Poly(4‐Vinylpyridine)‐Based Cubosomes: Synthesis, Assembly, and Loading Capabilities
Polymer cubosomes (PCs) are 3D porous microparticles with high surface area that have great potential for applications that require a large interfacial area including catalysis, drug delivery, and energy storage. Most reported PCs are based on chemically inert block copolymers (BCPs) with limited in...
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2024-12-01
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| Series: | Small Science |
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| Online Access: | https://doi.org/10.1002/smsc.202400274 |
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| author | Marcel Schumacher Nadine Tänzer Marius G. Braun Manuel Trömer Giada Quintieri Mahima Goel Markus Heidelmann André H. Gröschel |
| author_facet | Marcel Schumacher Nadine Tänzer Marius G. Braun Manuel Trömer Giada Quintieri Mahima Goel Markus Heidelmann André H. Gröschel |
| author_sort | Marcel Schumacher |
| collection | DOAJ |
| description | Polymer cubosomes (PCs) are 3D porous microparticles with high surface area that have great potential for applications that require a large interfacial area including catalysis, drug delivery, and energy storage. Most reported PCs are based on chemically inert block copolymers (BCPs) with limited intrinsic functionality, which is why they have been mainly used as templating material. Herein, the synthesis, self‐assembly, and loading of poly(4‐vinylpyridine) (P4VP)‐based PCs are reported. The pyridinic moieties are located inside the PC wall and are well‐known functional groups for coordination, cross‐linking, and pH response, which is demonstrated on platinum coordination and pH‐dependent dye release. |
| format | Article |
| id | doaj-art-b043e2fa3b2b4511955218bd3ae647f1 |
| institution | DOAJ |
| issn | 2688-4046 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | Small Science |
| spelling | doaj-art-b043e2fa3b2b4511955218bd3ae647f12025-08-20T02:49:16ZengWiley-VCHSmall Science2688-40462024-12-01412n/an/a10.1002/smsc.202400274Poly(4‐Vinylpyridine)‐Based Cubosomes: Synthesis, Assembly, and Loading CapabilitiesMarcel Schumacher0Nadine Tänzer1Marius G. Braun2Manuel Trömer3Giada Quintieri4Mahima Goel5Markus Heidelmann6André H. Gröschel7Institute of Physical Chemistry and Center for Soft Nanoscience (SoN) University of Münster Busso‐Peus‐Str. 10 Münster 48149 GermanyInstitute of Physical Chemistry and Center for Soft Nanoscience (SoN) University of Münster Busso‐Peus‐Str. 10 Münster 48149 GermanyInstitute of Physical Chemistry and Center for Soft Nanoscience (SoN) University of Münster Busso‐Peus‐Str. 10 Münster 48149 GermanyInstitute of Physical Chemistry and Center for Soft Nanoscience (SoN) University of Münster Busso‐Peus‐Str. 10 Münster 48149 GermanyInstitute of Physical Chemistry and Center for Soft Nanoscience (SoN) University of Münster Busso‐Peus‐Str. 10 Münster 48149 GermanyPolymer Materials for Energy Storage (PES), Bavarian Center for Battery Technology (BayBatt) and Bavarian Polymer Institute (BPI) University of Bayreuth Universitätsstr. 30 Bayreuth 95448 GermanyInterdisciplinary Center for Analytics on the Nanoscale (ICAN) University of Duisburg‐Essen Duisburg 47057 GermanyInternational Graduate School BACCARA University of Münster Münster 48149 GermanyPolymer cubosomes (PCs) are 3D porous microparticles with high surface area that have great potential for applications that require a large interfacial area including catalysis, drug delivery, and energy storage. Most reported PCs are based on chemically inert block copolymers (BCPs) with limited intrinsic functionality, which is why they have been mainly used as templating material. Herein, the synthesis, self‐assembly, and loading of poly(4‐vinylpyridine) (P4VP)‐based PCs are reported. The pyridinic moieties are located inside the PC wall and are well‐known functional groups for coordination, cross‐linking, and pH response, which is demonstrated on platinum coordination and pH‐dependent dye release.https://doi.org/10.1002/smsc.202400274block copolymershybrid materialsinverse morphologiesmesoporous microparticlesself‐assemblies |
| spellingShingle | Marcel Schumacher Nadine Tänzer Marius G. Braun Manuel Trömer Giada Quintieri Mahima Goel Markus Heidelmann André H. Gröschel Poly(4‐Vinylpyridine)‐Based Cubosomes: Synthesis, Assembly, and Loading Capabilities Small Science block copolymers hybrid materials inverse morphologies mesoporous microparticles self‐assemblies |
| title | Poly(4‐Vinylpyridine)‐Based Cubosomes: Synthesis, Assembly, and Loading Capabilities |
| title_full | Poly(4‐Vinylpyridine)‐Based Cubosomes: Synthesis, Assembly, and Loading Capabilities |
| title_fullStr | Poly(4‐Vinylpyridine)‐Based Cubosomes: Synthesis, Assembly, and Loading Capabilities |
| title_full_unstemmed | Poly(4‐Vinylpyridine)‐Based Cubosomes: Synthesis, Assembly, and Loading Capabilities |
| title_short | Poly(4‐Vinylpyridine)‐Based Cubosomes: Synthesis, Assembly, and Loading Capabilities |
| title_sort | poly 4 vinylpyridine based cubosomes synthesis assembly and loading capabilities |
| topic | block copolymers hybrid materials inverse morphologies mesoporous microparticles self‐assemblies |
| url | https://doi.org/10.1002/smsc.202400274 |
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