OPTIMISATION OF A HYDROPHILIC INTERACTION LIQUID CHROMATOGRAPHY METHOD FOR CATECHOLAMINES AND RELATED MOLECULES ANALYSIS

A simple and specific method for the analysis of 11 compounds (catecholamines, their precursors and their metabolites) has been developed using hydrophilic interaction chromatography. Adrenaline, noradrenalin, dopamine, serotonin, 3,4-dihydroxy-phenylalanine, 3-methoxytyramine, tryptophan, homovanil...

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Main Authors: RALUCA-IOANA CHIRITA-TAMPU, ADRIANA FINARU, CLAIRE ELFAKIR
Format: Article
Language:English
Published: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2017-03-01
Series:Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
Subjects:
Online Access:http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201701&vol=1&aid=4487
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author RALUCA-IOANA CHIRITA-TAMPU
ADRIANA FINARU
CLAIRE ELFAKIR
author_facet RALUCA-IOANA CHIRITA-TAMPU
ADRIANA FINARU
CLAIRE ELFAKIR
author_sort RALUCA-IOANA CHIRITA-TAMPU
collection DOAJ
description A simple and specific method for the analysis of 11 compounds (catecholamines, their precursors and their metabolites) has been developed using hydrophilic interaction chromatography. Adrenaline, noradrenalin, dopamine, serotonin, 3,4-dihydroxy-phenylalanine, 3-methoxytyramine, tryptophan, homovanillic acid, tyrosine, 3,4-dihydroxy-phenylacetic acid, 5-hydroxyindole-3-acetic acid and 3,4-dihydroxybenzylalanine (as internal standard) were separated on a TSK gel amide 80 column. The influence of parameters such as organic modifier type and content, salt nature and concentration, pH as well as column temperature on the selectivity were investigated. The optimized mobile phase consisted of a 20 mM ammonium acetate aqueous solution buffered at pH 3 and acetonitrile (20:80 v/v) mixture.
format Article
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institution OA Journals
issn 1582-540X
1582-540X
language English
publishDate 2017-03-01
publisher Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
record_format Article
series Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
spelling doaj-art-abb9f636364443bfabfe54671d3df5f42025-08-20T02:20:13ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2017-03-011813141OPTIMISATION OF A HYDROPHILIC INTERACTION LIQUID CHROMATOGRAPHY METHOD FOR CATECHOLAMINES AND RELATED MOLECULES ANALYSISRALUCA-IOANA CHIRITA-TAMPU 0ADRIANA FINARU1CLAIRE ELFAKIR21. ”Vasile Alecsandri” University of Bacau, 157, Calea Marasesti, 600115, Bacau, Romania 2. Institute of Organic and Analytical Chemistry, CNRS UMR 7311, University of Orleans, BP 6759, 45067 Orléans, France ”Vasile Alecsandri” University of Bacau, 157, Calea Marasesti, 600115, Bacau, Romania Institute of Organic and Analytical Chemistry, CNRS UMR 7311, University of Orleans, BP 6759, 45067 Orléans, FranceA simple and specific method for the analysis of 11 compounds (catecholamines, their precursors and their metabolites) has been developed using hydrophilic interaction chromatography. Adrenaline, noradrenalin, dopamine, serotonin, 3,4-dihydroxy-phenylalanine, 3-methoxytyramine, tryptophan, homovanillic acid, tyrosine, 3,4-dihydroxy-phenylacetic acid, 5-hydroxyindole-3-acetic acid and 3,4-dihydroxybenzylalanine (as internal standard) were separated on a TSK gel amide 80 column. The influence of parameters such as organic modifier type and content, salt nature and concentration, pH as well as column temperature on the selectivity were investigated. The optimized mobile phase consisted of a 20 mM ammonium acetate aqueous solution buffered at pH 3 and acetonitrile (20:80 v/v) mixture.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201701&vol=1&aid=4487catecholamineHILIC optimizationindolamineneurotransmittersTSK gel Amide 80
spellingShingle RALUCA-IOANA CHIRITA-TAMPU
ADRIANA FINARU
CLAIRE ELFAKIR
OPTIMISATION OF A HYDROPHILIC INTERACTION LIQUID CHROMATOGRAPHY METHOD FOR CATECHOLAMINES AND RELATED MOLECULES ANALYSIS
Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
catecholamine
HILIC optimization
indolamine
neurotransmitters
TSK gel Amide 80
title OPTIMISATION OF A HYDROPHILIC INTERACTION LIQUID CHROMATOGRAPHY METHOD FOR CATECHOLAMINES AND RELATED MOLECULES ANALYSIS
title_full OPTIMISATION OF A HYDROPHILIC INTERACTION LIQUID CHROMATOGRAPHY METHOD FOR CATECHOLAMINES AND RELATED MOLECULES ANALYSIS
title_fullStr OPTIMISATION OF A HYDROPHILIC INTERACTION LIQUID CHROMATOGRAPHY METHOD FOR CATECHOLAMINES AND RELATED MOLECULES ANALYSIS
title_full_unstemmed OPTIMISATION OF A HYDROPHILIC INTERACTION LIQUID CHROMATOGRAPHY METHOD FOR CATECHOLAMINES AND RELATED MOLECULES ANALYSIS
title_short OPTIMISATION OF A HYDROPHILIC INTERACTION LIQUID CHROMATOGRAPHY METHOD FOR CATECHOLAMINES AND RELATED MOLECULES ANALYSIS
title_sort optimisation of a hydrophilic interaction liquid chromatography method for catecholamines and related molecules analysis
topic catecholamine
HILIC optimization
indolamine
neurotransmitters
TSK gel Amide 80
url http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201701&vol=1&aid=4487
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AT claireelfakir optimisationofahydrophilicinteractionliquidchromatographymethodforcatecholaminesandrelatedmoleculesanalysis