A comparative study using different resins to determine thorium isotopes

Thorium is a naturally occurring radioactive element that is widely distributed in the crust of the Earth. This element is very common in mineral formations in regions with high levels of natural radioactivity, therefore, its determination in environmental samples is important. Thorium isotopes (228...

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Main Authors: Mychelle Munyck Linhares Rosa, Maria Helena Tirollo Taddei, Luan Teixeira Vieira Cheberle, Paulo Sérgio Cardoso Silva, Vera Akiko Maihara
Format: Article
Language:English
Published: Brazilian Radiation Protection Society (Sociedade Brasileira de Proteção Radiológica, SBPR) 2019-02-01
Series:Brazilian Journal of Radiation Sciences
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Online Access:https://bjrs.org.br/revista/index.php/REVISTA/article/view/644
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author Mychelle Munyck Linhares Rosa
Maria Helena Tirollo Taddei
Luan Teixeira Vieira Cheberle
Paulo Sérgio Cardoso Silva
Vera Akiko Maihara
author_facet Mychelle Munyck Linhares Rosa
Maria Helena Tirollo Taddei
Luan Teixeira Vieira Cheberle
Paulo Sérgio Cardoso Silva
Vera Akiko Maihara
author_sort Mychelle Munyck Linhares Rosa
collection DOAJ
description Thorium is a naturally occurring radioactive element that is widely distributed in the crust of the Earth. This element is very common in mineral formations in regions with high levels of natural radioactivity, therefore, its determination in environmental samples is important. Thorium isotopes (228Th, 230Th, and 232Th) were determined in a reference material, the IAEA Soil 327 sample, to validate the two methods, these isotopes were also analyzed in two groups of food samples, employing these different resins. The initial preparation with acid dissolution is the same to both, in the first is used anion exchange resin (DOWEX 1x2) and electrodeposition in silver planchets. And in the second method is used a specific chromatographic resin (TEVA) and cerium fluoride microprecipitation. At the end both analysis are quantified by alpha spectrometry. The two methods the results obtained were satisfactory for the reference material used, with relative error of less than 4% for 228Th, 230Th, and 232Th. The analysis of variance for samples foods analyzed seen to be no significant difference between the methods used for thorium isotopes determination. The main differences found between methods were spectrums resolutions, time and cost of analysis.
format Article
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institution Kabale University
issn 2319-0612
language English
publishDate 2019-02-01
publisher Brazilian Radiation Protection Society (Sociedade Brasileira de Proteção Radiológica, SBPR)
record_format Article
series Brazilian Journal of Radiation Sciences
spelling doaj-art-aed8d97c35fa4f86aa60009c33783f812025-08-20T03:27:36ZengBrazilian Radiation Protection Society (Sociedade Brasileira de Proteção Radiológica, SBPR)Brazilian Journal of Radiation Sciences2319-06122019-02-0172A (Suppl.)10.15392/bjrs.v7i2A.644498A comparative study using different resins to determine thorium isotopesMychelle Munyck Linhares Rosa0Maria Helena Tirollo Taddei1Luan Teixeira Vieira Cheberle2Paulo Sérgio Cardoso Silva3Vera Akiko Maihara4IPEN - Instituto de Pesquisas Energéticas e Nucleares Comissão Nacional de Energia Nuclear / Laboratório de Poços de Caldas - CNEN / LAPOC Ambientis RadioproteçãoComissão Nacional de Energia Nuclear / Laboratório de Poços de Caldas - CNEN / LAPOCAmbientis RadioproteçãoIPEN - Instituto de Pesquisas Energéticas e NuclearesIPEN - Instituto de Pesquisas Energéticas e NuclearesThorium is a naturally occurring radioactive element that is widely distributed in the crust of the Earth. This element is very common in mineral formations in regions with high levels of natural radioactivity, therefore, its determination in environmental samples is important. Thorium isotopes (228Th, 230Th, and 232Th) were determined in a reference material, the IAEA Soil 327 sample, to validate the two methods, these isotopes were also analyzed in two groups of food samples, employing these different resins. The initial preparation with acid dissolution is the same to both, in the first is used anion exchange resin (DOWEX 1x2) and electrodeposition in silver planchets. And in the second method is used a specific chromatographic resin (TEVA) and cerium fluoride microprecipitation. At the end both analysis are quantified by alpha spectrometry. The two methods the results obtained were satisfactory for the reference material used, with relative error of less than 4% for 228Th, 230Th, and 232Th. The analysis of variance for samples foods analyzed seen to be no significant difference between the methods used for thorium isotopes determination. The main differences found between methods were spectrums resolutions, time and cost of analysis.https://bjrs.org.br/revista/index.php/REVISTA/article/view/644thorium isotopeselectrodepositionmicroprecipitation.
spellingShingle Mychelle Munyck Linhares Rosa
Maria Helena Tirollo Taddei
Luan Teixeira Vieira Cheberle
Paulo Sérgio Cardoso Silva
Vera Akiko Maihara
A comparative study using different resins to determine thorium isotopes
Brazilian Journal of Radiation Sciences
thorium isotopes
electrodeposition
microprecipitation.
title A comparative study using different resins to determine thorium isotopes
title_full A comparative study using different resins to determine thorium isotopes
title_fullStr A comparative study using different resins to determine thorium isotopes
title_full_unstemmed A comparative study using different resins to determine thorium isotopes
title_short A comparative study using different resins to determine thorium isotopes
title_sort comparative study using different resins to determine thorium isotopes
topic thorium isotopes
electrodeposition
microprecipitation.
url https://bjrs.org.br/revista/index.php/REVISTA/article/view/644
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