Evaluation of Distribution of Succinic Acid between Binary Phase System with Biodiesel + N,N-Dioctyloctan-1-amine
The present study is aimed at using one of the most promising methods called reactive extraction to extract succinic acid from aqueous solution by using N,N-dioctyloctan-1-amine in biodiesel as diluent made from sunflower oil, rice bran oil, sesame oil, and karanji oil. The results of extraction stu...
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| Format: | Article |
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Wiley
2019-01-01
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| Series: | International Journal of Chemical Engineering |
| Online Access: | http://dx.doi.org/10.1155/2019/9346038 |
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| author | Sunder Lal Pal Shourabh Singh Raghuwanshi Kanti Kumar Athankar Ashwani Kumar Rathore |
| author_facet | Sunder Lal Pal Shourabh Singh Raghuwanshi Kanti Kumar Athankar Ashwani Kumar Rathore |
| author_sort | Sunder Lal Pal |
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| description | The present study is aimed at using one of the most promising methods called reactive extraction to extract succinic acid from aqueous solution by using N,N-dioctyloctan-1-amine in biodiesel as diluent made from sunflower oil, rice bran oil, sesame oil, and karanji oil. The results of extraction studies with the diluents (physical) showed their inability to recover any acid by themselves. In reactive extraction, the organic phase extracting power solely depends on tri-n-octylamine. The ranges of the distribution coefficient are found as 7.62–18.12 for sunflower oil biodiesel, 8.33–17.45 for rice bran oil biodiesel, 7.0–17.67 for sesame oil biodiesel, and 9.85–21.36 for karanji oil biodiesel. The ranges of the loading ratio are 0.1–3.0 for sunflower oil biodiesel, 0.1–2.9 for rice bran oil biodiesel, 0.2–2.9 for sesame oil biodiesel, and 0.1–2.9 for karanji oil biodiesel. The karanji and sunflower oil showed higher values of distribution coefficient (KD) over rice bran oil and sesame oil which might be due to presence of both C20 and special fatty acids. The results show that biogenous diluents along with N,N-dioctyloctan-1-amine as extractant form a nontoxic and viable option for the extraction of succinic acid in the binary phase system. |
| format | Article |
| id | doaj-art-a782dbdecba1449782eea48204a2c02c |
| institution | OA Journals |
| issn | 1687-806X 1687-8078 |
| language | English |
| publishDate | 2019-01-01 |
| publisher | Wiley |
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| series | International Journal of Chemical Engineering |
| spelling | doaj-art-a782dbdecba1449782eea48204a2c02c2025-08-20T02:20:57ZengWileyInternational Journal of Chemical Engineering1687-806X1687-80782019-01-01201910.1155/2019/93460389346038Evaluation of Distribution of Succinic Acid between Binary Phase System with Biodiesel + N,N-Dioctyloctan-1-amineSunder Lal Pal0Shourabh Singh Raghuwanshi1Kanti Kumar Athankar2Ashwani Kumar Rathore3Department of Chemical Engineering, Maulana Azad National Institute of Technology, Bhopal 462003, MP, IndiaDepartment of Chemical Engineering, Maulana Azad National Institute of Technology, Bhopal 462003, MP, IndiaDepartment of Chemical and Biochemical Engineering, Faculty of Chemical and Food Technology, Slovak University of Technology, Bratislava 812 37, Radlinskeho 9, SlovakiaDepartment of Chemical Engineering, Maulana Azad National Institute of Technology, Bhopal 462003, MP, IndiaThe present study is aimed at using one of the most promising methods called reactive extraction to extract succinic acid from aqueous solution by using N,N-dioctyloctan-1-amine in biodiesel as diluent made from sunflower oil, rice bran oil, sesame oil, and karanji oil. The results of extraction studies with the diluents (physical) showed their inability to recover any acid by themselves. In reactive extraction, the organic phase extracting power solely depends on tri-n-octylamine. The ranges of the distribution coefficient are found as 7.62–18.12 for sunflower oil biodiesel, 8.33–17.45 for rice bran oil biodiesel, 7.0–17.67 for sesame oil biodiesel, and 9.85–21.36 for karanji oil biodiesel. The ranges of the loading ratio are 0.1–3.0 for sunflower oil biodiesel, 0.1–2.9 for rice bran oil biodiesel, 0.2–2.9 for sesame oil biodiesel, and 0.1–2.9 for karanji oil biodiesel. The karanji and sunflower oil showed higher values of distribution coefficient (KD) over rice bran oil and sesame oil which might be due to presence of both C20 and special fatty acids. The results show that biogenous diluents along with N,N-dioctyloctan-1-amine as extractant form a nontoxic and viable option for the extraction of succinic acid in the binary phase system.http://dx.doi.org/10.1155/2019/9346038 |
| spellingShingle | Sunder Lal Pal Shourabh Singh Raghuwanshi Kanti Kumar Athankar Ashwani Kumar Rathore Evaluation of Distribution of Succinic Acid between Binary Phase System with Biodiesel + N,N-Dioctyloctan-1-amine International Journal of Chemical Engineering |
| title | Evaluation of Distribution of Succinic Acid between Binary Phase System with Biodiesel + N,N-Dioctyloctan-1-amine |
| title_full | Evaluation of Distribution of Succinic Acid between Binary Phase System with Biodiesel + N,N-Dioctyloctan-1-amine |
| title_fullStr | Evaluation of Distribution of Succinic Acid between Binary Phase System with Biodiesel + N,N-Dioctyloctan-1-amine |
| title_full_unstemmed | Evaluation of Distribution of Succinic Acid between Binary Phase System with Biodiesel + N,N-Dioctyloctan-1-amine |
| title_short | Evaluation of Distribution of Succinic Acid between Binary Phase System with Biodiesel + N,N-Dioctyloctan-1-amine |
| title_sort | evaluation of distribution of succinic acid between binary phase system with biodiesel n n dioctyloctan 1 amine |
| url | http://dx.doi.org/10.1155/2019/9346038 |
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