Comparing two synthesis methods: Exploring unique characteristics and catalytic activity of fenton catalyst Fe3O4/zeolite-NaY in methylene blue degradation

A composite catalyst was developed to degrade methylene blue (MB) via the Fenton reaction from Fe3O4 and H2O2 with zeolite-NaY as magnetite support to reduce agglomeration. Hydrothermal and co-precipitation approaches were used to synthesize the composite. The co-precipitation method here was proven...

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Main Authors: Dinia Astira, Romario Abdullah, Utari Zulfiani, Dety Oktavia Sulistiono, Zeni Rahmawati, Triyanda Gunawan, Mohd Hafiz Dzarfan Othman, Muhammad Hasan, Ratna Ediati, Hamzah Fansuri
Format: Article
Language:English
Published: Elsevier 2024-12-01
Series:Case Studies in Chemical and Environmental Engineering
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666016424003578
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author Dinia Astira
Romario Abdullah
Utari Zulfiani
Dety Oktavia Sulistiono
Zeni Rahmawati
Triyanda Gunawan
Mohd Hafiz Dzarfan Othman
Muhammad Hasan
Ratna Ediati
Hamzah Fansuri
author_facet Dinia Astira
Romario Abdullah
Utari Zulfiani
Dety Oktavia Sulistiono
Zeni Rahmawati
Triyanda Gunawan
Mohd Hafiz Dzarfan Othman
Muhammad Hasan
Ratna Ediati
Hamzah Fansuri
author_sort Dinia Astira
collection DOAJ
description A composite catalyst was developed to degrade methylene blue (MB) via the Fenton reaction from Fe3O4 and H2O2 with zeolite-NaY as magnetite support to reduce agglomeration. Hydrothermal and co-precipitation approaches were used to synthesize the composite. The co-precipitation method here was proven to be more suitable to produce the composite. Under optimal conditions, all composite catalysts achieved a remarkable MB reduction (more than 90 %) as confirmed through TLC analysis and UV–Vis spectra. Notably, based on linear regression, FeZ-A maintained over 60 % activity after 15 uses, while FeZ-2 showed the least Fe ion leaching. This demonstrated the effectiveness and stability of the developed catalysts.
format Article
id doaj-art-a7dac1c632aa41a48d5779fc49f19728
institution OA Journals
issn 2666-0164
language English
publishDate 2024-12-01
publisher Elsevier
record_format Article
series Case Studies in Chemical and Environmental Engineering
spelling doaj-art-a7dac1c632aa41a48d5779fc49f197282025-08-20T02:17:57ZengElsevierCase Studies in Chemical and Environmental Engineering2666-01642024-12-011010096310.1016/j.cscee.2024.100963Comparing two synthesis methods: Exploring unique characteristics and catalytic activity of fenton catalyst Fe3O4/zeolite-NaY in methylene blue degradationDinia Astira0Romario Abdullah1Utari Zulfiani2Dety Oktavia Sulistiono3Zeni Rahmawati4Triyanda Gunawan5Mohd Hafiz Dzarfan Othman6Muhammad Hasan7Ratna Ediati8Hamzah Fansuri9Departement of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Sukolilo, Surabaya 60111, IndonesiaDepartement of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Sukolilo, Surabaya 60111, IndonesiaDepartement of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Sukolilo, Surabaya 60111, IndonesiaDepartement of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Sukolilo, Surabaya 60111, Indonesia; Automotive Engineering, Engineering Department, Politeknik Negeri Jember, Jember 68101, IndonesiaDepartement of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Sukolilo, Surabaya 60111, IndonesiaDepartement of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Sukolilo, Surabaya 60111, IndonesiaAdvanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 Skudai, Johor Bahru, MalaysiaDepartment of Chemistry Education, Faculty of Teacher Training and Education, Universitas Syiah Kuala, Darussalam, Banda Aceh 23111, IndonesiaDepartement of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Sukolilo, Surabaya 60111, IndonesiaDepartement of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Sukolilo, Surabaya 60111, Indonesia; Corresponding author.A composite catalyst was developed to degrade methylene blue (MB) via the Fenton reaction from Fe3O4 and H2O2 with zeolite-NaY as magnetite support to reduce agglomeration. Hydrothermal and co-precipitation approaches were used to synthesize the composite. The co-precipitation method here was proven to be more suitable to produce the composite. Under optimal conditions, all composite catalysts achieved a remarkable MB reduction (more than 90 %) as confirmed through TLC analysis and UV–Vis spectra. Notably, based on linear regression, FeZ-A maintained over 60 % activity after 15 uses, while FeZ-2 showed the least Fe ion leaching. This demonstrated the effectiveness and stability of the developed catalysts.http://www.sciencedirect.com/science/article/pii/S2666016424003578Fe3O4Zeolite-NaYCatalystCompositeWastewater treatmentHetero-fenton
spellingShingle Dinia Astira
Romario Abdullah
Utari Zulfiani
Dety Oktavia Sulistiono
Zeni Rahmawati
Triyanda Gunawan
Mohd Hafiz Dzarfan Othman
Muhammad Hasan
Ratna Ediati
Hamzah Fansuri
Comparing two synthesis methods: Exploring unique characteristics and catalytic activity of fenton catalyst Fe3O4/zeolite-NaY in methylene blue degradation
Case Studies in Chemical and Environmental Engineering
Fe3O4
Zeolite-NaY
Catalyst
Composite
Wastewater treatment
Hetero-fenton
title Comparing two synthesis methods: Exploring unique characteristics and catalytic activity of fenton catalyst Fe3O4/zeolite-NaY in methylene blue degradation
title_full Comparing two synthesis methods: Exploring unique characteristics and catalytic activity of fenton catalyst Fe3O4/zeolite-NaY in methylene blue degradation
title_fullStr Comparing two synthesis methods: Exploring unique characteristics and catalytic activity of fenton catalyst Fe3O4/zeolite-NaY in methylene blue degradation
title_full_unstemmed Comparing two synthesis methods: Exploring unique characteristics and catalytic activity of fenton catalyst Fe3O4/zeolite-NaY in methylene blue degradation
title_short Comparing two synthesis methods: Exploring unique characteristics and catalytic activity of fenton catalyst Fe3O4/zeolite-NaY in methylene blue degradation
title_sort comparing two synthesis methods exploring unique characteristics and catalytic activity of fenton catalyst fe3o4 zeolite nay in methylene blue degradation
topic Fe3O4
Zeolite-NaY
Catalyst
Composite
Wastewater treatment
Hetero-fenton
url http://www.sciencedirect.com/science/article/pii/S2666016424003578
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