ATF4 participates in perfluorooctane sulfonate-induced neurotoxicity by regulating ferroptosis

Evidence from animal and human research suggests that perfluorooctane sulfonate (PFOS), a prevalent persistent organic pollutant (POP), exerts neurotoxic effects, but the precise mechanisms remain unclear. Additionally, the function of activating transcription factor 4 (ATF4), a crucial modulator of...

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Main Authors: Fangling Zhu, Nan Wang, Yichao Xu, Xiaohua Su, Ziliang Deng, Yongdui Ruan, Daifan Lin, Yun Chen, Zhuoni Kuang, Guanlin Chen, Chengcheng Yu, Xiaoxuan Ling, Linhua Liu
Format: Article
Language:English
Published: Elsevier 2025-07-01
Series:Ecotoxicology and Environmental Safety
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Online Access:http://www.sciencedirect.com/science/article/pii/S0147651325006396
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author Fangling Zhu
Nan Wang
Yichao Xu
Xiaohua Su
Ziliang Deng
Yongdui Ruan
Daifan Lin
Yun Chen
Zhuoni Kuang
Guanlin Chen
Chengcheng Yu
Xiaoxuan Ling
Linhua Liu
author_facet Fangling Zhu
Nan Wang
Yichao Xu
Xiaohua Su
Ziliang Deng
Yongdui Ruan
Daifan Lin
Yun Chen
Zhuoni Kuang
Guanlin Chen
Chengcheng Yu
Xiaoxuan Ling
Linhua Liu
author_sort Fangling Zhu
collection DOAJ
description Evidence from animal and human research suggests that perfluorooctane sulfonate (PFOS), a prevalent persistent organic pollutant (POP), exerts neurotoxic effects, but the precise mechanisms remain unclear. Additionally, the function of activating transcription factor 4 (ATF4), a crucial modulator of cellular metabolism, redox balance, and survival, in PFOS-induced neurotoxicity has not been fully elucidated. In vitro metabolomics studies revealed that PFOS elevated the intracellular concentration of reactive oxygen species (ROS) and lowered the levels of reduced L-glutathione (GSH). Significant alterations in the mRNA and protein expression levels of ferroptosis-related biomarkers, including ferroptosis-related genes [NRF2, nuclear receptor coactivator 4 (NCOA4), KEAP1, xCT/SLC7A11, GPX4, and FTH1], cellular iron, and lipid peroxidation were observed. Moreover, erastin (Ers) exacerbated lipid peroxidation, which was alleviated by ferrostatin-1 (Fer-1) and N-acetyl-L-cysteine (NAC). In mice, PFOS exposure damaged the structure and function of the hippocampus, including decreasing the number of neurons and impairing spatial learning and memory capacity. Importantly, ferroptosis was also observed in vivo, concomitant with the inhibition of ATF4, which was also observed in vitro. ATF4 silencing further increased ROS levels, lipid peroxidation, and ferroptosis induced by PFOS, whereas NAC and Fer-1 abrogated the effects of ATF4 silencing. Treatment with E235, an ATF4 activator, alleviated PFOS-induced ferroptosis. In conclusion, this study revealed that ATF4-mediated ferroptosis is involved in PFOS-induced neurotoxicity, offering novel mechanistic insights into the neurotoxic effects of PFOS and potentially paving the way for new therapeutic strategies.
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spelling doaj-art-a9843be0d48549c3988f7520b0ac2a482025-08-20T02:03:25ZengElsevierEcotoxicology and Environmental Safety0147-65132025-07-0129911830310.1016/j.ecoenv.2025.118303ATF4 participates in perfluorooctane sulfonate-induced neurotoxicity by regulating ferroptosisFangling Zhu0Nan Wang1Yichao Xu2Xiaohua Su3Ziliang Deng4Yongdui Ruan5Daifan Lin6Yun Chen7Zhuoni Kuang8Guanlin Chen9Chengcheng Yu10Xiaoxuan Ling11Linhua Liu12Dongguan Key Laboratory of Environmental Medicine, The First Dongguan Affiliated Hospital, School of Public Health, Guangdong Medical University, Dongguan, Guangdong Province 523808, PR China; Department of Preventive Medicine, School of Public Health, Guangdong Medical University, Dongguan, Guangdong Province 523808, PR ChinaDongguan Key Laboratory of Environmental Medicine, The First Dongguan Affiliated Hospital, School of Public Health, Guangdong Medical University, Dongguan, Guangdong Province 523808, PR ChinaDongguan Key Laboratory of Environmental Medicine, The First Dongguan Affiliated Hospital, School of Public Health, Guangdong Medical University, Dongguan, Guangdong Province 523808, PR ChinaLaboratory Animal Center, Guangdong Medical University, Dongguan 523808, PR ChinaDepartment of Histology and Embryology of the Basic Medical College, Guangdong Medical University, Dongguan, Guangdong Province 523808, PR ChinaDongguan Key Laboratory of Environmental Medicine, The First Dongguan Affiliated Hospital, School of Public Health, Guangdong Medical University, Dongguan, Guangdong Province 523808, PR ChinaDongguan Key Laboratory of Environmental Medicine, The First Dongguan Affiliated Hospital, School of Public Health, Guangdong Medical University, Dongguan, Guangdong