Scanning SQUID characterization of strained multiferroic iron substituted gadolinium orthochromite thin film

Canted antiferromagnets GdCrO3 and GdFeO3 have drawn extensive attention due to large magnetoelectric effects, although low temperature multiferroic ordering currently limits possible applications. Iron substitution into GdCrO3 increases both antiferromagnetic and ferroelectric transition temperatur...

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Main Authors: J. Bedard, J. Pfund, M. Jain, I. Sochnikov
Format: Article
Language:English
Published: AIP Publishing LLC 2025-03-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/9.0000888
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author J. Bedard
J. Pfund
M. Jain
I. Sochnikov
author_facet J. Bedard
J. Pfund
M. Jain
I. Sochnikov
author_sort J. Bedard
collection DOAJ
description Canted antiferromagnets GdCrO3 and GdFeO3 have drawn extensive attention due to large magnetoelectric effects, although low temperature multiferroic ordering currently limits possible applications. Iron substitution into GdCrO3 increases both antiferromagnetic and ferroelectric transition temperatures. Room temperature magnetoelectric coupling in a single-phase material has yet to be realized. Here, we report the synthesis of a strained GdFe0.5Cr0.5O3 thin film grown on SrTiO3 and investigation of magnetic domain structure and temperature dependence with scanning superconducting quantum interference device (SQUID) microscopy. Magnetic domain structure remains above 70 K although magnetization of the domain dramatically decreases, which is consistent with bulk hysteresis measurements, in contrast to unstrained samples previously studied. Our results suggest strain tuning Dzyaloshinskii-Moriya interactions in GdFe0.5Cr0.5O3 offers a route to control multiferroic properties in this family of materials.
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spelling doaj-art-abfda2e27a9445c1917b01cded7223cf2025-08-20T01:55:52ZengAIP Publishing LLCAIP Advances2158-32262025-03-01153035313035313-610.1063/9.0000888Scanning SQUID characterization of strained multiferroic iron substituted gadolinium orthochromite thin filmJ. Bedard0J. Pfund1M. Jain2I. Sochnikov3Department of Physics, University of Connecticut, Storrs, Connecticut 06269, USADepartment of Physics, University of Connecticut, Storrs, Connecticut 06269, USADepartment of Physics, University of Connecticut, Storrs, Connecticut 06269, USADepartment of Physics, University of Connecticut, Storrs, Connecticut 06269, USACanted antiferromagnets GdCrO3 and GdFeO3 have drawn extensive attention due to large magnetoelectric effects, although low temperature multiferroic ordering currently limits possible applications. Iron substitution into GdCrO3 increases both antiferromagnetic and ferroelectric transition temperatures. Room temperature magnetoelectric coupling in a single-phase material has yet to be realized. Here, we report the synthesis of a strained GdFe0.5Cr0.5O3 thin film grown on SrTiO3 and investigation of magnetic domain structure and temperature dependence with scanning superconducting quantum interference device (SQUID) microscopy. Magnetic domain structure remains above 70 K although magnetization of the domain dramatically decreases, which is consistent with bulk hysteresis measurements, in contrast to unstrained samples previously studied. Our results suggest strain tuning Dzyaloshinskii-Moriya interactions in GdFe0.5Cr0.5O3 offers a route to control multiferroic properties in this family of materials.http://dx.doi.org/10.1063/9.0000888
spellingShingle J. Bedard
J. Pfund
M. Jain
I. Sochnikov
Scanning SQUID characterization of strained multiferroic iron substituted gadolinium orthochromite thin film
AIP Advances
title Scanning SQUID characterization of strained multiferroic iron substituted gadolinium orthochromite thin film
title_full Scanning SQUID characterization of strained multiferroic iron substituted gadolinium orthochromite thin film
title_fullStr Scanning SQUID characterization of strained multiferroic iron substituted gadolinium orthochromite thin film
title_full_unstemmed Scanning SQUID characterization of strained multiferroic iron substituted gadolinium orthochromite thin film
title_short Scanning SQUID characterization of strained multiferroic iron substituted gadolinium orthochromite thin film
title_sort scanning squid characterization of strained multiferroic iron substituted gadolinium orthochromite thin film
url http://dx.doi.org/10.1063/9.0000888
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