Green coal and lubricant via hydrogen-free hydrothermal liquefaction of biomass

Abstract Biocrude derived from biomass via hydrothermal liquefaction (HTL) is a sustainable substitute for petroleum to obtain energy and biochemicals. Upgrading biocrude inevitably faces the trade-off between consuming large amounts of hydrogen via hydrotreating and high yield of solid residue with...

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Main Authors: Maojiong Cao, Reaihan E, Changbin Yuan, Lasse Aistrup Rosendahl, Yuanhui Zhang, Charles Chunbao Xu, Yulong Wu, Deliang Kong, Yingxian Wang, Jiaming Li, Zhidan Liu
Format: Article
Language:English
Published: Nature Portfolio 2025-01-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-56037-z
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Summary:Abstract Biocrude derived from biomass via hydrothermal liquefaction (HTL) is a sustainable substitute for petroleum to obtain energy and biochemicals. Upgrading biocrude inevitably faces the trade-off between consuming large amounts of hydrogen via hydrotreating and high yield of solid residue without additional hydrogen. In this work, we report a non-hydrogenated refinery paradigm for nearly complete valorization (~90%), via co-generating green coal and bio-lubricant. The obtained green coal has higher heating values comparable to commercial coals, with a lower fuel ratio and reduced ash content. Viscosity of upgraded vacuum distillate is comparable to that of a lubricant oil. A life cycle assessment confirms 28% reduction in greenhouse gas emission and 35% reduction in energy input of this paradigm compared with conventional hydrotreating biorefinery. This approach presents an environmentally friendly, safe and convenient paradigm for biocrude refining from huge biowaste towards carbon-neutral society.
ISSN:2041-1723