Province 523808, PR ChinaOccupational Health Monitoring, Foshan Institute of Occupational Disease Prevention and Control (Foshan Institute of Occupational Health), Foshan 528000, PR ChinaOccupational Health Monitoring, Foshan Institute of Occupational Disease Prevention and Control (Foshan Institute of Occupational Health), Foshan 528000, PR ChinaOccupational Health Monitoring, Foshan Institute of Occupational Disease Prevention and Control (Foshan Institute of Occupational Health), Foshan 528000, PR ChinaHealth Surveillance Department, Foshan Institute of Occupational Disease Prevention and Control (Foshan Institute of Occupational Health), Foshan 528000, PR ChinaDongguan Key Laboratory of Environmental Medicine, The First Dongguan Affiliated Hospital, School of Public Health, Guangdong Medical University, Dongguan, Guangdong Province 523808, PR China; Experimental Teaching Center, School of Public Health, Guangdong Medical University, Dongguan, Guangdong Province 523808, PR China; Corresponding authors at: Dongguan Key Laboratory of Environmental Medicine, The First Dongguan Affiliated Hospital, School of Public Health, Guangdong Medical University, Dongguan, Guangdong Province 523808, PR China.Dongguan Key Laboratory of Environmental Medicine, The First Dongguan Affiliated Hospital, School of Public Health, Guangdong Medical University, Dongguan, Guangdong Province 523808, PR China; Department of Preventive Medicine, School of Public Health, Guangdong Medical University, Dongguan, Guangdong Province 523808, PR China; Corresponding authors at: Dongguan Key Laboratory of Environmental Medicine, The First Dongguan Affiliated Hospital, School of Public Health, Guangdong Medical University, Dongguan, Guangdong Province 523808, PR China.Evidence from animal and human research suggests that perfluorooctane sulfonate (PFOS), a prevalent persistent organic pollutant (POP), exerts neurotoxic effects, but the precise mechanisms remain unclear. Additionally, the function of activating transcription factor 4 (ATF4), a crucial modulator of cellular metabolism, redox balance, and survival, in PFOS-induced neurotoxicity has not been fully elucidated. In vitro metabolomics studies revealed that PFOS elevated the intracellular concentration of reactive oxygen species (ROS) and lowered the levels of reduced L-glutathione (GSH). Significant alterations in the mRNA and protein expression levels of ferroptosis-related biomarkers, including ferroptosis-related genes [NRF2, nuclear receptor coactivator 4 (NCOA4), KEAP1, xCT/SLC7A11, GPX4, and FTH1], cellular iron, and lipid peroxidation were observed. Moreover, erastin (Ers) exacerbated lipid peroxidation, which was alleviated by ferrostatin-1 (Fer-1) and N-acetyl-L-cysteine (NAC). In mice, PFOS exposure damaged the structure and function of the hippocampus, including decreasing the number of neurons and impairing spatial learning and memory capacity. Importantly, ferroptosis was also observed in vivo, concomitant with the inhibition of ATF4, which was also observed in vitro. ATF4 silencing further increased ROS levels, lipid peroxidation, and ferroptosis induced by PFOS, whereas NAC and Fer-1 abrogated the effects of ATF4 silencing. Treatment with E235, an ATF4 activator, alleviated PFOS-induced ferroptosis. In conclusion, this study revealed that ATF4-mediated ferroptosis is involved in PFOS-induced neurotoxicity, offering novel mechanistic insights into the neurotoxic effects of PFOS and potentially paving the way for new therapeutic strategies.http://www.sciencedirect.com/science/article/pii/S0147651325006396ATF4PFOSferroptosisimpaired learning and memory abilities
spellingShingle Fangling Zhu
Nan Wang
Yichao Xu
Xiaohua Su
Ziliang Deng
Yongdui Ruan
Daifan Lin
Yun Chen
Zhuoni Kuang
Guanlin Chen
Chengcheng Yu
Xiaoxuan Ling
Linhua Liu
ATF4 participates in perfluorooctane sulfonate-induced neurotoxicity by regulating ferroptosis
Ecotoxicology and Environmental Safety
ATF4
PFOS
ferroptosis
impaired learning and memory abilities
title ATF4 participates in perfluorooctane sulfonate-induced neurotoxicity by regulating ferroptosis
title_full ATF4 participates in perfluorooctane sulfonate-induced neurotoxicity by regulating ferroptosis
title_fullStr ATF4 participates in perfluorooctane sulfonate-induced neurotoxicity by regulating ferroptosis
title_full_unstemmed ATF4 participates in perfluorooctane sulfonate-induced neurotoxicity by regulating ferroptosis
title_short ATF4 participates in perfluorooctane sulfonate-induced neurotoxicity by regulating ferroptosis
title_sort atf4 participates in perfluorooctane sulfonate induced neurotoxicity by regulating ferroptosis
topic ATF4
PFOS
ferroptosis
impaired learning and memory abilities
url http://www.sciencedirect.com/science/article/pii/S0147651325006396
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