The superior oxidation resistance of 60NiTi aircraft bearing alloy by introducing TiN and Ni3Ti multiple-layer structure

To improve the oxidation resistance of 60NiTi alloy, the TiN layer was introduced at the outermost of 60NiTi alloy. The results showed that the 60NiTi alloy exhibited the superior oxidation resistance owing to the construction of TiN layer, regardless of oxidation temperatures. After high-temperatur...

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Main Authors: Yunfei Wang, Huan Yang, Zheng Guo, Yanqing Wu, Guohao Zhang, Xinjian Cao, Yiping Zheng, Yang Li, Haizhen Wang, Xianglong Meng, Zhiyong Gao, Xiaoyang Yi
Format: Article
Language:English
Published: Elsevier 2025-07-01
Series:Journal of Materials Research and Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2238785425016345
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author Yunfei Wang
Huan Yang
Zheng Guo
Yanqing Wu
Guohao Zhang
Xinjian Cao
Yiping Zheng
Yang Li
Haizhen Wang
Xianglong Meng
Zhiyong Gao
Xiaoyang Yi
author_facet Yunfei Wang
Huan Yang
Zheng Guo
Yanqing Wu
Guohao Zhang
Xinjian Cao
Yiping Zheng
Yang Li
Haizhen Wang
Xianglong Meng
Zhiyong Gao
Xiaoyang Yi
author_sort Yunfei Wang
collection DOAJ
description To improve the oxidation resistance of 60NiTi alloy, the TiN layer was introduced at the outermost of 60NiTi alloy. The results showed that the 60NiTi alloy exhibited the superior oxidation resistance owing to the construction of TiN layer, regardless of oxidation temperatures. After high-temperature oxidation (900 °C), the oxidation layer of the solution treated and nitrided 60NiTi alloys consisted of a multilayer structure comprising: TiO2+NiTiO3+Ti oxide (Holes), Ni-rich + Ti2O3+Ti rich oxide (Holes), and Ni3Ti, from the outermost to the matrix. The amount of NiTiO3 oxides is less and the volume percentage of Ti2O3 oxide is more in the nitrided 60NiTi alloy, compared to the solution treated 60NiTi alloy. Density functional theory (DFT) calculations revealed that the O2− adsorption capacity of (200)TiN was significantly weaker than that of (110)NiTi, which further confirmed that the introduction of TiN layer was beneficial for enhancing the high-temperature oxidation resistance of 60NiTi alloy.
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publishDate 2025-07-01
publisher Elsevier
record_format Article
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spelling doaj-art-aaafb285847d499ea142b19dd75abb552025-08-20T02:40:15ZengElsevierJournal of Materials Research and Technology2238-78542025-07-01373269328810.1016/j.jmrt.2025.06.212The superior oxidation resistance of 60NiTi aircraft bearing alloy by introducing TiN and Ni3Ti multiple-layer structureYunfei Wang0Huan Yang1Zheng Guo2Yanqing Wu3Guohao Zhang4Xinjian Cao5Yiping Zheng6Yang Li7Haizhen Wang8Xianglong Meng9Zhiyong Gao10Xiaoyang Yi11School of Materials Science and Engineering, Harbin Institute of Technology, Harbin, 150001, China; Yantai Key Laboratory of Advanced Nuclear Energy Materials and Irradiation Technology, College of Nuclear Equipment & Nuclear Engineering, Yantai University, Yantai, 264005, ChinaYantai Key Laboratory of Advanced Nuclear Energy Materials and Irradiation Technology, College of Nuclear Equipment & Nuclear Engineering, Yantai University, Yantai, 264005, ChinaYantai Key Laboratory of Advanced Nuclear Energy Materials and Irradiation Technology, College of Nuclear Equipment & Nuclear Engineering, Yantai University, Yantai, 264005, ChinaYantai Key Laboratory of Advanced Nuclear Energy Materials and Irradiation Technology, College of Nuclear Equipment & Nuclear Engineering, Yantai University, Yantai, 264005, ChinaYantai Key Laboratory of Advanced Nuclear Energy Materials and Irradiation Technology, College of Nuclear Equipment & Nuclear Engineering, Yantai University, Yantai, 