Thermophysical Enhancement of Graphene Oxide-Enhanced Quaternary Nitrate for Concentrated Solar Power Applications

With the continuous progress of global renewable energy, the reliability of the performance of heat storage materials is becoming increasingly important. In this study, graphene oxide (GO) was used as an additive to investigate its influence on the heat storage performance of quaternary nitrate molt...

Full description

Saved in:
Bibliographic Details
Main Authors: Yingchun Wang, Haonan Zhang, Hantao Liu, Hong Hou, Yonghong Guo, Wenrui Chang
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/18/10/2607
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850126442591944704
author Yingchun Wang
Haonan Zhang
Hantao Liu
Hong Hou
Yonghong Guo
Wenrui Chang
author_facet Yingchun Wang
Haonan Zhang
Hantao Liu
Hong Hou
Yonghong Guo
Wenrui Chang
author_sort Yingchun Wang
collection DOAJ
description With the continuous progress of global renewable energy, the reliability of the performance of heat storage materials is becoming increasingly important. In this study, graphene oxide (GO) was used as an additive to investigate its influence on the heat storage performance of quaternary nitrate molten salt. Quaternary nitrate molten salts doped in different proportions of 0.5, 1.0, 1.5, and 2.0 wt.% were prepared by the high-temperature hot melting method, and their properties were characterized in detail. The results show that the optimal concentration value of graphene oxide nanosheets is 1.0 wt.%, at which point the thermal parameters such as the specific heat capacity and thermal conductivity of the molten salt are optimal. Meanwhile, differential scanning calorimetry and thermogravimetric analysis tests verified the enhanced effect of the thermal performance. Furthermore, transmission electron microscopy and scanning electron microscopy analyses indicated that the insertion and encapsulation of nanosheets in the channel structure between nitrate crystals were effective. The modification methods used in this paper can enhance the thermophysical properties of nitrates. Meanwhile, the methods proposed in this paper can provide new ideas for the practice of heat-requiring systems.
format Article
id doaj-art-a9e1530040ff4b528017cb9abab9beb9
institution OA Journals
issn 1996-1073
language English
publishDate 2025-05-01
publisher MDPI AG
record_format Article
series Energies
spelling doaj-art-a9e1530040ff4b528017cb9abab9beb92025-08-20T02:33:55ZengMDPI AGEnergies1996-10732025-05-011810260710.3390/en18102607Thermophysical Enhancement of Graphene Oxide-Enhanced Quaternary Nitrate for Concentrated Solar Power ApplicationsYingchun Wang0Haonan Zhang1Hantao Liu2Hong Hou3Yonghong Guo4Wenrui Chang5School of Mechanical Engineering, North University of China, Taiyuan 030051, ChinaKey Laboratory of Shanxi Province for Solar Thermal Technology, Taiyuan 030051, ChinaSchool of Mechanical Engineering, North University of China, Taiyuan 030051, ChinaDepartment of Energy and Power Engineering, Shanxi Institute of Energy, Jinzhong 030600, ChinaDepartment of Energy and Power Engineering, Shanxi Institute of Energy, Jinzhong 030600, ChinaShanxi Wojin New Materials Co., Ltd., Lvliang 030051, ChinaWith the continuous progress of global renewable energy, the reliability of the performance of heat storage materials is becoming increasingly important. In this study, graphene oxide (GO) was used as an additive to investigate its influence on the heat storage performance of quaternary nitrate molten salt. Quaternary nitrate molten salts doped in different proportions of 0.5, 1.0, 1.5, and 2.0 wt.% were prepared by the high-temperature hot melting method, and their properties were characterized in detail. The results show that the optimal concentration value of graphene oxide nanosheets is 1.0 wt.%, at which point the thermal parameters such as the specific heat capacity and thermal conductivity of the molten salt are optimal. Meanwhile, differential scanning calorimetry and thermogravimetric analysis tests verified the enhanced effect of the thermal performance. Furthermore, transmission electron microscopy and scanning electron microscopy analyses indicated that the insertion and encapsulation of nanosheets in the channel structure between nitrate crystals were effective. The modification methods used in this paper can enhance the thermophysical properties of nitrates. Meanwhile, the methods proposed in this paper can provide new ideas for the practice of heat-requiring systems.https://www.mdpi.com/1996-1073/18/10/2607graphene oxidequaternary nitratemolten saltthermal storagespecific heat capacity
spellingShingle Yingchun Wang
Haonan Zhang
Hantao Liu
Hong Hou
Yonghong Guo
Wenrui Chang
Thermophysical Enhancement of Graphene Oxide-Enhanced Quaternary Nitrate for Concentrated Solar Power Applications
Energies
graphene oxide
quaternary nitrate
molten salt
thermal storage
specific heat capacity
title Thermophysical Enhancement of Graphene Oxide-Enhanced Quaternary Nitrate for Concentrated Solar Power Applications
title_full Thermophysical Enhancement of Graphene Oxide-Enhanced Quaternary Nitrate for Concentrated Solar Power Applications
title_fullStr Thermophysical Enhancement of Graphene Oxide-Enhanced Quaternary Nitrate for Concentrated Solar Power Applications
title_full_unstemmed Thermophysical Enhancement of Graphene Oxide-Enhanced Quaternary Nitrate for Concentrated Solar Power Applications
title_short Thermophysical Enhancement of Graphene Oxide-Enhanced Quaternary Nitrate for Concentrated Solar Power Applications
title_sort thermophysical enhancement of graphene oxide enhanced quaternary nitrate for concentrated solar power applications
topic graphene oxide
quaternary nitrate
molten salt
thermal storage
specific heat capacity
url https://www.mdpi.com/1996-1073/18/10/2607
work_keys_str_mv AT yingchunwang thermophysicalenhancementofgrapheneoxideenhancedquaternarynitrateforconcentratedsolarpowerapplications
AT haonanzhang thermophysicalenhancementofgrapheneoxideenhancedquaternarynitrateforconcentratedsolarpowerapplications
AT hantaoliu thermophysicalenhancementofgrapheneoxideenhancedquaternarynitrateforconcentratedsolarpowerapplications
AT honghou thermophysicalenhancementofgrapheneoxideenhancedquaternarynitrateforconcentratedsolarpowerapplications
AT yonghongguo thermophysicalenhancementofgrapheneoxideenhancedquaternarynitrateforconcentratedsolarpowerapplications
AT wenruichang thermophysicalenhancementofgrapheneoxideenhancedquaternarynitrateforconcentratedsolarpowerapplications