Laser Fabrication of Multi‐Dimensional Perovskite Patterns with Intelligent Anti‐Counterfeiting Applications

Abstract Perovskites have gained widespread attention across various fields such as photovoltaics, displays, and imaging. Despite their promising applications, achieving precise and high‐quality patterning of perovskite films remains a challenge. In this study, femtosecond laser direct writing techn...

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Main Authors: Xiangyu Xu, Shoufang Liu, Yan Kuai, Yuxuan Jiang, Zhijia Hu, Benli Yu, Siqi Li
Format: Article
Language:English
Published: Wiley 2024-11-01
Series:Advanced Science
Subjects:
Online Access:https://doi.org/10.1002/advs.202309862
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author Xiangyu Xu
Shoufang Liu
Yan Kuai
Yuxuan Jiang
Zhijia Hu
Benli Yu
Siqi Li
author_facet Xiangyu Xu
Shoufang Liu
Yan Kuai
Yuxuan Jiang
Zhijia Hu
Benli Yu
Siqi Li
author_sort Xiangyu Xu
collection DOAJ
description Abstract Perovskites have gained widespread attention across various fields such as photovoltaics, displays, and imaging. Despite their promising applications, achieving precise and high‐quality patterning of perovskite films remains a challenge. In this study, femtosecond laser direct writing technology is utilized to achieve rapid and highly precise micro/nanofabrication on perovskites. The study successfully fabricates multiple structured and emission‐tunable perovskite patterns composed of A2(FA)n−1PbnX3n+1 (A represents a series of long‐chain amine cations, and X = Cl, Br, I), encompassing 2D, quasi‐2D, and 3D structures. The study delves into the intricate interplay between fabrication technology and the growth of multi‐dimensional perovskites: higher repetition rates, coupled with appropriate laser power, prove more conducive to perovskite growth. By employing precise halogen element design, the simultaneous generation of two distinct color quick‐response (QR) code patterns is achieved through one‐step laser processing. These mirrored QR codes offer a novel approach to anti‐counterfeiting. To further enhance anti‐counterfeiting capabilities, artificial intelligence (AI)‐based methods are introduced for recognizing patterned perovskite anti‐counterfeiting labels. The combination of deep learning algorithms and a non‐deterministic manufacturing process provides a convenient means of identification and creates unclonable features. This integration of materials science, laser fabrication, and AI offers innovative solutions for the future of security features.
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spelling doaj-art-a8af045b924b4012b139733a46ff9da82025-08-20T02:58:41ZengWileyAdvanced Science2198-38442024-11-011142n/an/a10.1002/advs.202309862Laser Fabrication of Multi‐Dimensional Perovskite Patterns with Intelligent Anti‐Counterfeiting ApplicationsXiangyu Xu0Shoufang Liu1Yan Kuai2Yuxuan Jiang3Zhijia Hu4Benli Yu5Siqi Li6School of Physics and Optoelectronic Engineering Anhui University Hefei Anhui 230601 P. R. ChinaSchool of Physics and Optoelectronic Engineering Anhui University Hefei Anhui 230601 P. R. ChinaInformation Materials and Intelligent Sensing Laboratory of Anhui Province Anhui University Hefei Anhui 230601 P. R. ChinaSchool of Physics and Optoelectronic Engineering Anhui University Hefei Anhui 230601 P. R. ChinaSchool of Physics and Optoelectronic Engineering Anhui University Hefei Anhui 230601 P. R. ChinaSchool of Physics and Optoelectronic Engineering Anhui University Hefei Anhui 230601 P. R. ChinaSchool of Physics and Optoelectronic Engineering Anhui University Hefei Anhui 230601 P. R. ChinaAbstract Perovskites have gained widespread attention across various fields such as photovoltaics, displays, and imaging. Despite their promising applications, achieving precise and high‐quality patterning of perovskite films remains a challenge. In this study, femtosecond laser direct writing technology is utilized to achieve rapid and highly precise micro/nanofabrication on perovskites. The study successfully fabricates multiple structured and emission‐tunable perovskite patterns composed of A2(FA)n−1PbnX3n+1 (A represents a series of long‐chain amine cations, and X = Cl, Br, I), encompassing 2D, quasi‐2D, and 3D structures. The study delves into the intricate interplay between fabrication technology and the growth of multi‐dimensional perovskites: higher repetition rates, coupled with appropriate laser power, prove more conducive to perovskite growth. By employing precise halogen element design, the simultaneous generation of two distinct color quick‐response (QR) code patterns is achieved through one‐step laser processing. These mirrored QR codes offer a novel approach to anti‐counterfeiting. To further enhance anti‐counterfeiting capabilities, artificial intelligence (AI)‐based methods are introduced for recognizing patterned perovskite anti‐counterfeiting labels. The combination of deep learning algorithms and a non‐deterministic manufacturing process provides a convenient means of identification and creates unclonable features. This integration of materials science, laser fabrication, and AI offers innovative solutions for the future of security features.https://doi.org/10.1002/advs.202309862anti‐counterfeitingartificial intelligencefemtosecond laser direct writingperovskite
spellingShingle Xiangyu Xu
Shoufang Liu
Yan Kuai
Yuxuan Jiang
Zhijia Hu
Benli Yu
Siqi Li
Laser Fabrication of Multi‐Dimensional Perovskite Patterns with Intelligent Anti‐Counterfeiting Applications
Advanced Science
anti‐counterfeiting
artificial intelligence
femtosecond laser direct writing
perovskite
title Laser Fabrication of Multi‐Dimensional Perovskite Patterns with Intelligent Anti‐Counterfeiting Applications
title_full Laser Fabrication of Multi‐Dimensional Perovskite Patterns with Intelligent Anti‐Counterfeiting Applications
title_fullStr Laser Fabrication of Multi‐Dimensional Perovskite Patterns with Intelligent Anti‐Counterfeiting Applications
title_full_unstemmed Laser Fabrication of Multi‐Dimensional Perovskite Patterns with Intelligent Anti‐Counterfeiting Applications
title_short Laser Fabrication of Multi‐Dimensional Perovskite Patterns with Intelligent Anti‐Counterfeiting Applications
title_sort laser fabrication of multi dimensional perovskite patterns with intelligent anti counterfeiting applications
topic anti‐counterfeiting
artificial intelligence
femtosecond laser direct writing
perovskite
url https://doi.org/10.1002/advs.202309862
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