Physical Vapor Deposition Techniques for CO2 Electroreduction: A Review

CO2 electroreduction offers a promising approach to reducing the human carbon footprint by converting CO2 into fuels and valuable chemicals. Physical vapor deposition (PVD) techniques, including sputtering, thermal evaporation, and pulsed laser deposition, enable the fabrication of high‐performance...

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Main Authors: Samah A. Mahyoub, Arshad Farid, Muhammad Zain Azeem, Danah A. AL Fadhil, Fahim A. Qaraah, Qasem A. Drmosh
Format: Article
Language:English
Published: Wiley-VCH 2025-05-01
Series:Small Structures
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Online Access:https://doi.org/10.1002/sstr.202400501
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author Samah A. Mahyoub
Arshad Farid
Muhammad Zain Azeem
Danah A. AL Fadhil
Fahim A. Qaraah
Qasem A. Drmosh
author_facet Samah A. Mahyoub
Arshad Farid
Muhammad Zain Azeem
Danah A. AL Fadhil
Fahim A. Qaraah
Qasem A. Drmosh
author_sort Samah A. Mahyoub
collection DOAJ
description CO2 electroreduction offers a promising approach to reducing the human carbon footprint by converting CO2 into fuels and valuable chemicals. Physical vapor deposition (PVD) techniques, including sputtering, thermal evaporation, and pulsed laser deposition, enable the fabrication of high‐performance catalysts with controlled morphology, strong adhesion, and high purity. These methods allow precise customization of surface features, enhancing catalyst stability and efficiency. PVD facilitates the deposition of various materials, such as metal oxides, alloys, and nanocomposites, making it essential for developing durable catalysts for energy conversion and environmental applications. This review explores the role of PVD in CO2 reduction, focusing on its advantages over alternative deposition techniques like electrodeposition and chemical vapor deposition. It highlights PVD's ability to produce uniform, reproducible films with tailored catalytic properties. Challenges related to scalability, uniformity, and deposition efficiency are discussed, along with potential solutions such as codeposition, multilayer strategies, and hybrid approaches. Future advancements in deposition techniques and material design are also considered to enhance catalyst performance. By addressing these aspects, this review provides insights into optimizing PVD‐based catalysts for efficient and stable CO2 reduction.
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issn 2688-4062
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publisher Wiley-VCH
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spelling doaj-art-b120655a8fc446c19ec889088266306d2025-08-20T02:11:03ZengWiley-VCHSmall Structures2688-40622025-05-0165n/an/a10.1002/sstr.202400501Physical Vapor Deposition Techniques for CO2 Electroreduction: A ReviewSamah A. Mahyoub0Arshad Farid1Muhammad Zain Azeem2Danah A. AL Fadhil3Fahim A. Qaraah4Qasem A. Drmosh5Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management King Fahd University of Petroleum & Minerals (KFUPM) Dhahran 31261 Saudi ArabiaDepartment of Materials Science and Engineering King Fahd University of Petroleum & Minerals Dhahran 31261 Saudi ArabiaDepartment of Materials Science and Engineering King Fahd University of Petroleum & Minerals Dhahran 31261 Saudi ArabiaDepartment of Materials Science and Engineering King Fahd University of Petroleum & Minerals Dhahran 31261 Saudi ArabiaInterdisciplinary Research Center for Hydrogen Technologies and Carbon Management King Fahd University of Petroleum & Minerals (KFUPM) Dhahran 31261 Saudi ArabiaInterdisciplinary Research Center for Hydrogen Technologies and Carbon Management King Fahd University of Petroleum & Minerals (KFUPM) Dhahran 31261 Saudi ArabiaCO2 electroreduction offers a promising approach to reducing the human carbon footprint by converting CO2 into fuels and valuable chemicals. Physical vapor deposition (PVD) techniques, including sputtering, thermal evaporation, and pulsed laser deposition, enable the fabrication of high‐performance catalysts with controlled morphology, strong adhesion, and high purity. These methods allow precise customization of surface features, enhancing catalyst stability and efficiency. PVD facilitates the deposition of various materials, such as metal oxides, alloys, and nanocomposites, making it essential for developing durable catalysts for energy conversion and environmental applications. This review explores the role of PVD in CO2 reduction, focusing on its advantages over alternative deposition techniques like electrodeposition and chemical vapor deposition. It highlights PVD's ability to produce uniform, reproducible films with tailored catalytic properties. Challenges related to scalability, uniformity, and deposition efficiency are discussed, along with potential solutions such as codeposition, multilayer strategies, and hybrid approaches. Future advancements in deposition techniques and material design are also considered to enhance catalyst performance. By addressing these aspects, this review provides insights into optimizing PVD‐based catalysts for efficient and stable CO2 reduction.https://doi.org/10.1002/sstr.202400501CO2 electroreductionphysical vapor depositionpulsed laser depositionsputteringthermal evaporation
spellingShingle Samah A. Mahyoub
Arshad Farid
Muhammad Zain Azeem
Danah A. AL Fadhil
Fahim A. Qaraah
Qasem A. Drmosh
Physical Vapor Deposition Techniques for CO2 Electroreduction: A Review
Small Structures
CO2 electroreduction
physical vapor deposition
pulsed laser deposition
sputtering
thermal evaporation
title Physical Vapor Deposition Techniques for CO2 Electroreduction: A Review
title_full Physical Vapor Deposition Techniques for CO2 Electroreduction: A Review
title_fullStr Physical Vapor Deposition Techniques for CO2 Electroreduction: A Review
title_full_unstemmed Physical Vapor Deposition Techniques for CO2 Electroreduction: A Review
title_short Physical Vapor Deposition Techniques for CO2 Electroreduction: A Review
title_sort physical vapor deposition techniques for co2 electroreduction a review
topic CO2 electroreduction
physical vapor deposition
pulsed laser deposition
sputtering
thermal evaporation
url https://doi.org/10.1002/sstr.202400501
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AT danahaalfadhil physicalvapordepositiontechniquesforco2electroreductionareview
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