Selective leaching of nickel from prereduced limonitic laterite under moderate HPAL conditions- part I: Dissolution

High pressure acid leaching (HPAL) is the primary method for extraction of nickel from limonitic laterite. The severe operating conditions, the complexity of facilities, and several technical problems, such as scale formation, have always accompanied the HPAL, however. In this paper, the...

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Main Authors: Chang Y., Zhao K., Pešić B.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2016-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2016/1450-53391600023C.pdf
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author Chang Y.
Zhao K.
Pešić B.
author_facet Chang Y.
Zhao K.
Pešić B.
author_sort Chang Y.
collection DOAJ
description High pressure acid leaching (HPAL) is the primary method for extraction of nickel from limonitic laterite. The severe operating conditions, the complexity of facilities, and several technical problems, such as scale formation, have always accompanied the HPAL, however. In this paper, the selective acid leaching of nickel from the pre-reduced limonitic laterite under moderate HPAL conditions was studied. For the calcine with reduction degree of 93.4%, about 88.2% nickel could be selectively extracted at 100°C with an acid/ore ratio of 0.164, leaving less then 5.0g/L iron in the solution. Further increase of leaching temperature, and the ensuing dehydration, transformed goethite in the leaching residue to hematite. When the temperatures were as high as 180°C, the recovery of nickel increased to 95.2%, within one hour, depressing the residual soluble iron to below 1.0g/L (pO2= 1.0 MPa, acid/ore= 0.287).
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institution Kabale University
issn 1450-5339
2217-7175
language English
publishDate 2016-01-01
publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-aa60a60bf0e94db3bc3bba3a284894402025-02-02T13:59:46ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392217-71752016-01-0152212713410.2298/JMMB151102023C1450-53391600023CSelective leaching of nickel from prereduced limonitic laterite under moderate HPAL conditions- part I: DissolutionChang Y.0Zhao K.1Pešić B.2Northeastern University, School of Materials & Metallurgy, Shenyang, P.R. ChinaNortheastern University, School of Materials & Metallurgy, Shenyang, P.R. ChinaUniversity of Idaho, Department of Chemical and Materials Engineering, Moscow, USAHigh pressure acid leaching (HPAL) is the primary method for extraction of nickel from limonitic laterite. The severe operating conditions, the complexity of facilities, and several technical problems, such as scale formation, have always accompanied the HPAL, however. In this paper, the selective acid leaching of nickel from the pre-reduced limonitic laterite under moderate HPAL conditions was studied. For the calcine with reduction degree of 93.4%, about 88.2% nickel could be selectively extracted at 100°C with an acid/ore ratio of 0.164, leaving less then 5.0g/L iron in the solution. Further increase of leaching temperature, and the ensuing dehydration, transformed goethite in the leaching residue to hematite. When the temperatures were as high as 180°C, the recovery of nickel increased to 95.2%, within one hour, depressing the residual soluble iron to below 1.0g/L (pO2= 1.0 MPa, acid/ore= 0.287).http://www.doiserbia.nb.rs/img/doi/1450-5339/2016/1450-53391600023C.pdfnickelselective leachingreductive roastinggoethitehematite
spellingShingle Chang Y.
Zhao K.
Pešić B.
Selective leaching of nickel from prereduced limonitic laterite under moderate HPAL conditions- part I: Dissolution
Journal of Mining and Metallurgy. Section B: Metallurgy
nickel
selective leaching
reductive roasting
goethite
hematite
title Selective leaching of nickel from prereduced limonitic laterite under moderate HPAL conditions- part I: Dissolution
title_full Selective leaching of nickel from prereduced limonitic laterite under moderate HPAL conditions- part I: Dissolution
title_fullStr Selective leaching of nickel from prereduced limonitic laterite under moderate HPAL conditions- part I: Dissolution
title_full_unstemmed Selective leaching of nickel from prereduced limonitic laterite under moderate HPAL conditions- part I: Dissolution
title_short Selective leaching of nickel from prereduced limonitic laterite under moderate HPAL conditions- part I: Dissolution
title_sort selective leaching of nickel from prereduced limonitic laterite under moderate hpal conditions part i dissolution
topic nickel
selective leaching
reductive roasting
goethite
hematite
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2016/1450-53391600023C.pdf
work_keys_str_mv AT changy selectiveleachingofnickelfromprereducedlimoniticlateriteundermoderatehpalconditionspartidissolution
AT zhaok selectiveleachingofnickelfromprereducedlimoniticlateriteundermoderatehpalconditionspartidissolution
AT pesicb selectiveleachingofnickelfromprereducedlimoniticlateriteundermoderatehpalconditionspartidissolution