Microwave-Assisted Green Synthesis of Binary/Ternary Zn<i><sub>x</sub></i>Co<sub>1−<i>x</i></sub>Fe<sub>2</sub>O<sub>4</sub> (<i>x</i> = 0, 0.5, 1) Nanoparticles
In this study, magnetic binary/ternary Zn<i><sub>x</sub></i>Co<sub>1−<i>x</i></sub>Fe<sub>2</sub>O<sub>4</sub> (<i>x</i> = 0, 0.5, 1) nanoparticles were synthesized using a straightforward one-step microwave techniqu...
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2024-11-01
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| author | Sanaz Chamani Masoumeh Khatamian |
| author_facet | Sanaz Chamani Masoumeh Khatamian |
| author_sort | Sanaz Chamani |
| collection | DOAJ |
| description | In this study, magnetic binary/ternary Zn<i><sub>x</sub></i>Co<sub>1−<i>x</i></sub>Fe<sub>2</sub>O<sub>4</sub> (<i>x</i> = 0, 0.5, 1) nanoparticles were synthesized using a straightforward one-step microwave technique. To produce the Zn<i><sub>x</sub></i>Co<sub>1−<i>x</i></sub>Fe<sub>2</sub>O<sub>4</sub> nanoparticles, iron (III) nitrate nonahydrate, zinc nitrate hexahydrate, and cobalt nitrate hexahydrate were used as metal sources, with urea used as the fuel and ammonium nitrate as the oxidizer. These materials were combined in an alumina crucible covered by a CuO jacket to absorb microwave energy and facilitate calcination. The thermal treatment involved placing the alumina crucible in a domestic microwave oven at 450 W for 30 min. The key strengths of this experimental strategy include its simplicity, cost-effectiveness, and rapidity, aligning with green chemistry principles. The synthesized nanoparticles were characterized using X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, a vibrating sample magnetometer (VSM), and Brunauer–Emmett–Teller (BET) analysis. XRD analysis confirmed the presence of the pure ferrite nanocrystalline phase. Scanning electron microscopy (SEM), employed with energy-dispersive X-ray spectroscopy (EDS), was used to study the surface morphology and analyze the elemental composition. The SEM analysis revealed that the synthesized magnetic nanoparticles had particle sizes ranging from 30 to 50 nm. Furthermore, we explored the potential use of these magnetic nanoparticles as photocatalysts for degrading organic pollutants such as methylene blue in aqueous solutions. |
| format | Article |
| id | doaj-art-b182100931ad40f1ae8a683cdfdd59e8 |
| institution | Kabale University |
| issn | 2673-4583 |
| language | English |
| publishDate | 2024-11-01 |
| publisher | MDPI AG |
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| series | Chemistry Proceedings |
| spelling | doaj-art-b182100931ad40f1ae8a683cdfdd59e82025-08-20T03:27:13ZengMDPI AGChemistry Proceedings2673-45832024-11-011612910.3390/ecsoc-28-20248Microwave-Assisted Green Synthesis of Binary/Ternary Zn<i><sub>x</sub></i>Co<sub>1−<i>x</i></sub>Fe<sub>2</sub>O<sub>4</sub> (<i>x</i> = 0, 0.5, 1) NanoparticlesSanaz Chamani0Masoumeh Khatamian1Koç University Boron and Advanced Materials Applications and Research Center (KUBAM), Istanbul 34450, TurkeyInorganic Chemistry Department, Faculty of Chemistry, University of Tabriz, Tabriz 5166616471, IranIn this study, magnetic binary/ternary Zn<i><sub>x</sub></i>Co<sub>1−<i>x</i></sub>Fe<sub>2</sub>O<sub>4</sub> (<i>x</i> = 0, 0.5, 1) nanoparticles were synthesized using a straightforward one-step microwave technique. To produce the Zn<i><sub>x</sub></i>Co<sub>1−<i>x</i></sub>Fe<sub>2</sub>O<sub>4</sub> nanoparticles, iron (III) nitrate nonahydrate, zinc nitrate hexahydrate, and cobalt nitrate hexahydrate were used as metal sources, with urea used as the fuel and ammonium nitrate as the oxidizer. These materials were combined in an alumina crucible covered by a CuO jacket to absorb microwave energy and facilitate calcination. The thermal treatment involved placing the alumina crucible in a domestic microwave oven at 450 W for 30 min. The key strengths of this experimental strategy include its simplicity, cost-effectiveness, and rapidity, aligning with green chemistry principles. The synthesized nanoparticles were characterized using X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, a vibrating sample magnetometer (VSM), and Brunauer–Emmett–Teller (BET) analysis. XRD analysis confirmed the presence of the pure ferrite nanocrystalline phase. Scanning electron microscopy (SEM), employed with energy-dispersive X-ray spectroscopy (EDS), was used to study the surface morphology and analyze the elemental composition. The SEM analysis revealed that the synthesized magnetic nanoparticles had particle sizes ranging from 30 to 50 nm. Furthermore, we explored the potential use of these magnetic nanoparticles as photocatalysts for degrading organic pollutants such as methylene blue in aqueous solutions.https://www.mdpi.com/2673-4583/16/1/29microwave synthesismagnetic nanoparticlesphotocatalystorganic pollutants |
| spellingShingle | Sanaz Chamani Masoumeh Khatamian Microwave-Assisted Green Synthesis of Binary/Ternary Zn<i><sub>x</sub></i>Co<sub>1−<i>x</i></sub>Fe<sub>2</sub>O<sub>4</sub> (<i>x</i> = 0, 0.5, 1) Nanoparticles Chemistry Proceedings microwave synthesis magnetic nanoparticles photocatalyst organic pollutants |
| title | Microwave-Assisted Green Synthesis of Binary/Ternary Zn<i><sub>x</sub></i>Co<sub>1−<i>x</i></sub>Fe<sub>2</sub>O<sub>4</sub> (<i>x</i> = 0, 0.5, 1) Nanoparticles |
| title_full | Microwave-Assisted Green Synthesis of Binary/Ternary Zn<i><sub>x</sub></i>Co<sub>1−<i>x</i></sub>Fe<sub>2</sub>O<sub>4</sub> (<i>x</i> = 0, 0.5, 1) Nanoparticles |
| title_fullStr | Microwave-Assisted Green Synthesis of Binary/Ternary Zn<i><sub>x</sub></i>Co<sub>1−<i>x</i></sub>Fe<sub>2</sub>O<sub>4</sub> (<i>x</i> = 0, 0.5, 1) Nanoparticles |
| title_full_unstemmed | Microwave-Assisted Green Synthesis of Binary/Ternary Zn<i><sub>x</sub></i>Co<sub>1−<i>x</i></sub>Fe<sub>2</sub>O<sub>4</sub> (<i>x</i> = 0, 0.5, 1) Nanoparticles |
| title_short | Microwave-Assisted Green Synthesis of Binary/Ternary Zn<i><sub>x</sub></i>Co<sub>1−<i>x</i></sub>Fe<sub>2</sub>O<sub>4</sub> (<i>x</i> = 0, 0.5, 1) Nanoparticles |
| title_sort | microwave assisted green synthesis of binary ternary zn i sub x sub i co sub 1 i x i sub fe sub 2 sub o sub 4 sub i x i 0 0 5 1 nanoparticles |
| topic | microwave synthesis magnetic nanoparticles photocatalyst organic pollutants |
| url | https://www.mdpi.com/2673-4583/16/1/29 |
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