Pinacol Coupling of Aromatic Aldehydes using La-Ticl4 in CH3COOEt under Ultrasound Irradiation

Titanium tetrachloride can be reduced by lanthanum filings to the corresponding low valent titanium complex, which can induce some aromatic aldehydes to the corresponding pinacols in 28%-97% yields within 10-50 min in ethyl acetate at r.t. under ultrasound irradiation.

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Main Authors: Ji-Tai Li, Xue-Li Sun, Zhi-Ping Lin, Tong-Shuang Li
Format: Article
Language:English
Published: Wiley 2006-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2006/107491
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author Ji-Tai Li
Xue-Li Sun
Zhi-Ping Lin
Tong-Shuang Li
author_facet Ji-Tai Li
Xue-Li Sun
Zhi-Ping Lin
Tong-Shuang Li
author_sort Ji-Tai Li
collection DOAJ
description Titanium tetrachloride can be reduced by lanthanum filings to the corresponding low valent titanium complex, which can induce some aromatic aldehydes to the corresponding pinacols in 28%-97% yields within 10-50 min in ethyl acetate at r.t. under ultrasound irradiation.
format Article
id doaj-art-a7abca5667004d50a91e55ee2898dda8
institution OA Journals
issn 0973-4945
2090-9810
language English
publishDate 2006-01-01
publisher Wiley
record_format Article
series E-Journal of Chemistry
spelling doaj-art-a7abca5667004d50a91e55ee2898dda82025-08-20T02:20:57ZengWileyE-Journal of Chemistry0973-49452090-98102006-01-013423023510.1155/2006/107491Pinacol Coupling of Aromatic Aldehydes using La-Ticl4 in CH3COOEt under Ultrasound IrradiationJi-Tai Li0Xue-Li Sun1Zhi-Ping Lin2Tong-Shuang Li3College of Chemistry and Environmental Science, Hebei University, Key Laboratory of Analytical Science and Technology of Hebei Province, Baoding 071002, ChinaCollege of Chemistry and Environmental Science, Hebei University, Key Laboratory of Analytical Science and Technology of Hebei Province, Baoding 071002, ChinaCollege of Chemistry and Environmental Science, Hebei University, Key Laboratory of Analytical Science and Technology of Hebei Province, Baoding 071002, ChinaCollege of Chemistry and Environmental Science, Hebei University, Key Laboratory of Analytical Science and Technology of Hebei Province, Baoding 071002, ChinaTitanium tetrachloride can be reduced by lanthanum filings to the corresponding low valent titanium complex, which can induce some aromatic aldehydes to the corresponding pinacols in 28%-97% yields within 10-50 min in ethyl acetate at r.t. under ultrasound irradiation.http://dx.doi.org/10.1155/2006/107491
spellingShingle Ji-Tai Li
Xue-Li Sun
Zhi-Ping Lin
Tong-Shuang Li
Pinacol Coupling of Aromatic Aldehydes using La-Ticl4 in CH3COOEt under Ultrasound Irradiation
E-Journal of Chemistry
title Pinacol Coupling of Aromatic Aldehydes using La-Ticl4 in CH3COOEt under Ultrasound Irradiation
title_full Pinacol Coupling of Aromatic Aldehydes using La-Ticl4 in CH3COOEt under Ultrasound Irradiation
title_fullStr Pinacol Coupling of Aromatic Aldehydes using La-Ticl4 in CH3COOEt under Ultrasound Irradiation
title_full_unstemmed Pinacol Coupling of Aromatic Aldehydes using La-Ticl4 in CH3COOEt under Ultrasound Irradiation
title_short Pinacol Coupling of Aromatic Aldehydes using La-Ticl4 in CH3COOEt under Ultrasound Irradiation
title_sort pinacol coupling of aromatic aldehydes using la ticl4 in ch3cooet under ultrasound irradiation
url http://dx.doi.org/10.1155/2006/107491
work_keys_str_mv AT jitaili pinacolcouplingofaromaticaldehydesusinglaticl4inch3cooetunderultrasoundirradiation
AT xuelisun pinacolcouplingofaromaticaldehydesusinglaticl4inch3cooetunderultrasoundirradiation
AT zhipinglin pinacolcouplingofaromaticaldehydesusinglaticl4inch3cooetunderultrasoundirradiation
AT tongshuangli pinacolcouplingofaromaticaldehydesusinglaticl4inch3cooetunderultrasoundirradiation