Groundwater quality beyond potability: decoding the hydrogeochemical signatures using spatial and statistical methods in regions of Dindigul District, Tamil Nadu

Abstract Groundwater in the Jivalsaragu area of Dindigul district, Tamil Nadu, is essential for domestic and agricultural purposes. However, contamination from the usage of excessive fertilizers and natural weathering of charnockite & migmatite have significantly deteriorated the groundwater qua...

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Main Authors: Pragadeeshwaran Kannan, Gurugnanam Balasubramaniyan, Shankar Karuppannan, Bairavi Swaminathan, S. Chrisben Sam, Bagyaraj Murugesan
Format: Article
Language:English
Published: Springer 2025-08-01
Series:Discover Sustainability
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Online Access:https://doi.org/10.1007/s43621-025-01344-0
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author Pragadeeshwaran Kannan
Gurugnanam Balasubramaniyan
Shankar Karuppannan
Bairavi Swaminathan
S. Chrisben Sam
Bagyaraj Murugesan
author_facet Pragadeeshwaran Kannan
Gurugnanam Balasubramaniyan
Shankar Karuppannan
Bairavi Swaminathan
S. Chrisben Sam
Bagyaraj Murugesan
author_sort Pragadeeshwaran Kannan
collection DOAJ
description Abstract Groundwater in the Jivalsaragu area of Dindigul district, Tamil Nadu, is essential for domestic and agricultural purposes. However, contamination from the usage of excessive fertilizers and natural weathering of charnockite & migmatite have significantly deteriorated the groundwater quality in the study area, highlighting the need for a comprehensive assessment. The results reveal that the groundwater is alkaline and hard, primarily due to elevated levels of Ca2+, Mg2+ and HCO3 −, which reduce its suitability for domestic purposes. Hydrogeochemical analysis, irrigation suitability indices, and statistical methods such as correlation and principal component analysis were applied. Significant pollution was observed, with 95% magnesium, 85% sulphate, and 60% calcium above acceptable limits due to fertilizer leaching and mineral dissolution. According to Gibbs, evaporation is the fundamental driver of groundwater chemistry, and Correlation shows significant interaction among parameters, such as strong positive trends between electrical conductivity and total dissolved solids. Principal Component Analysis (PCA1-4) revealed that mineral concentration and salinity are the most critical factors influencing groundwater quality. Wilcox indicates that 50% of the samples were unsuitable due to sodium and chloride enrichment. Water Quality Index (WQI) implies that 50% of water is extremely poor, 25% very poor, and 20% unsuitable due to rock-weathering and anthropogenic inputs. The irrigation indices (SAR, KR, SSP, and MAR) reveal that 70% of the water can be used for irrigation after treatment, while the rest is inappropriate. The findings conclude that the study area requires groundwater management steps such as treatment, aquifer recharge systems and sustainable irrigation.
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spelling doaj-art-ac5f785a6c094121b2ea28c04b0a74fe2025-08-20T03:42:22ZengSpringerDiscover Sustainability2662-99842025-08-016112210.1007/s43621-025-01344-0Groundwater quality beyond potability: decoding the hydrogeochemical signatures using spatial and statistical methods in regions of Dindigul District, Tamil NaduPragadeeshwaran Kannan0Gurugnanam Balasubramaniyan1Shankar Karuppannan2Bairavi Swaminathan3S. Chrisben Sam4Bagyaraj Murugesan5Centre for Applied Geology, The Gandhigram Rural Institute (Deemed to be University)Centre for Applied Geology, The Gandhigram Rural Institute (Deemed to be University)Department of Applied Geology, College of Applied Natural Science, Adama Science and Technology UniversityCentre for Applied Geology, The Gandhigram Rural Institute (Deemed to be University)Centre for Applied Geology, The Gandhigram Rural Institute (Deemed to be University)Centre for Applied Geology, The Gandhigram Rural Institute (Deemed to be University)Abstract Groundwater in the Jivalsaragu area of Dindigul district, Tamil Nadu, is essential for domestic and agricultural purposes. However, contamination from the usage of excessive fertilizers and natural weathering of charnockite & migmatite have significantly deteriorated the groundwater quality in the study area, highlighting the need for a comprehensive assessment. The results reveal that the groundwater is alkaline and hard, primarily due to elevated levels of Ca2+, Mg2+ and HCO3 −, which reduce its suitability for domestic purposes. Hydrogeochemical analysis, irrigation suitability indices, and statistical methods such as correlation and principal component analysis were applied. Significant pollution was observed, with 95% magnesium, 85% sulphate, and 60% calcium above acceptable limits due to fertilizer leaching and mineral dissolution. According to Gibbs, evaporation is the fundamental driver of groundwater chemistry, and Correlation shows significant interaction among parameters, such as strong positive trends between electrical conductivity and total dissolved solids. Principal Component Analysis (PCA1-4) revealed that mineral concentration and salinity are the most critical factors influencing groundwater quality. Wilcox indicates that 50% of the samples were unsuitable due to sodium and chloride enrichment. Water Quality Index (WQI) implies that 50% of water is extremely poor, 25% very poor, and 20% unsuitable due to rock-weathering and anthropogenic inputs. The irrigation indices (SAR, KR, SSP, and MAR) reveal that 70% of the water can be used for irrigation after treatment, while the rest is inappropriate. The findings conclude that the study area requires groundwater management steps such as treatment, aquifer recharge systems and sustainable irrigation.https://doi.org/10.1007/s43621-025-01344-0HydrogeochemistryGISPrincipal component analysisGroundwater quality indexIrrigation indices
spellingShingle Pragadeeshwaran Kannan
Gurugnanam Balasubramaniyan
Shankar Karuppannan
Bairavi Swaminathan
S. Chrisben Sam
Bagyaraj Murugesan
Groundwater quality beyond potability: decoding the hydrogeochemical signatures using spatial and statistical methods in regions of Dindigul District, Tamil Nadu
Discover Sustainability
Hydrogeochemistry
GIS
Principal component analysis
Groundwater quality index
Irrigation indices
title Groundwater quality beyond potability: decoding the hydrogeochemical signatures using spatial and statistical methods in regions of Dindigul District, Tamil Nadu
title_full Groundwater quality beyond potability: decoding the hydrogeochemical signatures using spatial and statistical methods in regions of Dindigul District, Tamil Nadu
title_fullStr Groundwater quality beyond potability: decoding the hydrogeochemical signatures using spatial and statistical methods in regions of Dindigul District, Tamil Nadu
title_full_unstemmed Groundwater quality beyond potability: decoding the hydrogeochemical signatures using spatial and statistical methods in regions of Dindigul District, Tamil Nadu
title_short Groundwater quality beyond potability: decoding the hydrogeochemical signatures using spatial and statistical methods in regions of Dindigul District, Tamil Nadu
title_sort groundwater quality beyond potability decoding the hydrogeochemical signatures using spatial and statistical methods in regions of dindigul district tamil nadu
topic Hydrogeochemistry
GIS
Principal component analysis
Groundwater quality index
Irrigation indices
url https://doi.org/10.1007/s43621-025-01344-0
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