NH3CH2CH2NH3PhCO2SnPhCl3OH, AN UNEXPECTED ADDUCT: SYNTHESIS AND SPECTROSCOPIC STUDIES
On allowing NH3CH2CH2NH3(PhCO2)2 in slightly hydrated methanol to react with SnPh2Cl2, NH3CH2CH2NH3PhCO2SnPhCl3OH is obtained as a white precipitate. The IR and Mössbauer studies allow to suggest a moiety obtained by addition of OH- and PhCO2- to SnPhCl3, the environment around the tin being octahed...
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2010-07-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
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| Online Access: | http://pubs.ub.ro/dwnl.php?id=CSCC6201011V02S01A0005 |
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| author | Libasse Diop Kochikpa Y.A. Okio |
| author_facet | Libasse Diop Kochikpa Y.A. Okio |
| author_sort | Libasse Diop |
| collection | DOAJ |
| description | On allowing NH3CH2CH2NH3(PhCO2)2 in slightly hydrated methanol to react with SnPh2Cl2, NH3CH2CH2NH3PhCO2SnPhCl3OH is obtained as a white precipitate. The IR and Mössbauer studies allow to suggest a moiety obtained by addition of OH- and PhCO2- to SnPhCl3, the environment around the tin being octahedral, PhCO2- behaving as a monocoordinating ligand. |
| format | Article |
| id | doaj-art-b0fc406507ed49bbbfbe134bb4765f9d |
| institution | OA Journals |
| issn | 1582-540X |
| language | English |
| publishDate | 2010-07-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj-art-b0fc406507ed49bbbfbe134bb4765f9d2025-08-20T02:00:37ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X2010-07-01112299302NH3CH2CH2NH3PhCO2SnPhCl3OH, AN UNEXPECTED ADDUCT: SYNTHESIS AND SPECTROSCOPIC STUDIESLibasse DiopKochikpa Y.A. OkioOn allowing NH3CH2CH2NH3(PhCO2)2 in slightly hydrated methanol to react with SnPh2Cl2, NH3CH2CH2NH3PhCO2SnPhCl3OH is obtained as a white precipitate. The IR and Mössbauer studies allow to suggest a moiety obtained by addition of OH- and PhCO2- to SnPhCl3, the environment around the tin being octahedral, PhCO2- behaving as a monocoordinating ligand.http://pubs.ub.ro/dwnl.php?id=CSCC6201011V02S01A0005phenyl tin compoundbenzoateinfrared spectrumMössbauer spectrumpolymeric structure |
| spellingShingle | Libasse Diop Kochikpa Y.A. Okio NH3CH2CH2NH3PhCO2SnPhCl3OH, AN UNEXPECTED ADDUCT: SYNTHESIS AND SPECTROSCOPIC STUDIES Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry phenyl tin compound benzoate infrared spectrum Mössbauer spectrum polymeric structure |
| title | NH3CH2CH2NH3PhCO2SnPhCl3OH, AN UNEXPECTED ADDUCT: SYNTHESIS AND SPECTROSCOPIC STUDIES |
| title_full | NH3CH2CH2NH3PhCO2SnPhCl3OH, AN UNEXPECTED ADDUCT: SYNTHESIS AND SPECTROSCOPIC STUDIES |
| title_fullStr | NH3CH2CH2NH3PhCO2SnPhCl3OH, AN UNEXPECTED ADDUCT: SYNTHESIS AND SPECTROSCOPIC STUDIES |
| title_full_unstemmed | NH3CH2CH2NH3PhCO2SnPhCl3OH, AN UNEXPECTED ADDUCT: SYNTHESIS AND SPECTROSCOPIC STUDIES |
| title_short | NH3CH2CH2NH3PhCO2SnPhCl3OH, AN UNEXPECTED ADDUCT: SYNTHESIS AND SPECTROSCOPIC STUDIES |
| title_sort | nh3ch2ch2nh3phco2snphcl3oh an unexpected adduct synthesis and spectroscopic studies |
| topic | phenyl tin compound benzoate infrared spectrum Mössbauer spectrum polymeric structure |
| url | http://pubs.ub.ro/dwnl.php?id=CSCC6201011V02S01A0005 |
| work_keys_str_mv | AT libassediop nh3ch2ch2nh3phco2snphcl3ohanunexpectedadductsynthesisandspectroscopicstudies AT kochikpayaokio nh3ch2ch2nh3phco2snphcl3ohanunexpectedadductsynthesisandspectroscopicstudies |