Validation of a method for estimating pulmonary dead space in ventilated beagles to correct exhaled propofol concentration in mixed air

Abstract Background Mixed exhaled air has been widely used to determine exhaled propofol concentrations with online analyzers, but changes in dead space proportions may lead to inaccurate assessments of critical drug concentration data. This study proposes a method to correct propofol concentration...

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Main Authors: Xiaoxiao Li, Pan Chang, Xing Liu, Zhongjun Zhao, Yixiang Duan, Wensheng Zhang
Format: Article
Language:English
Published: BMC 2025-01-01
Series:BMC Veterinary Research
Subjects:
Online Access:https://doi.org/10.1186/s12917-024-04458-1
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author Xiaoxiao Li
Pan Chang
Xing Liu
Zhongjun Zhao
Yixiang Duan
Wensheng Zhang
author_facet Xiaoxiao Li
Pan Chang
Xing Liu
Zhongjun Zhao
Yixiang Duan
Wensheng Zhang
author_sort Xiaoxiao Li
collection DOAJ
description Abstract Background Mixed exhaled air has been widely used to determine exhaled propofol concentrations with online analyzers, but changes in dead space proportions may lead to inaccurate assessments of critical drug concentration data. This study proposes a method to correct propofol concentration in mixed air by estimating pulmonary dead space through reconstructing volumetric capnography (Vcap) from time-CO2 and time-volume curves, validated with vacuum ultraviolet time-of-flight mass spectrometry (VUV-TOF MS). Methods Existing monitoring parameters, including time-volume and time-CO2 curves, were used to determine Vcap. The ratio of physiological dead space to tidal volume (VD/VT) was calculated using Bohr’s formula. Additionally, an animal experiment on beagles was conducted with continuous propofol administration until a pseudo-steady state in exhaled propofol concentration was achieved. The propofol concentration in mixed air (CONCmix), and in alveolar air combined with N2 (CONCAN) were measured using VUV-TOF MS to calculate VD/VT. The agreements between VD/VT values from the two methods, along with the predicted CONCAN values based on Vcap and the actual measured CONCAN values were evaluated using the intraclass correlation coefficient (ICC) and Pearson correlation analysis. Results After 30 min of continuous propofol administration, a stable respiratory cycle was selected for analysis in each beagle. The calculated VD/VT-Bohr values were 0.535 for beagle A, 0.544 for beagle B, and 0.552 for beagle C. Additionally, based on CONCmix and CONCAN, the calculated VD/VT-VUV-TOF MS values were 0.494, 0.504, and 0.513, respectively. Strong agreement between the two methods was demonstrated by an ICC of 0.994 (P = 0.003) and Pearson’s r of 0.995 (P = 0.045). Additionally, the predicted CONCAN values from mixed exhaled air (5.11 parts per billion by volume (ppbv) for beagle A, 5.93 ppbv for beagle B, and 2.56 ppbv for beagle C) showed strong agreement with the actual CONCAN values, with an ICC of 0.996 (P = 0.002) and Pearson’s r of 0.994 (P = 0.046). Conclusion The physiological dead space to tidal volume ratio from mixed air in beagles can be accurately measured using the existing time-volume and time-CO2 curves from the anesthesia machine, enabling corrections of exhaled propofol concentrations in mixed air samples.
