Effect of rice husk derived activated carbon surface coating on NMC 811 characteristics and performance as lithium-ion battery cathode

Nickel manganese cobalt with high nickel content (LiNi0.8Mn0.1Co0.1O2, NMC 811) is known for its high capacity. However, it is prone to air which could lead to structural degradation and result in capacity fading. Surface coating with carbon is known to tackle this issue. In this work, rice husk is...

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Main Authors: Fiona Angellinnov, Achmad Subhan, Wara Dyah Pita Rengga, Arif Jumari, Anne Zulfia Syahrial
Format: Article
Language:English
Published: Elsevier 2025-05-01
Series:Results in Surfaces and Interfaces
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666845925001540
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author Fiona Angellinnov
Achmad Subhan
Wara Dyah Pita Rengga
Arif Jumari
Anne Zulfia Syahrial
author_facet Fiona Angellinnov
Achmad Subhan
Wara Dyah Pita Rengga
Arif Jumari
Anne Zulfia Syahrial
author_sort Fiona Angellinnov
collection DOAJ
description Nickel manganese cobalt with high nickel content (LiNi0.8Mn0.1Co0.1O2, NMC 811) is known for its high capacity. However, it is prone to air which could lead to structural degradation and result in capacity fading. Surface coating with carbon is known to tackle this issue. In this work, rice husk is utilized as a renewable and cheap carbon source for the surface coating material of NMC 811. Rice husk was carbonized and activated using sodium hydroxide. NMC 811 was synthesized using solution combustion and then coated with rice husk via a solid state method followed by calcination. The results showed that adding activated carbon derived from rice husk to NMC 811 did not alter its structure nor morphology, but increased conductivity and lithium-ion diffusion. In this work, 5 wt% rice husk derived activated carbon surface coated NMC 811 provided the highest capacity of 44.5063 mAh/g.
format Article
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institution OA Journals
issn 2666-8459
language English
publishDate 2025-05-01
publisher Elsevier
record_format Article
series Results in Surfaces and Interfaces
spelling doaj-art-a9d01205a9084dbb958ab32bd01ed0a02025-08-20T02:37:41ZengElsevierResults in Surfaces and Interfaces2666-84592025-05-011910056710.1016/j.rsurfi.2025.100567Effect of rice husk derived activated carbon surface coating on NMC 811 characteristics and performance as lithium-ion battery cathodeFiona Angellinnov0Achmad Subhan1Wara Dyah Pita Rengga2Arif Jumari3Anne Zulfia Syahrial4Department of Metallurgical and Materials Engineering, Faculty of Engineering, Universitas Indonesia, Depok, 16424, IndonesiaResearch Centre for Advanced Materials-National Research and Innovation Agency, South Tangerang, 15314, IndonesiaDepartment of Chemical Engineering, Universitas Negeri Semarang, Sekaran Campus, Gunungpati, Semarang, Central Java, 50229, IndonesiaDepartment of Chemical Engineering, Faculty of Engineering, Universitas Sebelas Maret, Jl. Ir. Sutami 36A, Surakarta, Central Java, 57126, Indonesia; Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret, Jl. Slamet Riyadi 435, Surakarta, Central Java, 57146, IndonesiaDepartment of Metallurgical and Materials Engineering, Faculty of Engineering, Universitas Indonesia, Depok, 16424, Indonesia; Tropical Renewable Energy Centre, Faculty of Engineering, Universitas Indonesia, Depok, 16424, Indonesia; Corresponding author. Department of Metallurgical and Materials Engineering, Faculty of Engineering, Universitas Indonesia, Depok, 16424, Indonesia.Nickel manganese cobalt with high nickel content (LiNi0.8Mn0.1Co0.1O2, NMC 811) is known for its high capacity. However, it is prone to air which could lead to structural degradation and result in capacity fading. Surface coating with carbon is known to tackle this issue. In this work, rice husk is utilized as a renewable and cheap carbon source for the surface coating material of NMC 811. Rice husk was carbonized and activated using sodium hydroxide. NMC 811 was synthesized using solution combustion and then coated with rice husk via a solid state method followed by calcination. The results showed that adding activated carbon derived from rice husk to NMC 811 did not alter its structure nor morphology, but increased conductivity and lithium-ion diffusion. In this work, 5 wt% rice husk derived activated carbon surface coated NMC 811 provided the highest capacity of 44.5063 mAh/g.http://www.sciencedirect.com/science/article/pii/S2666845925001540Activated carbon coatingCathodeLithium-ion batteryNMC 811Rice husk
spellingShingle Fiona Angellinnov
Achmad Subhan
Wara Dyah Pita Rengga
Arif Jumari
Anne Zulfia Syahrial
Effect of rice husk derived activated carbon surface coating on NMC 811 characteristics and performance as lithium-ion battery cathode
Results in Surfaces and Interfaces
Activated carbon coating
Cathode
Lithium-ion battery
NMC 811
Rice husk
title Effect of rice husk derived activated carbon surface coating on NMC 811 characteristics and performance as lithium-ion battery cathode
title_full Effect of rice husk derived activated carbon surface coating on NMC 811 characteristics and performance as lithium-ion battery cathode
title_fullStr Effect of rice husk derived activated carbon surface coating on NMC 811 characteristics and performance as lithium-ion battery cathode
title_full_unstemmed Effect of rice husk derived activated carbon surface coating on NMC 811 characteristics and performance as lithium-ion battery cathode
title_short Effect of rice husk derived activated carbon surface coating on NMC 811 characteristics and performance as lithium-ion battery cathode
title_sort effect of rice husk derived activated carbon surface coating on nmc 811 characteristics and performance as lithium ion battery cathode
topic Activated carbon coating
Cathode
Lithium-ion battery
NMC 811
Rice husk
url http://www.sciencedirect.com/science/article/pii/S2666845925001540
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