A novel design for continuous measurement of CO2 from deep remineralization of petrogenic organic carbon

Abstract The oxidation of petrogenic organic carbon contributes a large CO2 flux to the atmosphere, regulating the geological carbon cycle. While few in situ fluxes have been measured in near‐surface sedimentary rocks, deep fracture‐controlled metamorphic terranes remain unexplored. Here, we present...

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Main Authors: Wan‐Yin Lien, Rick Chen, Jui‐Fen Tsai, Jhen‐Nien Chen, Li‐Hung Lin, Pei‐Ling Wang
Format: Article
Language:English
Published: Wiley 2025-05-01
Series:Vadose Zone Journal
Online Access:https://doi.org/10.1002/vzj2.70020
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author Wan‐Yin Lien
Rick Chen
Jui‐Fen Tsai
Jhen‐Nien Chen
Li‐Hung Lin
Pei‐Ling Wang
author_facet Wan‐Yin Lien
Rick Chen
Jui‐Fen Tsai
Jhen‐Nien Chen
Li‐Hung Lin
Pei‐Ling Wang
author_sort Wan‐Yin Lien
collection DOAJ
description Abstract The oxidation of petrogenic organic carbon contributes a large CO2 flux to the atmosphere, regulating the geological carbon cycle. While few in situ fluxes have been measured in near‐surface sedimentary rocks, deep fracture‐controlled metamorphic terranes remain unexplored. Here, we present a novel design for continuous in situ measurements of subsurface CO2 flux feasible for metamorphic rocks. The accumulative CO2 measurements were performed by either the passive mode or active recirculation on an 80‐m deep borehole in eastern Taiwan. Measurements in the passive mode yielded stepwise CO2 releases in the fractured zone and steady accumulation in the pulverized zone at rates (18.9–132 mgC m−2 day−1) resembling those for other active orogens. By contrast, the active recirculation produced an overestimation of CO2 flux. The high flux combined with variation patterns highlights heterogeneous metamorphic terranes as an important CO2 source and the necessities of extended monitoring using the passive mode.
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institution Kabale University
issn 1539-1663
language English
publishDate 2025-05-01
publisher Wiley
record_format Article
series Vadose Zone Journal
spelling doaj-art-ac039626671a4459a7990722908596fa2025-08-20T03:27:47ZengWileyVadose Zone Journal1539-16632025-05-01243n/an/a10.1002/vzj2.70020A novel design for continuous measurement of CO2 from deep remineralization of petrogenic organic carbonWan‐Yin Lien0Rick Chen1Jui‐Fen Tsai2Jhen‐Nien Chen3Li‐Hung Lin4Pei‐Ling Wang5Department of Geosciences National Taiwan University Taipei TaiwanInstitute of Oceanography National Taiwan University Taipei TaiwanDepartment of Geosciences National Taiwan University Taipei TaiwanDepartment of Geosciences National Taiwan University Taipei TaiwanDepartment of Geosciences National Taiwan University Taipei TaiwanInstitute of Oceanography National Taiwan University Taipei TaiwanAbstract The oxidation of petrogenic organic carbon contributes a large CO2 flux to the atmosphere, regulating the geological carbon cycle. While few in situ fluxes have been measured in near‐surface sedimentary rocks, deep fracture‐controlled metamorphic terranes remain unexplored. Here, we present a novel design for continuous in situ measurements of subsurface CO2 flux feasible for metamorphic rocks. The accumulative CO2 measurements were performed by either the passive mode or active recirculation on an 80‐m deep borehole in eastern Taiwan. Measurements in the passive mode yielded stepwise CO2 releases in the fractured zone and steady accumulation in the pulverized zone at rates (18.9–132 mgC m−2 day−1) resembling those for other active orogens. By contrast, the active recirculation produced an overestimation of CO2 flux. The high flux combined with variation patterns highlights heterogeneous metamorphic terranes as an important CO2 source and the necessities of extended monitoring using the passive mode.https://doi.org/10.1002/vzj2.70020
spellingShingle Wan‐Yin Lien
Rick Chen
Jui‐Fen Tsai
Jhen‐Nien Chen
Li‐Hung Lin
Pei‐Ling Wang
A novel design for continuous measurement of CO2 from deep remineralization of petrogenic organic carbon
Vadose Zone Journal
title A novel design for continuous measurement of CO2 from deep remineralization of petrogenic organic carbon
title_full A novel design for continuous measurement of CO2 from deep remineralization of petrogenic organic carbon
title_fullStr A novel design for continuous measurement of CO2 from deep remineralization of petrogenic organic carbon
title_full_unstemmed A novel design for continuous measurement of CO2 from deep remineralization of petrogenic organic carbon
title_short A novel design for continuous measurement of CO2 from deep remineralization of petrogenic organic carbon
title_sort novel design for continuous measurement of co2 from deep remineralization of petrogenic organic carbon
url https://doi.org/10.1002/vzj2.70020
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