Analysis of Gas Utilization Rate of Vanadium Titanium Magnetite Reduced by CH4-H2-CO Mixed Gas in Blast Furnace

Gas utilization rate is a very important production parameter in the ironmaking blast furnace (BF), which can effectively reflect the utilization of fuel chemical energy. While hydrogen rich gas (such as shale gas) was injected into BF, with the introduction of CH4 in the hydrogen rich gas, the trad...

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Main Authors: Xudong Gao, Xin Li
Format: Article
Language:English
Published: Polish Academy of Sciences 2025-06-01
Series:Archives of Metallurgy and Materials
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Online Access:https://journals.pan.pl/Content/135498/AMM-2025-2-06-Xudong-Gao.pdf
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author Xudong Gao
Xin Li
author_facet Xudong Gao
Xin Li
author_sort Xudong Gao
collection DOAJ
description Gas utilization rate is a very important production parameter in the ironmaking blast furnace (BF), which can effectively reflect the utilization of fuel chemical energy. While hydrogen rich gas (such as shale gas) was injected into BF, with the introduction of CH4 in the hydrogen rich gas, the traditional calculation formula for the utilization rate of binary mixed gas (H2-CO) was no longer suitable for the calculation of the utilization rate of ternary mixed gas (CH4-H2-CO). Based on the principle of oxygen migration in the gas-solid reduction reaction, this paper established and derived the method for calculating the utilization rate of mixed gas after methane-rich gas was injected into BF (the mixed gas changes from H2-CO type to CH4-H2-CO type), it is helpful to analyze the influence of CH4 introduction in hydrogen rich gas on the utilization rate of mixed gas in reduction reaction after injecting hydrogen rich gas. In this paper, the change of gas utilization rates and physical phases of 0.5 mol Fe2O3, 0.5 mol V2O5 and 1 mol TiO2 reduced by different amounts of H2-CO or CH4-H2-CO at 700℃, 850℃ and 1000℃ were studied respectively, some meaningful results were obtained through comparative analysis, which provides a theoretical basis for methane rich gas injection practice of vanadium titanium magnetite blast furnace (VTM-BF).
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spelling doaj-art-aaebdf21ca9a4e7b83821eb586d89f672025-08-20T03:31:21ZengPolish Academy of SciencesArchives of Metallurgy and Materials2300-19092025-06-01vol. 70No 2575582https://doi.org/10.24425/amm.2025.153458Analysis of Gas Utilization Rate of Vanadium Titanium Magnetite Reduced by CH4-H2-CO Mixed Gas in Blast FurnaceXudong Gao0https://orcid.org/0009-0001-1087-8031Xin Li1https://orcid.org/0009-0003-0911-8101Chongqing University of Science and Technology, School of Metallurgy And Materials Engineering, Chongqing, 401331, Pr, ChinaIronmaking Division, Institution of Cisdi Group Co., Ltd, Chongqing, 401122, Pr, ChinaGas utilization rate is a very important production parameter in the ironmaking blast furnace (BF), which can effectively reflect the utilization of fuel chemical energy. While hydrogen rich gas (such as shale gas) was injected into BF, with the introduction of CH4 in the hydrogen rich gas, the traditional calculation formula for the utilization rate of binary mixed gas (H2-CO) was no longer suitable for the calculation of the utilization rate of ternary mixed gas (CH4-H2-CO). Based on the principle of oxygen migration in the gas-solid reduction reaction, this paper established and derived the method for calculating the utilization rate of mixed gas after methane-rich gas was injected into BF (the mixed gas changes from H2-CO type to CH4-H2-CO type), it is helpful to analyze the influence of CH4 introduction in hydrogen rich gas on the utilization rate of mixed gas in reduction reaction after injecting hydrogen rich gas. In this paper, the change of gas utilization rates and physical phases of 0.5 mol Fe2O3, 0.5 mol V2O5 and 1 mol TiO2 reduced by different amounts of H2-CO or CH4-H2-CO at 700℃, 850℃ and 1000℃ were studied respectively, some meaningful results were obtained through comparative analysis, which provides a theoretical basis for methane rich gas injection practice of vanadium titanium magnetite blast furnace (VTM-BF).https://journals.pan.pl/Content/135498/AMM-2025-2-06-Xudong-Gao.pdfch4-h2-co mixed gasreduction reactiongas utilization ratevanadium titanium magnetite
spellingShingle Xudong Gao
Xin Li
Analysis of Gas Utilization Rate of Vanadium Titanium Magnetite Reduced by CH4-H2-CO Mixed Gas in Blast Furnace
Archives of Metallurgy and Materials
ch4-h2-co mixed gas
reduction reaction
gas utilization rate
vanadium titanium magnetite
title Analysis of Gas Utilization Rate of Vanadium Titanium Magnetite Reduced by CH4-H2-CO Mixed Gas in Blast Furnace
title_full Analysis of Gas Utilization Rate of Vanadium Titanium Magnetite Reduced by CH4-H2-CO Mixed Gas in Blast Furnace
title_fullStr Analysis of Gas Utilization Rate of Vanadium Titanium Magnetite Reduced by CH4-H2-CO Mixed Gas in Blast Furnace
title_full_unstemmed Analysis of Gas Utilization Rate of Vanadium Titanium Magnetite Reduced by CH4-H2-CO Mixed Gas in Blast Furnace
title_short Analysis of Gas Utilization Rate of Vanadium Titanium Magnetite Reduced by CH4-H2-CO Mixed Gas in Blast Furnace
title_sort analysis of gas utilization rate of vanadium titanium magnetite reduced by ch4 h2 co mixed gas in blast furnace
topic ch4-h2-co mixed gas
reduction reaction
gas utilization rate
vanadium titanium magnetite
url https://journals.pan.pl/Content/135498/AMM-2025-2-06-Xudong-Gao.pdf
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AT xinli analysisofgasutilizationrateofvanadiumtitaniummagnetitereducedbych4h2comixedgasinblastfurnace