Extraordinarily persistent photo-induced carriers mediated by interfacial exciton splitter in organic single-crystalline semiconductors

Exciton dissociation into free electron-hole carriers is a central issue in optoelectronic devices. Despite recent progress in free-carrier generation due to an admixture of organic compounds, strategies to prolong the lifetime of photo-induced carriers are limited. Herein, we present a proof-of-con...

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Main Authors: Nobutaka Osakabe, Akifumi Yamamura, Tatsuyuki Makita, Yasunari Tamai, Shun Watanabe, Jun Takeya
Format: Article
Language:English
Published: IOP Publishing 2025-01-01
Series:Applied Physics Express
Subjects:
Online Access:https://doi.org/10.35848/1882-0786/adcefa
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author Nobutaka Osakabe
Akifumi Yamamura
Tatsuyuki Makita
Yasunari Tamai
Shun Watanabe
Jun Takeya
author_facet Nobutaka Osakabe
Akifumi Yamamura
Tatsuyuki Makita
Yasunari Tamai
Shun Watanabe
Jun Takeya
author_sort Nobutaka Osakabe
collection DOAJ
description Exciton dissociation into free electron-hole carriers is a central issue in optoelectronic devices. Despite recent progress in free-carrier generation due to an admixture of organic compounds, strategies to prolong the lifetime of photo-induced carriers are limited. Herein, we present a proof-of-concept of efficient exciton dissociation via heterogeneous device engineering; an insulating polymer layer adjacent to organic semiconductors (OSCs) in conjunction with an application of electrical voltage can capture photogenerated electrons selectively, and the resulting semipermanent built-in electric field gives rise to extraordinarily persistent photo-induced carriers, which lasts for more than half a year in single-crystalline OSCs.
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publishDate 2025-01-01
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series Applied Physics Express
spelling doaj-art-adbae2b506f84eb881916d4ba45d557e2025-08-20T02:16:44ZengIOP PublishingApplied Physics Express1882-07862025-01-0118505100110.35848/1882-0786/adcefaExtraordinarily persistent photo-induced carriers mediated by interfacial exciton splitter in organic single-crystalline semiconductorsNobutaka Osakabe0Akifumi Yamamura1Tatsuyuki Makita2Yasunari Tamai3Shun Watanabe4https://orcid.org/0000-0001-7377-6043Jun Takeya5Department of Advanced Material Science, Graduate School of Frontier Science, The University of Tokyo , 5-1-5 Kashiwanoha, Kashiwa Chiba, 277-8561, JapanDepartment of Advanced Material Science, Graduate School of Frontier Science, The University of Tokyo , 5-1-5 Kashiwanoha, Kashiwa Chiba, 277-8561, JapanDepartment of Advanced Material Science, Graduate School of Frontier Science, The University of Tokyo , 5-1-5 Kashiwanoha, Kashiwa Chiba, 277-8561, JapanDepartment of Advanced Material Science, Graduate School of Frontier Science, The University of Tokyo , 5-1-5 Kashiwanoha, Kashiwa Chiba, 277-8561, JapanDepartment of Advanced Material Science, Graduate School of Frontier Science, The University of Tokyo , 5-1-5 Kashiwanoha, Kashiwa Chiba, 277-8561, JapanDepartment of Advanced Material Science, Graduate School of Frontier Science, The University of Tokyo , 5-1-5 Kashiwanoha, Kashiwa Chiba, 277-8561, Japan; International Center for Materials Nanoarchitectonics (WPI-MANA) , National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba Ibaraki, 205-0044, Japan; JST , CREST, 4-1-8 Honcho, Kawaguchi Saitama, 332-0012, JapanExciton dissociation into free electron-hole carriers is a central issue in optoelectronic devices. Despite recent progress in free-carrier generation due to an admixture of organic compounds, strategies to prolong the lifetime of photo-induced carriers are limited. Herein, we present a proof-of-concept of efficient exciton dissociation via heterogeneous device engineering; an insulating polymer layer adjacent to organic semiconductors (OSCs) in conjunction with an application of electrical voltage can capture photogenerated electrons selectively, and the resulting semipermanent built-in electric field gives rise to extraordinarily persistent photo-induced carriers, which lasts for more than half a year in single-crystalline OSCs.https://doi.org/10.35848/1882-0786/adcefaorganic semiconductorssingle-crystalline filmsexciton splittingthin-film transistorsnon-volatile memories
spellingShingle Nobutaka Osakabe
Akifumi Yamamura
Tatsuyuki Makita
Yasunari Tamai
Shun Watanabe
Jun Takeya
Extraordinarily persistent photo-induced carriers mediated by interfacial exciton splitter in organic single-crystalline semiconductors
Applied Physics Express
organic semiconductors
single-crystalline films
exciton splitting
thin-film transistors
non-volatile memories
title Extraordinarily persistent photo-induced carriers mediated by interfacial exciton splitter in organic single-crystalline semiconductors
title_full Extraordinarily persistent photo-induced carriers mediated by interfacial exciton splitter in organic single-crystalline semiconductors
title_fullStr Extraordinarily persistent photo-induced carriers mediated by interfacial exciton splitter in organic single-crystalline semiconductors
title_full_unstemmed Extraordinarily persistent photo-induced carriers mediated by interfacial exciton splitter in organic single-crystalline semiconductors
title_short Extraordinarily persistent photo-induced carriers mediated by interfacial exciton splitter in organic single-crystalline semiconductors
title_sort extraordinarily persistent photo induced carriers mediated by interfacial exciton splitter in organic single crystalline semiconductors
topic organic semiconductors
single-crystalline films
exciton splitting
thin-film transistors
non-volatile memories
url https://doi.org/10.35848/1882-0786/adcefa
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