Regulating Topographical Deformation Response of Liquid Crystal Coatings by Electrical Quenching of Liquid Crystal Order Fluctuation

Alignment of liquid crystals (LCs) is critical for actuation of LC polymer‐based devices. A common strategy to induce surface deformation in LC polymer coatings involves engineering the polymers into multidomain configurations. The application of an electric field serves as an efficient means to ach...

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Main Author: Wei Feng
Format: Article
Language:English
Published: Wiley-VCH 2025-08-01
Series:Small Structures
Subjects:
Online Access:https://doi.org/10.1002/sstr.202500051
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author Wei Feng
author_facet Wei Feng
author_sort Wei Feng
collection DOAJ
description Alignment of liquid crystals (LCs) is critical for actuation of LC polymer‐based devices. A common strategy to induce surface deformation in LC polymer coatings involves engineering the polymers into multidomain configurations. The application of an electric field serves as an efficient means to achieve this goal. While LCs are partially ordered fluids characterized by intrinsic dynamic disorder and order fluctuations, these fluctuations can be suppressed by electric fields, a phenomenon known as electrical quenching. However, the impact of quenching LC order fluctuations on the molecular actuation behavior of LC polymers remains insufficiently understood. Herein, the translation of the electric quenching effect on LC order from the molecular scale to the macroscopic level, with a focus on regulating the topographical deformation of polymerized LC polymer coatings, is demonstrated. The findings reveal that the suppression of monomeric LC order fluctuations through electric quenching significantly reduces the topographical deformation of the polymerized network. This advancement offers new opportunities for fabricating tunable surfaces with complex patterns, broadening the potential applications of LC‐based dynamic surfaces.
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spelling doaj-art-acd0dad65dea476abc92f939d8a33bcd2025-08-20T03:59:25ZengWiley-VCHSmall Structures2688-40622025-08-0168n/an/a10.1002/sstr.202500051Regulating Topographical Deformation Response of Liquid Crystal Coatings by Electrical Quenching of Liquid Crystal Order FluctuationWei Feng0CAS Key Laboratory of Mechanical Behavior and Design of Materials Institute of Humanoid Robots Department of Modern Mechanics University of Science and Technology of China Hefei 230027 ChinaAlignment of liquid crystals (LCs) is critical for actuation of LC polymer‐based devices. A common strategy to induce surface deformation in LC polymer coatings involves engineering the polymers into multidomain configurations. The application of an electric field serves as an efficient means to achieve this goal. While LCs are partially ordered fluids characterized by intrinsic dynamic disorder and order fluctuations, these fluctuations can be suppressed by electric fields, a phenomenon known as electrical quenching. However, the impact of quenching LC order fluctuations on the molecular actuation behavior of LC polymers remains insufficiently understood. Herein, the translation of the electric quenching effect on LC order from the molecular scale to the macroscopic level, with a focus on regulating the topographical deformation of polymerized LC polymer coatings, is demonstrated. The findings reveal that the suppression of monomeric LC order fluctuations through electric quenching significantly reduces the topographical deformation of the polymerized network. This advancement offers new opportunities for fabricating tunable surfaces with complex patterns, broadening the potential applications of LC‐based dynamic surfaces.https://doi.org/10.1002/sstr.202500051liquid crystal alignmentsliquid crystal polymersorder fluctuation quenchingsurface topography
spellingShingle Wei Feng
Regulating Topographical Deformation Response of Liquid Crystal Coatings by Electrical Quenching of Liquid Crystal Order Fluctuation
Small Structures
liquid crystal alignments
liquid crystal polymers
order fluctuation quenching
surface topography
title Regulating Topographical Deformation Response of Liquid Crystal Coatings by Electrical Quenching of Liquid Crystal Order Fluctuation
title_full Regulating Topographical Deformation Response of Liquid Crystal Coatings by Electrical Quenching of Liquid Crystal Order Fluctuation
title_fullStr Regulating Topographical Deformation Response of Liquid Crystal Coatings by Electrical Quenching of Liquid Crystal Order Fluctuation
title_full_unstemmed Regulating Topographical Deformation Response of Liquid Crystal Coatings by Electrical Quenching of Liquid Crystal Order Fluctuation
title_short Regulating Topographical Deformation Response of Liquid Crystal Coatings by Electrical Quenching of Liquid Crystal Order Fluctuation
title_sort regulating topographical deformation response of liquid crystal coatings by electrical quenching of liquid crystal order fluctuation
topic liquid crystal alignments
liquid crystal polymers
order fluctuation quenching
surface topography
url https://doi.org/10.1002/sstr.202500051
work_keys_str_mv AT weifeng regulatingtopographicaldeformationresponseofliquidcrystalcoatingsbyelectricalquenchingofliquidcrystalorderfluctuation