Occurrence, Migration Behavior, and Environmental Burden of Phthalate Esters in Flooring Materials Used in Newly Renovated Chinese Homes

Phthalic acid esters (PAEs), a class of synthetic semi-volatile organic compounds, are extensively incorporated into decorative materials. However, their specific occurrence, migration behaviors, and environmental impact on these materials—which comprise the largest surface areas in residential sett...

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Main Authors: Ying Zhang, Li-Bo Chen, Hao-Yang Shen, Zi-Chao Wu, Ning-Zheng Zhu, Chong-Jing Gao, Ying Guo
Format: Article
Language:English
Published: MDPI AG 2025-06-01
Series:Toxics
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Online Access:https://www.mdpi.com/2305-6304/13/7/517
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author Ying Zhang
Li-Bo Chen
Hao-Yang Shen
Zi-Chao Wu
Ning-Zheng Zhu
Chong-Jing Gao
Ying Guo
author_facet Ying Zhang
Li-Bo Chen
Hao-Yang Shen
Zi-Chao Wu
Ning-Zheng Zhu
Chong-Jing Gao
Ying Guo
author_sort Ying Zhang
collection DOAJ
description Phthalic acid esters (PAEs), a class of synthetic semi-volatile organic compounds, are extensively incorporated into decorative materials. However, their specific occurrence, migration behaviors, and environmental impact on these materials—which comprise the largest surface areas in residential settings—remain insufficiently understood. This study investigated the distribution, emission dynamics, and environmental burdens of PAEs in flooring commonly used in Chinese households. The results showed that PAEs are widespread in flooring, with total concentrations ranging from 1220 to 166,000 ng/g (14,100 ng/g, median value). Solid wood flooring (55,900 ng/g) exhibited significantly higher PAE levels compared to engineered flooring (22,600 ng/g) and laminate flooring (4000 ng/g) (<i>p</i> < 0.05). Migration experiments revealed that solid wood flooring tended to continuously release PAEs, laminate flooring showed a pronounced capacity for PAE absorption, and engineered flooring exhibited both release and absorption behaviors. The initial PAE concentration is the dominant factor influencing migration rates, while the flooring type and substrate density also contribute to varying degrees. The estimated environmental burdens of PAEs resulting from flooring in newly renovated Chinese households ranged from 3.63 × 10<sup>9</sup> ng to 3.45 × 10<sup>11</sup> ng, with a median value of 1.23 × 10<sup>10</sup> ng. Households in the eastern and southwestern regions exhibited the highest PAE burdens, while the southern region showed the lowest. Socioeconomic factors such as residential floor area, number of rooms, household income, and renovation budget significantly influenced the environmental burden of PAEs derived from flooring.
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spelling doaj-art-adf582bdd4a44f71b973a7aaa53baa112025-08-20T03:08:13ZengMDPI AGToxics2305-63042025-06-0113751710.3390/toxics13070517Occurrence, Migration Behavior, and Environmental Burden of Phthalate Esters in Flooring Materials Used in Newly Renovated Chinese HomesYing Zhang0Li-Bo Chen1Hao-Yang Shen2Zi-Chao Wu3Ning-Zheng Zhu4Chong-Jing Gao5Ying Guo6Zhejiang Provincial Top Discipline of Biological Engineering (Level A), Zhejiang Wanli University, Ningbo 315100, ChinaZhejiang Provincial Top Discipline of Biological Engineering (Level A), Zhejiang Wanli University, Ningbo 315100, ChinaZhejiang Provincial Top Discipline of Biological Engineering (Level A), Zhejiang Wanli University, Ningbo 315100, ChinaZhejiang Provincial Top Discipline of Biological Engineering (Level A), Zhejiang Wanli University, Ningbo 315100, ChinaState Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, ChinaZhejiang Provincial Top Discipline of Biological Engineering (Level A), Zhejiang Wanli University, Ningbo 315100, ChinaGuangdong Key Laboratory of Environmental Pollution and Health, College of Environment and Climate, Jinan University, Guangzhou 510632, ChinaPhthalic acid esters (PAEs), a class of synthetic semi-volatile organic compounds, are extensively incorporated into decorative materials. However, their specific occurrence, migration behaviors, and environmental impact on these materials—which comprise the largest surface areas in residential settings—remain insufficiently understood. This study investigated the distribution, emission dynamics, and environmental burdens of PAEs in flooring commonly used in Chinese households. The results showed that PAEs are widespread in flooring, with total concentrations ranging from 1220 to 166,000 ng/g (14,100 ng/g, median value). Solid wood flooring (55,900 ng/g) exhibited significantly higher PAE levels compared to engineered flooring (22,600 ng/g) and laminate flooring (4000 ng/g) (<i>p</i> < 0.05). Migration experiments revealed that solid wood flooring tended to continuously release PAEs, laminate flooring showed a pronounced capacity for PAE absorption, and engineered flooring exhibited both release and absorption behaviors. The initial PAE concentration is the dominant factor influencing migration rates, while the flooring type and substrate density also contribute to varying degrees. The estimated environmental burdens of PAEs resulting from flooring in newly renovated Chinese households ranged from 3.63 × 10<sup>9</sup> ng to 3.45 × 10<sup>11</sup> ng, with a median value of 1.23 × 10<sup>10</sup> ng. Households in the eastern and southwestern regions exhibited the highest PAE burdens, while the southern region showed the lowest. Socioeconomic factors such as residential floor area, number of rooms, household income, and renovation budget significantly influenced the environmental burden of PAEs derived from flooring.https://www.mdpi.com/2305-6304/13/7/517phthalatesflooringmigrationenvironmental burden
spellingShingle Ying Zhang
Li-Bo Chen
Hao-Yang Shen
Zi-Chao Wu
Ning-Zheng Zhu
Chong-Jing Gao
Ying Guo
Occurrence, Migration Behavior, and Environmental Burden of Phthalate Esters in Flooring Materials Used in Newly Renovated Chinese Homes
Toxics
phthalates
flooring
migration
environmental burden
title Occurrence, Migration Behavior, and Environmental Burden of Phthalate Esters in Flooring Materials Used in Newly Renovated Chinese Homes
title_full Occurrence, Migration Behavior, and Environmental Burden of Phthalate Esters in Flooring Materials Used in Newly Renovated Chinese Homes
title_fullStr Occurrence, Migration Behavior, and Environmental Burden of Phthalate Esters in Flooring Materials Used in Newly Renovated Chinese Homes
title_full_unstemmed Occurrence, Migration Behavior, and Environmental Burden of Phthalate Esters in Flooring Materials Used in Newly Renovated Chinese Homes
title_short Occurrence, Migration Behavior, and Environmental Burden of Phthalate Esters in Flooring Materials Used in Newly Renovated Chinese Homes
title_sort occurrence migration behavior and environmental burden of phthalate esters in flooring materials used in newly renovated chinese homes
topic phthalates
flooring
migration
environmental burden
url https://www.mdpi.com/2305-6304/13/7/517
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