Chemical signatures of microbial life in an ecological end-member: Shifting hydroclimate and sediment fluxes influence DOM biogeochemistry in Lake Fryxell, a permanently ice-covered lake in the McMurdo Dry Valleys of Antarctica

The ice-covered lakes in the McMurdo Dry Valleys (MDV) of Antarctica provide end-member ecosystems for understanding the production of dissolved organic matter (DOM) in aquatic ecosystems in the absence of vegetation on the landscape and under resource and nutrient constraints. Given these constrain...

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Main Authors: Garrett P. Rue, Diane M. McKnight
Format: Article
Language:English
Published: Taylor & Francis Group 2025-12-01
Series:Arctic, Antarctic, and Alpine Research
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Online Access:https://www.tandfonline.com/doi/10.1080/15230430.2025.2478678
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author Garrett P. Rue
Diane M. McKnight
author_facet Garrett P. Rue
Diane M. McKnight
author_sort Garrett P. Rue
collection DOAJ
description The ice-covered lakes in the McMurdo Dry Valleys (MDV) of Antarctica provide end-member ecosystems for understanding the production of dissolved organic matter (DOM) in aquatic ecosystems in the absence of vegetation on the landscape and under resource and nutrient constraints. Given these constraints, DOM in MDV lakes is derived solely from microbial phototrophs and heterotrophic bacteria, contrasting with the dominant terrestrial sources in temperate regions. Previous research developed fluorometric approaches for characterizing DOM, including in MDV lakes. In this study we leveraged these approaches along with contemporary molecular-based techniques to elucidate changes in DOM composition across the depth profile for Lake Fryxell in the MDV. The results showed that the presence of organic molecules containing sulfur increased at depth where anoxic conditions prevailed. To evaluate the influences of climate-induced rising lake levels and multiple flood events in the MDV, we compared recent and historical samples. The results indicated a remarkable consistency in source-related fluorescence metrics over time, whereas a twofold decrease in sulfur content of the fulvic acid fraction was observed in samples from above and below the oxycline. Biogeochemical processes associated with the influx of iron oxide–rich sediments during flood events may have contributed to this change, and similar processes may stimulate biogeochemical cycling and remineralization in temperate lakes during seasonal transitions.
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series Arctic, Antarctic, and Alpine Research
spelling doaj-art-ab6c99722f684b8ba2c33572b68daa5f2025-08-20T02:12:29ZengTaylor & Francis GroupArctic, Antarctic, and Alpine Research1523-04301938-42462025-12-0157110.1080/15230430.2025.2478678Chemical signatures of microbial life in an ecological end-member: Shifting hydroclimate and sediment fluxes influence DOM biogeochemistry in Lake Fryxell, a permanently ice-covered lake in the McMurdo Dry Valleys of AntarcticaGarrett P. Rue0Diane M. McKnight1Institute for Arctic and Alpine Research, University of Colorado–Boulder, Boulder, Colorado, USAInstitute for Arctic and Alpine Research, University of Colorado–Boulder, Boulder, Colorado, USAThe ice-covered lakes in the McMurdo Dry Valleys (MDV) of Antarctica provide end-member ecosystems for understanding the production of dissolved organic matter (DOM) in aquatic ecosystems in the absence of vegetation on the landscape and under resource and nutrient constraints. Given these constraints, DOM in MDV lakes is derived solely from microbial phototrophs and heterotrophic bacteria, contrasting with the dominant terrestrial sources in temperate regions. Previous research developed fluorometric approaches for characterizing DOM, including in MDV lakes. In this study we leveraged these approaches along with contemporary molecular-based techniques to elucidate changes in DOM composition across the depth profile for Lake Fryxell in the MDV. The results showed that the presence of organic molecules containing sulfur increased at depth where anoxic conditions prevailed. To evaluate the influences of climate-induced rising lake levels and multiple flood events in the MDV, we compared recent and historical samples. The results indicated a remarkable consistency in source-related fluorescence metrics over time, whereas a twofold decrease in sulfur content of the fulvic acid fraction was observed in samples from above and below the oxycline. Biogeochemical processes associated with the influx of iron oxide–rich sediments during flood events may have contributed to this change, and similar processes may stimulate biogeochemical cycling and remineralization in temperate lakes during seasonal transitions.https://www.tandfonline.com/doi/10.1080/15230430.2025.2478678AntarcticalimnologybiogeochemistryDOMnutrient cyclinglake metabolism
spellingShingle Garrett P. Rue
Diane M. McKnight
Chemical signatures of microbial life in an ecological end-member: Shifting hydroclimate and sediment fluxes influence DOM biogeochemistry in Lake Fryxell, a permanently ice-covered lake in the McMurdo Dry Valleys of Antarctica
Arctic, Antarctic, and Alpine Research
Antarctica
limnology
biogeochemistry
DOM
nutrient cycling
lake metabolism
title Chemical signatures of microbial life in an ecological end-member: Shifting hydroclimate and sediment fluxes influence DOM biogeochemistry in Lake Fryxell, a permanently ice-covered lake in the McMurdo Dry Valleys of Antarctica
title_full Chemical signatures of microbial life in an ecological end-member: Shifting hydroclimate and sediment fluxes influence DOM biogeochemistry in Lake Fryxell, a permanently ice-covered lake in the McMurdo Dry Valleys of Antarctica
title_fullStr Chemical signatures of microbial life in an ecological end-member: Shifting hydroclimate and sediment fluxes influence DOM biogeochemistry in Lake Fryxell, a permanently ice-covered lake in the McMurdo Dry Valleys of Antarctica
title_full_unstemmed Chemical signatures of microbial life in an ecological end-member: Shifting hydroclimate and sediment fluxes influence DOM biogeochemistry in Lake Fryxell, a permanently ice-covered lake in the McMurdo Dry Valleys of Antarctica
title_short Chemical signatures of microbial life in an ecological end-member: Shifting hydroclimate and sediment fluxes influence DOM biogeochemistry in Lake Fryxell, a permanently ice-covered lake in the McMurdo Dry Valleys of Antarctica
title_sort chemical signatures of microbial life in an ecological end member shifting hydroclimate and sediment fluxes influence dom biogeochemistry in lake fryxell a permanently ice covered lake in the mcmurdo dry valleys of antarctica
topic Antarctica
limnology
biogeochemistry
DOM
nutrient cycling
lake metabolism
url https://www.tandfonline.com/doi/10.1080/15230430.2025.2478678
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