Assessment of the Use of Epicarp and Mesocarp of Green Coconut for Removal of Fluoride Ions in Aqueous Solution

Fruit consumption and processing result in considerable volumes of residual biomass. Transformation of this biomass into biosorbents offers an alternative for its reuse and disposal. As the green coconut shell is a waste often discarded in landfills and dumps, generating gases and leachate, two bios...

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Main Authors: César Augusto Canciam, Nehemias Curvelo Pereira
Format: Article
Language:English
Published: Wiley 2019-01-01
Series:International Journal of Chemical Engineering
Online Access:http://dx.doi.org/10.1155/2019/7163812
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author César Augusto Canciam
Nehemias Curvelo Pereira
author_facet César Augusto Canciam
Nehemias Curvelo Pereira
author_sort César Augusto Canciam
collection DOAJ
description Fruit consumption and processing result in considerable volumes of residual biomass. Transformation of this biomass into biosorbents offers an alternative for its reuse and disposal. As the green coconut shell is a waste often discarded in landfills and dumps, generating gases and leachate, two biosorbents were developed from the epicarp and mesocarp of green coconut to adsorb fluoride ions in aqueous solution. The kinetic experiments showed that sorption of fluoride ions reached equilibrium at 300 min for both epicarp and mesocarp at temperatures of 25°C, 35°C, and 45°C. The removal efficiency of fluoride ions varied from 66.25% (at 25°C) to 77.50% (at 45°C) for the epicarp and from 90% (at 25°C) to 97.50% (at 45°C) for the mesocarp. The thermodynamic parameters of the adsorption process showed that adsorption is a spontaneous, endothermic process for both biosorbents. The adsorption was classified as chemical, with the Langmuir isotherm model best suited to the adsorption isotherms data.
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institution Kabale University
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language English
publishDate 2019-01-01
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spelling doaj-art-ae6c2d19c15949c9a2c83b5f5129b56d2025-02-03T01:20:19ZengWileyInternational Journal of Chemical Engineering1687-806X1687-80782019-01-01201910.1155/2019/71638127163812Assessment of the Use of Epicarp and Mesocarp of Green Coconut for Removal of Fluoride Ions in Aqueous SolutionCésar Augusto Canciam0Nehemias Curvelo Pereira1M.Sc. in Chemical Engineering, Academic Department of Chemical Engineering, Federal University of Technology-Paraná, Ponta Grossa, BrazilPh.D. in Chemical Engineering, Chemical Engineering Department, State University of Maringá, Maringá, BrazilFruit consumption and processing result in considerable volumes of residual biomass. Transformation of this biomass into biosorbents offers an alternative for its reuse and disposal. As the green coconut shell is a waste often discarded in landfills and dumps, generating gases and leachate, two biosorbents were developed from the epicarp and mesocarp of green coconut to adsorb fluoride ions in aqueous solution. The kinetic experiments showed that sorption of fluoride ions reached equilibrium at 300 min for both epicarp and mesocarp at temperatures of 25°C, 35°C, and 45°C. The removal efficiency of fluoride ions varied from 66.25% (at 25°C) to 77.50% (at 45°C) for the epicarp and from 90% (at 25°C) to 97.50% (at 45°C) for the mesocarp. The thermodynamic parameters of the adsorption process showed that adsorption is a spontaneous, endothermic process for both biosorbents. The adsorption was classified as chemical, with the Langmuir isotherm model best suited to the adsorption isotherms data.http://dx.doi.org/10.1155/2019/7163812
spellingShingle César Augusto Canciam
Nehemias Curvelo Pereira
Assessment of the Use of Epicarp and Mesocarp of Green Coconut for Removal of Fluoride Ions in Aqueous Solution
International Journal of Chemical Engineering
title Assessment of the Use of Epicarp and Mesocarp of Green Coconut for Removal of Fluoride Ions in Aqueous Solution
title_full Assessment of the Use of Epicarp and Mesocarp of Green Coconut for Removal of Fluoride Ions in Aqueous Solution
title_fullStr Assessment of the Use of Epicarp and Mesocarp of Green Coconut for Removal of Fluoride Ions in Aqueous Solution
title_full_unstemmed Assessment of the Use of Epicarp and Mesocarp of Green Coconut for Removal of Fluoride Ions in Aqueous Solution
title_short Assessment of the Use of Epicarp and Mesocarp of Green Coconut for Removal of Fluoride Ions in Aqueous Solution
title_sort assessment of the use of epicarp and mesocarp of green coconut for removal of fluoride ions in aqueous solution
url http://dx.doi.org/10.1155/2019/7163812
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AT nehemiascurvelopereira assessmentoftheuseofepicarpandmesocarpofgreencoconutforremovaloffluorideionsinaqueoussolution