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spelling doaj-art-a8e4fd9452734defae99f86ea506fb3a2025-08-20T02:35:36ZengBMCBMC Veterinary Research1746-61482025-01-0121111010.1186/s12917-024-04458-1Validation of a method for estimating pulmonary dead space in ventilated beagles to correct exhaled propofol concentration in mixed airXiaoxiao Li0Pan Chang1Xing Liu2Zhongjun Zhao3Yixiang Duan4Wensheng Zhang5Department of Anesthesiology, West China Hospital, Sichuan UniversityDepartment of Anesthesiology, West China Hospital, Sichuan UniversityDepartment of Anesthesiology, West China Hospital, Sichuan UniversitySchool of Mechanical Engineering, Sichuan UniversitySchool of Mechanical Engineering, Sichuan UniversityDepartment of Anesthesiology, West China Hospital, Sichuan UniversityAbstract Background Mixed exhaled air has been widely used to determine exhaled propofol concentrations with online analyzers, but changes in dead space proportions may lead to inaccurate assessments of critical drug concentration data. This study proposes a method to correct propofol concentration in mixed air by estimating pulmonary dead space through reconstructing volumetric capnography (Vcap) from time-CO2 and time-volume curves, validated with vacuum ultraviolet time-of-flight mass spectrometry (VUV-TOF MS). Methods Existing monitoring parameters, including time-volume and time-CO2 curves, were used to determine Vcap. The ratio of physiological dead space to tidal volume (VD/VT) was calculated using Bohr’s formula. Additionally, an animal experiment on beagles was conducted with continuous propofol administration until a pseudo-steady state in exhaled propofol concentration was achieved. The propofol concentration in mixed air (CONCmix), and in alveolar air combined with N2 (CONCAN) were measured using VUV-TOF MS to calculate VD/VT. The agreements between VD/VT values from the two methods, along with the predicted CONCAN values based on Vcap and the actual measured CONCAN values were evaluated using the intraclass correlation coefficient (ICC) and Pearson correlation analysis. Results After 30 min of continuous propofol administration, a stable respiratory cycle was selected for analysis in each beagle. The calculated VD/VT-Bohr values were 0.535 for beagle A, 0.544 for beagle B, and 0.552 for beagle C. Additionally, based on CONCmix and CONCAN, the calculated VD/VT-VUV-TOF MS values were 0.494, 0.504, and 0.513, respectively. Strong agreement between the two methods was demonstrated by an ICC of 0.994 (P = 0.003) and Pearson’s r of 0.995 (P = 0.045). Additionally, the predicted CONCAN values from mixed exhaled air (5.11 parts per billion by volume (ppbv) for beagle A, 5.93 ppbv for beagle B, and 2.56 ppbv for beagle C) showed strong agreement with the actual CONCAN values, with an ICC of 0.996 (P = 0.002) and Pearson’s r of 0.994 (P = 0.046). Conclusion The physiological dead space to tidal volume ratio from mixed air in beagles can be accurately measured using the existing time-volume and time-CO2 curves from the anesthesia machine, enabling corrections of exhaled propofol concentrations in mixed air samples.https://doi.org/10.1186/s12917-024-04458-1Volumetric capnographyDead spacePropofolVacuum ultraviolet time-of-flight mass spectrometryOnline analysis
spellingShingle Xiaoxiao Li
Pan Chang
Xing Liu
Zhongjun Zhao
Yixiang Duan
Wensheng Zhang
Validation of a method for estimating pulmonary dead space in ventilated beagles to correct exhaled propofol concentration in mixed air
BMC Veterinary Research
Volumetric capnography
Dead space
Propofol
Vacuum ultraviolet time-of-flight mass spectrometry
Online analysis
title Validation of a method for estimating pulmonary dead space in ventilated beagles to correct exhaled propofol concentration in mixed air
title_full Validation of a method for estimating pulmonary dead space in ventilated beagles to correct exhaled propofol concentration in mixed air
title_fullStr Validation of a method for estimating pulmonary dead space in ventilated beagles to correct exhaled propofol concentration in mixed air
title_full_unstemmed Validation of a method for estimating pulmonary dead space in ventilated beagles to correct exhaled propofol concentration in mixed air
title_short Validation of a method for estimating pulmonary dead space in ventilated beagles to correct exhaled propofol concentration in mixed air
title_sort validation of a method for estimating pulmonary dead space in ventilated beagles to correct exhaled propofol concentration in mixed air
topic Volumetric capnography
Dead space
Propofol
Vacuum ultraviolet time-of-flight mass spectrometry
Online analysis
url https://doi.org/10.1186/s12917-024-04458-1
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