Band Tunable CdSe Quantum Dot-Doped Metals for Quantum Dot-Sensitized Solar Cell Application

Quantum dots are drawing great attention as a material for the next-generation solar cells because of the high absorption coefficient, tunable band gap, and multiple exciton generation effect. In search of the viable way to enhance the power conversion efficiency of quantum dot-sensitized solar cell...

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Main Authors: Dang Huu Phuc, Ha Thanh Tung
Format: Article
Language:English
Published: Wiley 2019-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2019/9812719
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author Dang Huu Phuc
Ha Thanh Tung
author_facet Dang Huu Phuc
Ha Thanh Tung
author_sort Dang Huu Phuc
collection DOAJ
description Quantum dots are drawing great attention as a material for the next-generation solar cells because of the high absorption coefficient, tunable band gap, and multiple exciton generation effect. In search of the viable way to enhance the power conversion efficiency of quantum dot-sensitized solar cells, we have succeeded in preparing the quantum dot solar cells with high efficiency based on CdSe:X (Mn2+ or Cu2+) nanocrystal by successive ionic layer absorption and reaction. The morphological observation and crystalline structure of photoanode were characterized by field-emission scanning electron microscopy, X-ray diffraction, and the EDX spectra. In addition, the electrochemical performance of photoelectrode was studied by the electrochemical impedance spectra. As a result, we have succeeded in designing QDSSCs with a high efficiency of 4.3%. Moreover, the optical properties, the direct optical energy gap, and both the conduction band and the valence band levels of the compositional CdSe:X were estimated by the theory of Tauc and discussed details. This theory is useful for us to understand the alignment energy structure of the compositions in electrodes, in particular, the conduction band and valence band levels of CdSe:X nanoparticles.
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spelling doaj-art-aa5a3566e25847bd896c482adb4870b42025-08-20T02:20:38ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2019-01-01201910.1155/2019/98127199812719Band Tunable CdSe Quantum Dot-Doped Metals for Quantum Dot-Sensitized Solar Cell ApplicationDang Huu Phuc0Ha Thanh Tung1Laboratory of Applied Physics, Advanced Institute of Materials Science, Ton Duc Thang University, Ho Chi Minh City, VietnamInstitute of Research and Development, Duy Tan University, Da Nang, VietnamQuantum dots are drawing great attention as a material for the next-generation solar cells because of the high absorption coefficient, tunable band gap, and multiple exciton generation effect. In search of the viable way to enhance the power conversion efficiency of quantum dot-sensitized solar cells, we have succeeded in preparing the quantum dot solar cells with high efficiency based on CdSe:X (Mn2+ or Cu2+) nanocrystal by successive ionic layer absorption and reaction. The morphological observation and crystalline structure of photoanode were characterized by field-emission scanning electron microscopy, X-ray diffraction, and the EDX spectra. In addition, the electrochemical performance of photoelectrode was studied by the electrochemical impedance spectra. As a result, we have succeeded in designing QDSSCs with a high efficiency of 4.3%. Moreover, the optical properties, the direct optical energy gap, and both the conduction band and the valence band levels of the compositional CdSe:X were estimated by the theory of Tauc and discussed details. This theory is useful for us to understand the alignment energy structure of the compositions in electrodes, in particular, the conduction band and valence band levels of CdSe:X nanoparticles.http://dx.doi.org/10.1155/2019/9812719
spellingShingle Dang Huu Phuc
Ha Thanh Tung
Band Tunable CdSe Quantum Dot-Doped Metals for Quantum Dot-Sensitized Solar Cell Application
International Journal of Photoenergy
title Band Tunable CdSe Quantum Dot-Doped Metals for Quantum Dot-Sensitized Solar Cell Application
title_full Band Tunable CdSe Quantum Dot-Doped Metals for Quantum Dot-Sensitized Solar Cell Application
title_fullStr Band Tunable CdSe Quantum Dot-Doped Metals for Quantum Dot-Sensitized Solar Cell Application
title_full_unstemmed Band Tunable CdSe Quantum Dot-Doped Metals for Quantum Dot-Sensitized Solar Cell Application
title_short Band Tunable CdSe Quantum Dot-Doped Metals for Quantum Dot-Sensitized Solar Cell Application
title_sort band tunable cdse quantum dot doped metals for quantum dot sensitized solar cell application
url http://dx.doi.org/10.1155/2019/9812719
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