Synthesis of silylbut-1-en-3-ynes and buta-1,3-dienes as building blocks via hydrosilylation of 1,4-bis(trimethylsilyl)buta-1,3-diyne

Synthesis of silylbut-1-en-3-ynes and buta-1,3-dienes as building blocks via hydrosilylation of 1,4-bis(trimethylsilyl)buta-1,3-diyne

Abstract The selective and efficient synthesis of (E)-1,2,4-trisilylbut-1-en-3-ynes obtained via Pt-catalyzed hydrosilylation of 1,4-bis(trimethylsilyl)buta-1,3-diyne is described. Optimized reaction conditions (Pt(PPh3)4) or Pt2(dvs)3, 100 °C, toluene, 18 h) yielded compounds with high isolation yi...

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Bibliographic Details
Main Authors: Kinga Stefanowska-Kątna, Jędrzej Walkowiak, Adrian Franczyk
Format: Article
Language:English
Published: Nature Portfolio 2024-12-01
Series:Scientific Reports
Subjects:
1,4-Bis(trimethylsilyl)buta-1,3-diyne
Hydrosilylation
But-1-en-3-ynes
1,3-dienes
Building blocks
Online Access:https://doi.org/10.1038/s41598-024-82198-w
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