Synthesis and DFT Calculation of a New Series of Enaminones based on 3-amino Coumarin
In this paper, the synthesis of various enaminones from the reaction of 3-aminocoumarin and ethyl-2,4-dioxo-4-arylbutanoate in the presence of p-toluene sulfonic acid is reported. The reaction was examined under different solvents and catalytic systems, which clearly proved the importance of acidic...
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| Format: | Article |
| Language: | English |
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University of Tehran
2020-09-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
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| Online Access: | https://jsciences.ut.ac.ir/article_76455_bf744fd16b0c53749e3353009891fe97.pdf |
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| _version_ | 1849387404737118208 |
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| author | Pegah Nouraie Shahram Moradi Dehaghi Alireza Foroumadi |
| author_facet | Pegah Nouraie Shahram Moradi Dehaghi Alireza Foroumadi |
| author_sort | Pegah Nouraie |
| collection | DOAJ |
| description | In this paper, the synthesis of various enaminones from the reaction of 3-aminocoumarin and ethyl-2,4-dioxo-4-arylbutanoate in the presence of p-toluene sulfonic acid is reported. The reaction was examined under different solvents and catalytic systems, which clearly proved the importance of acidic catalyst in this organic transformation. This work was also accompanied by density functional theory (DFT) studies to justify the formation of final products. |
| format | Article |
| id | doaj-art-b075d7621b924e148feba4e375f6ce71 |
| institution | Kabale University |
| issn | 1016-1104 2345-6914 |
| language | English |
| publishDate | 2020-09-01 |
| publisher | University of Tehran |
| record_format | Article |
| series | Journal of Sciences, Islamic Republic of Iran |
| spelling | doaj-art-b075d7621b924e148feba4e375f6ce712025-08-20T03:53:51ZengUniversity of TehranJournal of Sciences, Islamic Republic of Iran1016-11042345-69142020-09-0131321322010.22059/jsciences.2020.284918.100742576455Synthesis and DFT Calculation of a New Series of Enaminones based on 3-amino CoumarinPegah Nouraie0Shahram Moradi Dehaghi1Alireza Foroumadi2Tehran North Branch, Islamic Azad UniversityTehran North Branch, Islamic Azad UniversityTehran University of Medical SciencesIn this paper, the synthesis of various enaminones from the reaction of 3-aminocoumarin and ethyl-2,4-dioxo-4-arylbutanoate in the presence of p-toluene sulfonic acid is reported. The reaction was examined under different solvents and catalytic systems, which clearly proved the importance of acidic catalyst in this organic transformation. This work was also accompanied by density functional theory (DFT) studies to justify the formation of final products.https://jsciences.ut.ac.ir/article_76455_bf744fd16b0c53749e3353009891fe97.pdf3-aminocoumarinenaminonesdft studies |
| spellingShingle | Pegah Nouraie Shahram Moradi Dehaghi Alireza Foroumadi Synthesis and DFT Calculation of a New Series of Enaminones based on 3-amino Coumarin Journal of Sciences, Islamic Republic of Iran 3-aminocoumarin enaminones dft studies |
| title | Synthesis and DFT Calculation of a New Series of Enaminones based on 3-amino Coumarin |
| title_full | Synthesis and DFT Calculation of a New Series of Enaminones based on 3-amino Coumarin |
| title_fullStr | Synthesis and DFT Calculation of a New Series of Enaminones based on 3-amino Coumarin |
| title_full_unstemmed | Synthesis and DFT Calculation of a New Series of Enaminones based on 3-amino Coumarin |
| title_short | Synthesis and DFT Calculation of a New Series of Enaminones based on 3-amino Coumarin |
| title_sort | synthesis and dft calculation of a new series of enaminones based on 3 amino coumarin |
| topic | 3-aminocoumarin enaminones dft studies |
| url | https://jsciences.ut.ac.ir/article_76455_bf744fd16b0c53749e3353009891fe97.pdf |
| work_keys_str_mv | AT pegahnouraie synthesisanddftcalculationofanewseriesofenaminonesbasedon3aminocoumarin AT shahrammoradidehaghi synthesisanddftcalculationofanewseriesofenaminonesbasedon3aminocoumarin AT alirezaforoumadi synthesisanddftcalculationofanewseriesofenaminonesbasedon3aminocoumarin |