264005, ChinaState Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, ChinaSchool of Materials Science and Engineering, Harbin Institute of Technology, Harbin, 150001, ChinaYantai Key Laboratory of Advanced Nuclear Energy Materials and Irradiation Technology, College of Nuclear Equipment & Nuclear Engineering, Yantai University, Yantai, 264005, ChinaYantai Key Laboratory of Advanced Nuclear Energy Materials and Irradiation Technology, College of Nuclear Equipment & Nuclear Engineering, Yantai University, Yantai, 264005, ChinaSchool of Materials Science and Engineering, Harbin Institute of Technology, Harbin, 150001, ChinaSchool of Materials Science and Engineering, Harbin Institute of Technology, Harbin, 150001, China; Corresponding author.Yantai Key Laboratory of Advanced Nuclear Energy Materials and Irradiation Technology, College of Nuclear Equipment & Nuclear Engineering, Yantai University, Yantai, 264005, China; Shandong Key Laboratory of Special Metallic Materials for Nuclear Equipment, Yantai University, Yantai, 264005, Shandong, China; Corresponding author. Yantai Key Laboratory of Advanced Nuclear Energy Materials and Irradiation Technology, College of Nuclear Equipment & Nuclear Engineering, Yantai University, Yantai, 264005, China.To improve the oxidation resistance of 60NiTi alloy, the TiN layer was introduced at the outermost of 60NiTi alloy. The results showed that the 60NiTi alloy exhibited the superior oxidation resistance owing to the construction of TiN layer, regardless of oxidation temperatures. After high-temperature oxidation (900 °C), the oxidation layer of the solution treated and nitrided 60NiTi alloys consisted of a multilayer structure comprising: TiO2+NiTiO3+Ti oxide (Holes), Ni-rich + Ti2O3+Ti rich oxide (Holes), and Ni3Ti, from the outermost to the matrix. The amount of NiTiO3 oxides is less and the volume percentage of Ti2O3 oxide is more in the nitrided 60NiTi alloy, compared to the solution treated 60NiTi alloy. Density functional theory (DFT) calculations revealed that the O2− adsorption capacity of (200)TiN was significantly weaker than that of (110)NiTi, which further confirmed that the introduction of TiN layer was beneficial for enhancing the high-temperature oxidation resistance of 60NiTi alloy.http://www.sciencedirect.com/science/article/pii/S223878542501634560NiTi alloyNitriding treatmentOxidation behaviorMicrostructural evolutionFirst principle calculation
spellingShingle Yunfei Wang
Huan Yang
Zheng Guo
Yanqing Wu
Guohao Zhang
Xinjian Cao
Yiping Zheng
Yang Li
Haizhen Wang
Xianglong Meng
Zhiyong Gao
Xiaoyang Yi
The superior oxidation resistance of 60NiTi aircraft bearing alloy by introducing TiN and Ni3Ti multiple-layer structure
Journal of Materials Research and Technology
60NiTi alloy
Nitriding treatment
Oxidation behavior
Microstructural evolution
First principle calculation
title The superior oxidation resistance of 60NiTi aircraft bearing alloy by introducing TiN and Ni3Ti multiple-layer structure
title_full The superior oxidation resistance of 60NiTi aircraft bearing alloy by introducing TiN and Ni3Ti multiple-layer structure
title_fullStr The superior oxidation resistance of 60NiTi aircraft bearing alloy by introducing TiN and Ni3Ti multiple-layer structure
title_full_unstemmed The superior oxidation resistance of 60NiTi aircraft bearing alloy by introducing TiN and Ni3Ti multiple-layer structure
title_short The superior oxidation resistance of 60NiTi aircraft bearing alloy by introducing TiN and Ni3Ti multiple-layer structure
title_sort superior oxidation resistance of 60niti aircraft bearing alloy by introducing tin and ni3ti multiple layer structure
topic 60NiTi alloy
Nitriding treatment
Oxidation behavior
Microstructural evolution
First principle calculation
url http://www.sciencedirect.com/science/article/pii/S2238785425016345
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