Generation-3 Polyamidoamine Dendrimer-Silica Composite: Preparation and Cd(II) Removal Capacity
Generation-3 polyamidoamine (PAMAM) dendrimer was implanted on silica to produce a very good adsorbent (G-3 PAMAM-SGA). The composite was characterized and used for the removal of Cd(II) ions from aqueous solution. Kinetic data fit the Lagergren pseudo-second-order model and also follow the intrapar...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2020-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2020/6662402 |
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| Summary: | Generation-3 polyamidoamine (PAMAM) dendrimer was implanted on silica to produce a very good adsorbent (G-3 PAMAM-SGA). The composite was characterized and used for the removal of Cd(II) ions from aqueous solution. Kinetic data fit the Lagergren pseudo-second-order model and also follow the intraparticle diffusion kinetic model to an extent, which is an indication that the sorption process is controlled by both mechanisms: intraparticle/film layer and adsorption inside the pores/crevices of the composite. Equilibrium sorption data of Cd(II) on G-3 PAMAM-SGA fit the Freundlich isotherm (R2 = 0.9993) which is indicative of multilayered adsorption that occurred on heterogeneous surfaces. The ΔG° values for all temperatures studied were negative, which indicated a spontaneous and feasible process. The result implies that G-3 PAMAM-SGA is a promising adsorbent for microscale scavenging of Cd(II) ions in aqueous solutions. |
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| ISSN: | 2090-9063 2090-9071 |