculation Process
title_full Experimental Research on Quarry Wastewater Purification Using Flocculation Process
title_fullStr Experimental Research on Quarry Wastewater Purification Using Flocculation Process
title_full_unstemmed Experimental Research on Quarry Wastewater Purification Using Flocculation Process
title_short Experimental Research on Quarry Wastewater Purification Using Flocculation Process
title_sort experimental research on quarry wastewater purification using flocculation process
topic quarry
wastewater treatment
flocculant
DLVO
url https://www.mdpi.com/1420-3049/30/13/2761
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