A resistive electron irradiation microsensor made from conductive electrospun polycaprolactone fibers loaded with carbon nanotubes and fullerene C60

In this work electron radiation microdevices were fabricated and characterized. The microdevices consisted of aligned conductive electrospun fibers made of polycaprolactone loaded with multiwalled carbon nanotubes and C60 deposited onto gold interdigitated microelectrodes. They were capable of perma...

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Main Authors: Fabricio N. Molinari, Maria A. Mancuso, Emanuel Bilbao, Gustavo Giménez, Leandro N. Monsalve
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Nano Trends
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666978125000455
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author Fabricio N. Molinari
Maria A. Mancuso
Emanuel Bilbao
Gustavo Giménez
Leandro N. Monsalve
author_facet Fabricio N. Molinari
Maria A. Mancuso
Emanuel Bilbao
Gustavo Giménez
Leandro N. Monsalve
author_sort Fabricio N. Molinari
collection DOAJ
description In this work electron radiation microdevices were fabricated and characterized. The microdevices consisted of aligned conductive electrospun fibers made of polycaprolactone loaded with multiwalled carbon nanotubes and C60 deposited onto gold interdigitated microelectrodes. They were capable of permanently increasing their conductivity upon exposure to electron beam irradiation from 0.02 pC μm-2 accelerated at 10 and 20 keV. This phenomenon could be explained due to the ability of C60 to trap and stabilize negative charges and thus contribute to the conductivity of the polymer composite. The microdevices achieved their maximum conductivity after an irradiation between 0.22 and 0.27 pC μm-2 and this maximum was dependent of the electron acceleration. Montecarlo simulations were performed to explain dependence as function of electron penetration in the polymer composite. Moreover, the microdevices irradiated at 20 keV maintained their final conductivity and the microdevices irradiated at 10 keV increased their final conductivity after 6 days from irradiation. C60 proved to act as highly efficient electron scavengers within the polymer composite and contribute to its conductivity, and the microdevices have potential application as beta radiation sensors.
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spelling doaj-art-aa59e62e74ed4240b68db84d3ea8c21b2025-08-20T03:53:12ZengElsevierNano Trends2666-97812025-06-011010011610.1016/j.nwnano.2025.100116A resistive electron irradiation microsensor made from conductive electrospun polycaprolactone fibers loaded with carbon nanotubes and fullerene C60Fabricio N. Molinari0Maria A. Mancuso1Emanuel Bilbao2Gustavo Giménez3Leandro N. Monsalve4INTI Textiles, Av. Gral. Paz 5445, San Martín, Buenos Aires, Argentina; Institute of Atmospheric Pollution Research—National Research Council (IIA—CNR), Research Area of Rome 1, Strada Provinciale 35d, 9-00010 Montelibretti, ItalyInstitute of Atmospheric Pollution Research—National Research Council (IIA—CNR), Research Area of Rome 1, Strada Provinciale 35d, 9-00010 Montelibretti, ItalyINTI Micro y Nanotecnologías, Av. Gral. Paz 5445, San Martín, Buenos Aires, ArgentinaINTI Micro y Nanotecnologías, Av. Gral. Paz 5445, San Martín, Buenos Aires, ArgentinaINTI Textiles, Av. Gral. Paz 5445, San Martín, Buenos Aires, Argentina; Instituto de la Calidad Industrial (INCALIN – INTI – UNSAM), Av. Gral. Paz 5445, San Martín, Buenos Aires, Argentina; Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Godoy Cruz 2290 CABA, ArgentinaIn this work electron radiation microdevices were fabricated and characterized. The microdevices consisted of aligned conductive electrospun fibers made of polycaprolactone loaded with multiwalled carbon nanotubes and C60 deposited onto gold interdigitated microelectrodes. They were capable of permanently increasing their conductivity upon exposure to electron beam irradiation from 0.02 pC μm-2 accelerated at 10 and 20 keV. This phenomenon could be explained due to the ability of C60 to trap and stabilize negative charges and thus contribute to the conductivity of the polymer composite. The microdevices achieved their maximum conductivity after an irradiation between 0.22 and 0.27 pC μm-2 and this maximum was dependent of the electron acceleration. Montecarlo simulations were performed to explain dependence as function of electron penetration in the polymer composite. Moreover, the microdevices irradiated at 20 keV maintained their final conductivity and the microdevices irradiated at 10 keV increased their final conductivity after 6 days from irradiation. C60 proved to act as highly efficient electron scavengers within the polymer composite and contribute to its conductivity, and the microdevices have potential application as beta radiation sensors.http://www.sciencedirect.com/science/article/pii/S2666978125000455Conductive nanocompositeResistive sensorDosimeter
spellingShingle Fabricio N. Molinari
Maria A. Mancuso
Emanuel Bilbao
Gustavo Giménez
Leandro N. Monsalve
A resistive electron irradiation microsensor made from conductive electrospun polycaprolactone fibers loaded with carbon nanotubes and fullerene C60
Nano Trends
Conductive nanocomposite
Resistive sensor
Dosimeter
title A resistive electron irradiation microsensor made from conductive electrospun polycaprolactone fibers loaded with carbon nanotubes and fullerene C60
title_full A resistive electron irradiation microsensor made from conductive electrospun polycaprolactone fibers loaded with carbon nanotubes and fullerene C60
title_fullStr A resistive electron irradiation microsensor made from conductive electrospun polycaprolactone fibers loaded with carbon nanotubes and fullerene C60
title_full_unstemmed A resistive electron irradiation microsensor made from conductive electrospun polycaprolactone fibers loaded with carbon nanotubes and fullerene C60
title_short A resistive electron irradiation microsensor made from conductive electrospun polycaprolactone fibers loaded with carbon nanotubes and fullerene C60
title_sort resistive electron irradiation microsensor made from conductive electrospun polycaprolactone fibers loaded with carbon nanotubes and fullerene c60
topic Conductive nanocomposite
Resistive sensor
Dosimeter
url http://www.sciencedirect.com/science/article/pii/S2666978125000455
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