Efficient Extraction of Butyric Acid from Aqueous Solution using n-Dodecane: Measurement of Equilibrium Data and Thermodynamic Modeling
In this research, the liquid-liquid equilibrium data of the ternary system (water + n-butyric acid + n-dodecane) were obtained at a temperature of 298.2 K and a pressure of 101.3 kPa. The ternary phase diagram was drawn using data of tie-lines obtained from acid-base and Karl Fischer titrations. Han...
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| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Semnan University
2024-08-01
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| Series: | شیمی کاربردی روز |
| Subjects: | |
| Online Access: | https://chemistry.semnan.ac.ir/article_8949_a41bad0ad29fe91e808628012c0299f3.pdf |
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| Summary: | In this research, the liquid-liquid equilibrium data of the ternary system (water + n-butyric acid + n-dodecane) were obtained at a temperature of 298.2 K and a pressure of 101.3 kPa. The ternary phase diagram was drawn using data of tie-lines obtained from acid-base and Karl Fischer titrations. Hand and Othmer-Tobias equations were used to check the correlation of data of tie-lines. The obtained fit coefficients (0.997 for both equations) showed that the tie-lines are reliable. The distribution coefficients and selectivity factors in the two-phase region were obtained in the ranges of 1.88 to 2.14 and 343.78 to 122.44, respectively. The values obtained for these two parameters showed that n-dodecane is a high-efficiency solvent for removing butyric acid from the aqueous phase. NRTL equation was used for thermodynamic modeling of experimental data. The obtained binary interactions were examined after validating the data. The quality of the modeling was evaluated by calculating the root mean square deviations (rmsd). The value obtained for it (1.11%) showed that the modeling was done well. |
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| ISSN: | 2981-2437 |